• Title/Summary/Keyword: buffer gas

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The Studies for the Malate Tissue Biosensor Using Malate Dehydrogenase(Decarboxylating) in the Bundle Sheath Cell of the Corn Leaf (옥수수잎의 유관속초세포내에 들어 있는 Malate Dehydrogenase(Decarboxylating)을 이용한 Malate 측정용 조직바이오센서에 관한 연구)

  • 김의락;노광수
    • KSBB Journal
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    • v.9 no.3
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    • pp.319-324
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    • 1994
  • A biosensor for the measurement of malate has been constructed by the sodium-alginate immobilized bundle sheath cell tissue of corn leaf containing malate dehydrogenase (decarboxylating) (EC 1. 1. 1. 40) on the CO2 gas-sensing electrode. The proposed tissue sensor had the linear in the range of malate concentration $5.5{\times}10^{-5}M∼2.5{\times}10^{-2}M$ with a slope of 53.5 mV/decade in 0.02M Tris-HCl buffer solution at optimum pH 8.0, and $25^{\circ}C$. A response time was 16∼18min. The present L-malate sensing tissue sensor is stable for more than one week. At pH 7.4, Km value was $0.6{\times}10^{-5}M$. The various kinds of salt did not effect the signal of malate tissue biosensor as the inhibitor. We can measure the malate by the CO2 electrode at the pH=8.0. Thus, the proposed tissue sensor will be useful for the measurement of malate.

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Pulsatile Pressure Distribution on the Snubber of Reciprocating Compressor (왕복동식 압축기의 스너버내 맥동압 분포)

  • Lee, Gyeong-Hwan;Rahman, Mohammad-Shiddiqur;Chung, Han-Shik;Jung, Hyo-Min
    • Proceedings of the SAREK Conference
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    • 2007.11a
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    • pp.606-611
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    • 2007
  • Pulsation is an inherent phenomenon in reciprocating compressors. It interacts with piping to cause vibrations and performance problems. Indiscriminately connecting to a compressor can be dangerous and cost money in the form of broken equipment and piping, poor performance, inaccurate metering, unwanted vibration, and sometimes noise. Piping connected to a compressor can materially affect the performance and response. To minimize these detrimental effects, reciprocating compressor system should be equipped by pulsation suppression system. This study discusses pressure pulsation phenomena occurred in a reciprocating compressor system. An experiment applied air compressor unit, as pulsating pressure generator, has been done. The compressor was connected sequentially to a snubber model and pressure tank. Sensor probes were placed on the inlet and outlet pipes of snubber. Compressor was driven by a motor controlled by a frequency regulator. The experiment was conducted by adjusting the regulator at 40Hz. General information about an internal gas flow can be achieved by numerical analysis approach. Information of the velocity, pressure and turbulence kinetic energy distribution are presented in this paper. Based on this result, the design improvement might be done.

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Gas-Sensing Membrane Electrodes for the Determination of Dissolved Gases (III). Continuous-Automated Determination of Nitrite Ion Using a New Tubular PVC Membrane Type of Selective Electrode Nitrate (溶解氣體 分析用 氣體感應膜 이온選擇性 電極 (第 3 報). 새로운 管形 PVC膜 질산이온 選擇性 電極을 이용한 아질산이온의連續·自動化 定量)

  • Lee Heung Lark;Yun Jong-Hoon
    • Journal of the Korean Chemical Society
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    • v.35 no.1
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    • pp.51-58
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    • 1991
  • A new tubular poly(vinyl chloride) membrane type of nitrate selective electrode was prepared and its characteristics were evaluated. The response slope, detection limit, and response time (t$_{99}$) under the optimum membrane composition (5${\%}$ aliquat-NO$_3$ solution + 32${\%}$ poly(vinyl chloride) + 63${\%}$ dibutyl sebecate) of the electrode were 58.5 ${\pm}$ 0.1 mV/decade, 2.0 ${\times}$ 10$^{-5}$ M, and 25 seconds, respectively. The nitrite ion was determined by the continuous-automated method using the new electrode. 10$^{-2}$ M phosphate buffer solution (pH 7.6) was used as a recipient solution. And also hydrogen peroxide (0.3${\%}$) was added to the recipient as an oxidant. The linear response range and response range and response slope for the standard nitrite solution under the optimum condition of this electrode system were 8.0 ${\times}$ 10$^{-5}$ M ∼ 5.0 ${\times}$ 10$^{-2}$ M and 56.8 ${\pm}$ 0.2 mV/decade, respectively.

