• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2007년도 춘계학술대회 논문집
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• pp.123-126
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• 2007

Deformation behavior of $Zr_{55}Cu_{30}Al_{10}Ni_5$ (at. %) bulk metallic glass (BMG) fabricated by suction casting method has been investigated at elevated temperatures in this study. The BMG was first verified to have an amorphous structure thru X-ray diffraction (XRD) and differential scanning calorimetry (DSC). A series of compression tests has consequently been performed in supercooled liquid temperature region to investigate the high temperature deformation behavior. A transition from Newtonian to non-Newtonian flow appeared to take place depending upon both the strain rate and test temperature. A processing map based on a dynamic materials model has been constructed to estimate a feasible forming condition for this BMG alloy.

• 소성∙가공
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• 제16권4호
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• pp.309-312
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• 2007

Deformation behavior of $Zr_{55}Cu_{30}Al_{10}Ni_5$(at. %) bulk metallic glass(BMG) fabricated by suction casting method has been investigated at elevated temperatures in this study. The BMG was first verified to have an amorphous structure with the analysis of X-ray diffraction(XRD) and differential scanning calorimetry(DSC) data. A series of compression tests has consequently been performed in the region of supercooled liquid temperature to investigate the behavior of high temperature deformation. A transition from Newtonian to non-Newtonian flow appeared to take place depending upon both the strain rate and test temperature. A processing map based on a dynamic materials model has been constructed to estimate a feasible forming condition for this BMG alloy.

• 대한기계학회논문집A
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• 제36권6호
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• pp.591-598
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• 2012

본 연구에서는 CNC선반을 사용하여 다양한 공구재질과 절삭속도에서 벌크금속유리(BMG)의 절삭 특성을 평가하였다. 선반가공시 Zr-기 BMG의 표면거칠기와 칩 형상을 관찰하여 가공조건에 따른 절삭력과 공구툴 마모 등 절삭 특성을 비교 검토하였다. 직경 8 mm $Zr_{50}Cu_{40}Al_{10}$ BMG시험편의 절삭에는 네 종류의 절삭공구를 사용하였다. 가공후 BMG 시험편의 표면거칠기를 측정하였고, 표면거칠기에 미치는 공구 회전속도의 영향을 조사하였다. 회전속도가 빠를수록 낮은 표면거칠기를 나타내었고, 공구 재질의 영향도 크게 나타났다. 칩 형상의 관찰 결과, 산화를 일으키지 않은 BMG 칩은 단열 전단띠 발생과 함께 나선형상의 형태를 나타내지만, 산화를 일으킨 칩은 국부적으로 용융과 함께 칩들이 뭉치는 현상을 나타내었다. BMG시험편을 가공하는 동안 발생한 절삭력은 TiN-WC에서 가장 큰 값을 나타내고, PCD가 그 다음, Cermet툴에서 가장 작은 값을 나타내었다.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2007년도 추계학술대회 논문집
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• pp.143-145
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• 2007

The correlation between crystallization and deformation behavior in the supercooled liquid region (SLR) of a $Cu_{54}Ni_{6}Zr_{22}Ti_{18}$ bulk metallic glass (BMG) alloy is investigated by compression tests, differential scanning calorimetry (DSC), electron energy loss spectrometry (EELS) and high resolution transmission electron microscopy (HRTEM). In the SLR, This BMG alloy was strongly depended on the deformation temperature and the alloy exhibits important change in deformation behavior after a given time which is directly connected to the development of crystallization. Compressive stress impeded decomposition and consequently retarded forming of nano-crystal, which led to enlarge the homogeneous deformation region of the BMG alloy in SLR during compression test.

• 한국전기전자재료학회논문지
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• 제31권4호
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• pp.249-254
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• 2018

We researched about a bulk metallic glass system as an additive to an Ag paste for high temperature thermoelectric modules. Bulk metallic glass (BMG) ribbons were produced by using a rapid solidification process (RSP) under a cooling rate condition higher than $10^{\circ}C/sec$. We investigated BMG characteristics of the ribbons by means of x-ray diffraction (XRD) and differential scanning calorimetry (DSC) in order to evaluate the glass transition temperature ($T_g$) and the recrystallization temperature ($T_x$) lower than $400^{\circ}C$. A milling process was also developed to apply the BMG ribbons to a commercial Al paste as an additive for lower sintering temperature.

