Hexaphenylbenzene $C_6(C_6H_5)_6$

  • Kim Young-Sang (Department of Material Chemistry, Korea University) ;
  • Ko Jaejung (Department of Material Chemistry, Korea University) ;
  • Kang Sang Ook (Department of Material Chemistry, Korea University) ;
  • Han Won-Sik (Department of Material Chemistry, Korea University) ;
  • Jeong Jae-Ho (Department of Material Chemistry, Korea University) ;
  • Suh Il-Hwan (Department of Material Chemistry, Korea University)
  • Published : 2005.06.01

Abstract

The structure of the title compound has been determined by single-crystal X-ray diffraction work. The crystals are orthorhombic, space group $Pna2_1$ with a=11.095(3), b=21.834(7), c=12.574(4) $\AA$, and R1=0.0667. The average carbon bond length in aromaticity In the molecule is 1.386(1) $\AA$ and the average single bond length linking the central benEene ring and peripheral phenyl rings is 1.491(3) $\AA$. The average dihedral angle between the central benzene ring and each of six peripheral phenyl rings is $67.1(1)^{\circ}$ and the average dihedral angle between neighboring two phenyl rings is $55.0(1)^{\circ}$. Thus the molecule adopts a quasi-propeller configuration with approximate six-fold rotation symmetry.

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References

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