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Quantification of Glycerol by Malachite Green Fading Phenomenon: Application in Reaction By-Product of Biodiesel (말라카이트 그린의 색엷음 현상을 이용한 글리세롤의 정량: 바이오디젤 내 반응물 분석의 적용 가능성)

  • Lee, Mi-Hwa;Lee, Young-Chul;Shin, Hyun-Jae
    • KSBB Journal
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    • v.26 no.5
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    • pp.471-476
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    • 2011
  • Nowadays biodiesel (fatty acid methyl ester, FAME) has been becoming an important issue as a desired alternative of energy products because of non-toxic, biodegradable properties, and lower exhaust emissions. During esterification of fatty acids or transesterification of oils and fats with short chain alcohols by the alkali-catalyzed methanolysis, FAME and unrefined glycerol are generated. Quantification of glycerol as a by-product is important because of a determinant of biodiesel quality. However, the glycerol analysis by gas chromatography (GC) method has laborious works with sample preparation, long time and cost of sample analysis. Thus, there is a need to analyze glycerol more simply. Herein we demonstrate that the colorimetric assay for glycerol analysis conducted by UV-vis spectrophotometer at the wavelength 617 nm whose peak is maximum intensity of malachite green, resulting in the red-shift occurred proportionally as a function of glycerol amount. Thus, it is considered the solvent media for malachite green fading for biodiesel production: (1) water, (2) MeOH, and (3) EtOH. The resulting findings show that the peak intensity at 617 nm in glycerol-malachite green mixture had a relationship between glycerol concentration and degree of peak shift as increase in pure glycerol concentration approximately at pH 7.0. However, when it was measured the unrefined glycerol concentration by diluting and adjusting with water to buffer (pH 7.0), it was not observed the absorption peak at 617 nm because of impurities and OH ions. In case of glycerol from biodiesel production factories, glycerol concentration could be successfully measured.

A Study on the Microwave Electric-Field Focusing Waveguide Systems for Driving Plasma Visible Light (플라즈마 가시광 구동을 위한 초고주파 전계 집속형 도파관 시스템에 관한 연구)

  • Jeon, Hoo-Dong;Park, Eui-Joon
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.20 no.3
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    • pp.303-312
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    • 2009
  • In this study, a waveguide system for focusing the electric field is presented to emit the microwave-driven plasma visible light. This system consists of a magnetron for the microwave power supply, the waveguide section for power propagation, and the mesh-type cavity reactor. The quartz bulb containing a dose of sulfur powder and buffer gas Ar is located in the reactor, and forced by the strongly concentrated electric field for generating and exciting the sulfur plasma. That is, the conductor tips are loaded on each inner wall of the waveguide and the reactor, and then the plasma bulb is positioned between the tips, hence focusing the strong electric field on the bulb. Furthermore the waveguide section is designed for minimizing the degradations of matching characteristics according to the variations of the electrical conductivities of plasma at the transitory phase for plasma generation, hence providing the stable operation. Finally, the 2.45 GHz aluminum waveguide system is constructed, and then experiments for emitting the visible light are performed by using 400 W-class magnetron, showing the validity of designed system.

A Study on the Improvement of Voltage Measuring Method of 22.9 kV-y Distribution Lines (22.9 kV-y 배전선로의 전압계측방법 개선에 관한 연구)

  • Kil, Gyung-Suk;Song, Jae-Yong
    • Journal of Sensor Science and Technology
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    • v.7 no.4
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    • pp.293-299
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    • 1998
  • An objective of this study is to develop a voltage measuring device that uses a gas-filled switch (GS) on 22.9 kV-y extra-high voltage distribution lines. The voltage measuring device proposed in this paper is a kind of capacitive divider which consists of a detecting electrode attached outside of the bushing of GS, an impedance matching circuit, and a voltage buffer. It can be easily installed in an established GS without changing the structure. For the calibration and application investigations, the voltage measuring device was set up in the 25.8 kV 400 A GS, and a step pulse generator having 5 ns rise time is used. As a result, it was found that the frequency bandwidth of the voltage measuring device ranges from 1.35 Hz to about 13 MHz. The error of voltage dividing ratio which is evaluated by the commercial frequency voltage of 60 Hz was less than 0.2%. In addition, voltage dividing ratio in the commercial frequency voltage and in a non-oscillating impulse voltage were compared, and their deviation were less than 0.7%.

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Study on working gas ratio dependance of BST thin film (작업가스비에 따른 BST 박막의 특성)

  • Cui, Ming-Lu;Kwon, Hak-Yong;Park, In-Chul;Kim, Hong-Bae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07a
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    • pp.393-396
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    • 2004
  • 본 논문에서는 완충층용 MgO 박막을 P-type(100)Si 기판위에 작업가스 $Ar:O_2=80:20$, RF 파워 50W, 기판온도 $400^{\circ}C$, 10mtorr의 작업진공에서 $500{\AA}$ 증착하였다. 제작된 MgO/Si 기판위에 RF Magnetron sputtering법으로 작업가스 $Ar:O_2$의 비율을 90:10, 80:20, 70:30으로 변화하면서 $BST(Ba_{0.5}Sr_{0.5}TiO_3)$ 박막을 약 $2000{\AA}$ 증착하였다. XRD 측정결과 작업가스비의 변화에 관계없이(110)BST와 (111)BST 피크만이 관찰되었으며 작업가스 $Ar:O_2=80:20$에서 가장 양호한 결정성을 나타내었다. I-V 측정결과 인가전계 ${\pm}100kV/cm$에서 $10^{-7}A/cm^2$이하의 양호한 누설전류 특성을 보여주고 있으며 C-V 측정결과 작업가스 $Ar:O_2$의 비율 90:10, 80:20, 70:30에서의 비유전율은 각각 283, 305, 296으로서 작업가스비 80:20에서 제작된 박막의 특성이 가장 우수하였다. 작업가스비 80:20에서 제작된 박막의 SEM 측정결과 결정이 성장되었음을 확인할 수 있었고 그레인의 크기는 약 10nm였다.

