• Restorative Dentistry and Endodontics
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• v.32 no.1
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• pp.9-18
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• 2007

The purposes of this study were to examine the variability of adhesive thickness on the different site of the cavity wall when used total-etch system without filler and simplified self-etch system with filler and to evaluate the relationship between variable adhesive thickness and microtensile bond strength to the cavity wall. A class I cavity in six human molars was prepared to expose all dentinal walls. Three teeth were bonded with a filled adhesive, $Clearfil^{TM}$ SE bond ana the other three teeth were bonded with unfilled adhesives, $Scotchbond^{TM}$ Multi Purpose. Morphology and thickness of adhesive layer were examined using fluorescence microscope. Bonding agent thickness was measured at three points along the axial cavity wall edge of cavity margin (rim). halfway down each cavity wall (h1f), internal angle of the cavity (ang). After reproducing the adhesive thickness at rim, h1f and ang, micro-tensile bond strength were evaluated. For both bonding agents, adhesive thickness of ang was significantly thicker than that of rim and h1f (P <0.05). As reproduced the adhesive thickness, microtensile bond strength was increased as adhesive thickness was increased in two bonding agents. Adhesive thickness of internal angle of the cavity was significantly thicker than that of the cavity margin and the halfway cavity wall for both bonding agents. Microtensile bond strength of the thick adhesive layer at the internal angle of the cavity was higher than that of the thin adhesive layer at 1,he cavity margin and the halfway cavity in the two bonding systems.

• Bulletin of the Korean Chemical Society
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• v.20 no.4
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• pp.445-450
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• 1999

Molecular dynamics (MD) simulation of non-rigid H-Y zeolite framework are performed at 298.15 and 5.0 K. Usual bond stretching, bond angle bending, torsional rotational, and non-bonded Lennard-Jones and electrostatic interactions are considered as intraframework interaction potentials. Calculated atomic parameters are in good agreement with the experiment, which indicates the successful reproduction of the framework structure and its motion. Both calculated bond lengths and bond angles are also in good agreement with the experiment except generally for a little longer bond lengths and a little smaller T-O-H bond angles. The calculated overall site occupation of HI keeps the order O(2) > O(3) > O(4) > O(t) at 298.15 K, which is very different from the experimental prediction, O(l) > O(3) > O(2) at 5 K. Calculated IR spectra of the H-Y zeolite framework show that most of the main peaks of the O-H bonds are in the broad region 3700-5000 cm-1 and that the O-T stretching bands appeared in 0-2000 cm-1 and at 2700 cm-1

• Journal of Technologic Dentistry
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• v.41 no.3
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• pp.203-209
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• 2019

Purpose: The purpose of this study was to investigate the mechanical properties of polymer prosthetic and restorative materials for dental CAD/CAM using two test method; surface characteristics and shear bond strength. Methods: Commercialized CAD/CAM polymer blanks were investigated; One kinds of PMMA, and one PEKK blanks. A total of 20 PMMA and PEKK specimens were prepared, and each group was divided into 10 specimens. Average surface roughness was observed under surface profilometer. The contact angle was measured with a surface electrooptics. The bond strength was evaluated by a universal testing machine at a crosshead speed of 5mm/min. The data were statistically analyzed using independent t-test and Fisher's exact test(P<0.05). Results: The PMMA and PEKK group showed a significant difference in the shear bond strength with the composite resin(P<0.05). The surface roughness of the PEKK group was higher than that of the PMMA group. The fracture mode were observed in PEKK groups with 50% showing adhesive remnant index score. Conclusion: PEEK is used as substructure material and composite veneering material is applied. PEKK resins will contribute to the development of successful products that will provide structural and aesthetic satisfaction.

• Structural Engineering and Mechanics
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• v.75 no.3
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• pp.339-356
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• 2020

In this article, a developed bond-based peridynamic model for functionally graded materials (FGMs) is proposed to simulate the dynamic fracture behaviors in FGMs. In the developed bond-based peridynamic model for FGMs, bonds are categorized into three different types, including transverse directionally peridynamic bond, gradient directionally peridynamic bond and arbitrary directionally peridynamic bond, according to the geometrical relationship between directions of peridynamic bonds and gradient bonds in FGMs. The peridynamic micromodulus in the gradient directionally and arbitrary directionally peridynamic bonds can be determined using the weighted projection method. Firstly, the standard bond-based peridynamic simulations of crack propagation and branching in the homogeneous PMMA plate are performed for validations, and the results are in good agreement with the previous experimental observations and the previous phase-field numerical results. Then, the numerical study of crack initiation, propagation and branching in FGMs are conducted using the developed bond-based peridynamic model, and the influence of gradient direction on the dynamic fracture behaviors, such as crack patterns and crack tip propagation speed, in FGMs is systematically studied. Finally, numerical results reveal that crack branching in FGMs under dynamic loading conditions is easier to occur as the gradient angle decreases, which is measured by the gradient direction and direction of the initial crack.