• 대한기계학회논문집A
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• 제33권7호
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• pp.687-692
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• 2009

The friction welding of Zr-based bulk metallic glass (BMG) rods and tubes to similar BMGs, and to crystalline metals were performed. An infrared thermal imager (FLIR-Thermal Cam SC-2000) was used to measure the temperature distribution at joining interface of the specimens during friction welding. All BMGs adopted in this study showed a successful friction joining to similar BMG. The shape of the protrusion formed at the weld interface were examined. In order to characterize the friction weld interface, the micrographic observation and the X-ray diffraction analysis on the weld cross-section were carried out. The obtained results were discussed based on the temperature distribution measured at the weld interface A successful joining of the BMGs to crystalline metals could be obtained for certain pairs of the material combination through the precise control of the friction condition. The residual strength after dissimilar friction welding of BMG was evaluated by the four-point bending test and compared with the cases of friction welding to similar materials.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2006년도 춘계학술대회 논문집
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• pp.417-420
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• 2006

The composition and structure of dendrite phase within $Zr_{76.11}Ti_{4.20}Cu_{4.51}Ni_{3.16}Be_{1.49}Nb_{10.53}$ bulk metallic glass (BMG) were confirmed by using an EPMA, XRD and TEM, respectively. The chief elements of dendrite phase were Zr-Ti-Nb and had a BCC structure. The thermal properties of this BMG have been then subsequently investigated by using a differential scanning calorimeter (DSC). The glass transition and crystallization onset temperatures were determined as $339.7^{\circ}C$ and $375.8^{\circ}C$ for this alloy, respectively. Mechanical properties have also been examined by conducting a series of uniaxial compression tests at various temperatures within supercooled liquid region under the strain rates between $10^{-4}/s$ and $3{\times}10^{-2}/s$. The deformation behavior of BMG composite within supercooled liquid region is similar to one of Vit-1 exhibiting amorphous single phase alloy. The flow stresses of BMG composite, however, are entirely higher than those of Vit-1 because dendrite phases are interfere with moving of atoms.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2004년도 추계학술대회
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• pp.337-341
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• 2004

Bulk metallic glasses(BMG) with good mechanical properties have problems that engineering application fields have been limited because of limitation of the alloy size. In order to solving this problem, the friction welding of BMG has been tried using the superplastic-like deformation behavior under the supercooled liquid region. The apparatus for friction welding test was designed and constructed using pneumatic cylinder and gripper based on a conventional lathe. Friction welding have been tried to combination of same BMG alloy and crystalline alloys. The results of welding test were evaluated by X-ray diffraction, measurement of hardness and mechanical properties test. In order to obtain the optimized welding test conditions the temperature of friction interface was measured using Infrared thermal imager.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2003년도 추계학술대회논문집
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• pp.93-96
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• 2003

Recently, various bulk metallic glasses (BMG's) haying good mechanical and chemical properties were developed. BMG's can easily be deformed in the supercooled liquid region, via viscous flow mechanism. In our previous work, we evaluated the deformation behavior and some other basic properties of Z $r_{41.2}$ $Ti_{13.8}$C $u_{12.5}$N $i_{10}$B $e_{22.5}$ alloy. In this study, we investigated the micro forming of Z $r_{41.2}$ $Ti_{13.8}$C $u_{12.5}$N $i_{10}$B $e_{22.5}$ alloy. The process condition was chosen based on the viscosity data from TMA, and superalloy and Si wafer with micro patterns on the surface were used as forming die. The alloy showed good replication of the patterns. However, some stripe patterns, resembling scratches, appeared on the deformed alloy surface. These scratches can be reduced or eliminated by polishing before forming.ing.ore forming.ing.

• 소성∙가공
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• 제13권1호
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• pp.9-14
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• 2004

Recently, various bulk metallic glasses (BMG's) having good mechanical and chemical properties were developed. BMG's can easily be deformed in the supercooled liquid region, via viscous flow mechanism. By using the viscous flow, the very low pressure is needed to deform the materials. In this study, we investigated the structural transition and deformation behavior of Vitreloy 1 (Zr/sub 41.2/Ti/sub 13.8/Cu/sub 12.5/Ni/sub 10/Be/sub 22.5/) using TMA and DSC. We applied the results to the micro forming process. The forming condition was chosen based on the viscosity data from TMA, and Si wafer with micro patterns on the surface was used as a forming die. The deformed surface was analyzed by SEM and 3D Surface Profiling System. The alloy showed good replication of the patterns. Quantitative measurement of roughness was useful to evaluate the replication. Surface condition of the deformed surface was determined by the initial surface condition.