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Stability Analysis of Concrete Plugs Installed in Pilot Tunnels for the Storage of Compressed Air (압축공기 저장용 파일롯 터널에 설치된 콘크리트 플러그의 안정성 해석)

  • Lee, Youn-Kyou;Song, Won-Kyoung;Park, Chul-Whan;Choi, Byung-Hee
    • Tunnel and Underground Space
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    • v.20 no.6
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    • pp.446-454
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    • 2010
  • CAES-G/T (Compressed Air Energy Storage - Gas Turbine) power generation is a likely option for the buffer facility stabilizing the fluctuation of the renewable powers, such as wind and solar powers. Considering the geological conditions, the underground CAES facility is most probable if the CAES-G/T generation is planed in Korea. In this kind of facility, a concrete plug is installed to seal the compressed air in the container, so that the selection of the shape and dimension of concrete plug could be a critical design factor. The stability evaluation of two types of plug was carried out by investigating the distribution of the factor of safety in the plugs and the distribution of contact pressure over the contact surface. The analysis result shows that the taper-shaped plug is more structurally stable than the wedge-shaped plug for the given geological condition. Possible separation of the rock-concrete interface around the spring line of the wedge-shaped plug is anticipated, which means the possible leakage of compressed air through the side wall and also means the poor mobilization of frictional resistance on that area.

Study of the Variation of Optical Amplification Characteristics with Incident Beam Size and Temperature of a Cesium-vapor-based Optical Amplifier (세슘 원자 증기 기반 광 증폭기의 온도와 빔 크기에 따른 광 증폭 특성 연구)

  • Ryu, Siheon;Jeong, Yujae;Yeom, Dong-Il
    • Korean Journal of Optics and Photonics
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    • v.32 no.6
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    • pp.306-313
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    • 2021
  • We study the amplification properties of an optical amplifier based on a cesium-vapor cell. An optical amplification system including cesium vapor mixed with a buffer gas is built, and its amplification feature is investigated as a function of the size of the incident beam and the temperature of the cesium-vapor cell. We observe that the optical amplification properties, such as amplification factor and extraction efficiency, change significantly depending on the temperature and beam diameter of the pump and seed light. A maximum extraction efficiency of 56% is obtained when the temperature of the cesium cell is 90 ℃, with a 200-㎛ diameter of the pump (500 mW) and seed light (10 mW). The numerical simulation of the amplification properties agrees reasonably with the results obtained from the experiment.

Mg/Al Impregnated Biochar for the Removal and Recovery of Phosphates and Nitrate

  • Kim, Dong-Jin
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2019.10a
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    • pp.134-134
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    • 2019
  • Utilization of organic waste as a renewable energy source is promising for sustainability and mitigation of climate change. Pyrolysis converts organic waste to gas, oil, and biochar by incomplete biomass combustion. Biochar is widely used as a soil conditioner and adsorbent. Biochar adsorbs/desorbs metals and ions depending on the soil environment and condition to act as a nutrient buffer in soils. Biochar is also regarded as a carbon storage by fixation of organic carbon. Phosphorus (P) and nitrogen (N) are strictly controlled in many wastewater treatment plants because it causes eutrophication in water bodies. P and N is removed by biological and chemical methods in wastewater treatment plants and transferred to sludge for disposal. On the other hand, P is an irreplaceable essential element for all living organisms and its resource (phosphate rock) is estimated about 100 years of economical mining. Therefore, P and N recovery from waste and wastewater is a critical issue for sustainable human society. For the purpose, intensive researches have been carried out to remove and recover P and N from waste and wastewater. Previous studies have shown that biochars can adsorb and desorbed phosphates implying that biochars could be a complementary fertilizer. However, most of the conventional biochar have limited capacity to adsorb phosphates and nitrate. Recent studies have focused on biochar impregnated with metal salts to improve phosphates and nitrate adsorption by synthesizing biochars with novel structures and surface properties. Metal salts and metal oxides have been used for the surface modification of biochars. If P removal is the only concern, P adsorption kinetics and capacity are the only important factors. If both of P and N removal and the application of recovery are concerned, however, P and N desorption characteristics and bioavailability are also critical factors to be considered. Most of the researches on impregnated biochars have focused on P removal efficiency and kinetics. In this study, coffee waste is thermally treated to produce biochar and it was impregnated with Mg/Al to enhance phosphates and nitrate adsorption/desorption and P bioavailability to increase its value as a fertilizer. Kinetics of phosphates and nitrate adsorption/desorption and bioavailability analysis were carried out to estimate its potential as a P and N removal adsorbent in wasewater and a fertilizer in soil.

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