• Journal of Dental Rehabilitation and Applied Science
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• v.25 no.4
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• pp.403-415
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• 2009

The purpose of the study is to establish the effect of different abutment shapes and types of cements on the retention of the full veneer casted gold crowns. Metal dies that has the similar shape with the implant abutment were manufactured using a short(5mm) and long(10mm) dies with different convergence angles. Metal dies and gold crowns, which were made from the metal dies, were cemented with Temp-bond, Temp-bond mixed with petroleum jelly, ZPC and Premier implant cement. After that, these were tested for tensile force at the point of separation. The effect of convergence angle changes of different cement types on the retention was studied as well as the effects of the cement type changes with different convergence angles on the retention. In addition, study about the marginal gap of Premier implant cement used for this experiment was conducted. The results are as followed under the in-vitro experimental limits; 1. The retention of the Temp-bond mixed with petroleum jelly decreased as the convergence angle increased, and the retention was weakest among the cements. 2. The retention of ZPC decreased as convergence angle increased. When convergence angle was 5 degrees, ZPC showed stronger retention than Premier implant cement. 3. Premier implant cement had the weakest retention when the convergence angle was 5 degrees but when the convergence angle was 10 degrees, it had the strongest retention. As the angle increased more than 10 degrees, the retention decreased. 4. Premier implant cement showed bigger marginal gap when the convergence angle was 5 degrees than 10 degrees under the experimental condition.

• Journal of the Korea institute for structural maintenance and inspection
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• v.18 no.2
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• pp.38-46
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• 2014

Effects of various parameters on bond property between reinforcing bar and concrete are investigated in many researchers, and various study is on going to improve the bond strength. Properties of interface between reinforcement and concrete is important role in bond property. This study analyzed the interfacial bond mechanism between deformed bar and concrete by finite element analysis (FEA) to evaluate the effect of rib shape. The FEA model in this study is simplified 2D plane stress model. The variables of analysis are selected by rib angle, rib height, rib spacing and relative rib area. From the results of analysis, reinforcing bars with rib angle $30{\sim}60^{\circ}$ showed better bond strength than the others. Bond strength ratio following to the rib height is proportionally increased up to the $0.12d_b$, but rib spacing has little effect on bond strength. The results also indicated that relative rib area can be efficiently represented the properties of deformed shape in reinforcing bars, and zigzagged rib height shape showed excellent bond strength increase.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05a
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• pp.278-281
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• 2006

The aims of this study are to investigate rib geometries of reinforcing bars commercially available in Korea, Japan and USA, and evaluate bond performance using beam-end test specimens. Measurement of rib geometries of the bars include nominal area, average distance of rib, height of rib and an angle of rib perpendicular to bar axis. The result of this study show that rib height of Korean reinforcement bars are much less than those of Japan and USA resulting in the lowest value of relative rib area. Average bond strength of Korean D25 deformed bars is known as 9 % less than that of bars produced in USA. Bond strength depends primarily on the relative rib area. Bond strength of the high relative rib area bars produced in USA show 18% higher than that of bars produced in Korea.

• Proceedings of the Korea Concrete Institute Conference
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• 2010.05a
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• pp.51-52
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• 2010

The effect of bond strength of longitudinal reinforcing bars on shear strength of reinforced concrete beams is investigated from the view point of arch and truss actions. Stress fields with bond allow us identify possible failure modes including bond failure of a deep beam as well as a slender beam. The slope angle of diagonal compression fields is interpreted as balanced failures of two components involved for shear transfer.

• Korean Journal of Crystallography
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• v.16 no.1
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• pp.1-5
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• 2005

The structure of the title compound has been determined by single-crystal X-ray diffraction work. The crystals are orthorhombic, space group $Pna2_1$ with a=11.095(3), b=21.834(7), c=12.574(4) $\AA$, and R1=0.0667. The average carbon bond length in aromaticity In the molecule is 1.386(1) $\AA$ and the average single bond length linking the central benEene ring and peripheral phenyl rings is 1.491(3) $\AA$. The average dihedral angle between the central benzene ring and each of six peripheral phenyl rings is $67.1(1)^{\circ}$ and the average dihedral angle between neighboring two phenyl rings is $55.0(1)^{\circ}$. Thus the molecule adopts a quasi-propeller configuration with approximate six-fold rotation symmetry.

• Journal of the Korean Magnetics Society
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• v.15 no.6
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• pp.299-302
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• 2005

We investigated the structural md magnetic properties of Fe-Pt nanowires with linear and zigzag structures by using first-principle calculational methods. Structural degrees of freedom are optimized, the bond lengths and bond angles are determined, magnetic moments, spin density, and density of states are calculated. Results show that the zigzag structure is more stable than the linear one, and has a longer bond length and smaller magnetic moments for both Fe and Pt atoms.