• Journal of Korean Society of Water and Wastewater
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• v.14 no.1
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• pp.108-116
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• 2000

Chlorine is widely used as a disinfectant in drinking-water systems throughout the world. Chlorine residual was used as an indicator for prediction of water quality in water distribution systems. The variation of chlorine residual in drinking water distribution systems of Suwon city was simulated using EPANET. EPANET is a computerized simulation model which predicts the dynamic hydraulic and water quality behavior within a water distribution system operating over an extended time period. Sampling and analysis were performed to calibrated the computer model in 1999 (Aug. Summer). Water quality variables used in simulations are temperature, roughness coefficient, pipe diameter, pipe length, water demand, velocity and so on. Extended water residence time affected water quality due to the extended reaction time in some areas. All area showed the higher concentration of chlorine residual than 0.2mg/l(standard). So it can be concluded that any area in Suwon city is not in biological regrowth problem. Rechlorination turned out to be an useful method for uniform concentration of free chlorine residual in distribution system. The cost of disinfectant could be saved remarkably by cutting down the initial chlorine concentration to the level which guarantees minimum concentration (0.2mg/l) throughout the distribution system.

• 한국연소학회:학술대회논문집
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• 2001.11a
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• pp.137-141
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• 2001

The behavior of Cl is important to prevent HCl exhausted by incineration of RDF. Because RDF is composed of municipal wastes, its calorific value is very various. Thus components of RDF are to be analyzed and elemental analyze and calorific value are to be done. And in order to find the behavior of Cl during RDF combustion, Cl included in exhaust gas and ash is captured and analyzed. RDF which made by municipal and $Ca(OH)_2$ with regular ratio(Ca/0.5Cl) is incinerated in fluidized bed combustor. Cl included in exhaust gas and fly ash is captured and analyzed. Finally the change of Cl concentration included in exhaust gas and ash is analyzed and the behavior of Cl is investigated.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.30 no.3
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• pp.1-6
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• 1998

Elementally Chlorine Free (ECF) bleaching will be superior than Totally Chlorine free (TCF) bleaching, not only because they have no significant difference in effluent toxicity, but also those pulps bleached by ECF have higher brightness, strength, yield, etc., over those by TCF. With this belief, this paper focused on the chemistry of chlorine dioxide decomposition and ionization, both in water solution and in pulp slurry. Special attention was paid to chlorate ion because there have been controversies as how it is formed and what its behavior to the end pH of pulp bleaching is. As a result, during ionization of chlorine dioxide with water, both chlorate and chlorite were found to increase with increasing pH, but during ionization with pulp, chlorite was found to increase with end pH while chlorate decreased with increasing end pH. In the case of ionization with water, the disproportion equation $2CIO_2 + OH^{-} \lightarrow H_2O + CIO_3^{-} + CIO_2^{-}$ was thought to become the main reaction with the increasing pH, while in the case of ionization with pulp, the reaction $HCIO + CIO_2^{-}\lightarow H^{+} + Cl^{-} + CIO_3^{-}$ was the main reaction contributing to the formation of chlorate. Based on this above opinion, the contrary results of chlorine dioxide ionization from different researchers were discussed and explained.

• Korean journal of applied entomology
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• v.55 no.1
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• pp.27-33
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• 2016

Chlorine dioxide has been used as a disinfectant against microbial pathogens. Recently, its insecticidal activity has been known against stored insect pests by oxidative stress. However, any molecular target of the oxidative stress induced by chlorine dioxide has been not known in insects. This study assessed an enzyme activity of acetylcholinesterase (AChE) as a molecular target of chlorine dioxide in the Indianmeal moth, Plodia interpunctella. AChE activities were varied among developmental stages of P. interpunctella. Injection of chlorine dioxide with lethality-causing doses significantly increased AChE activity of the fifth instar larvae of P. interpunctella. Exposure of the larvae to chlorine dioxide fumigant also significantly increased AChE activity. The fifth instar larvae of P. interpunctella exhibited a negative phototaxis. However, chlorine dioxide treatment significantly interrupted the innate behavior. These results suggest that AChE is one of molecular targets of oxidative stress due to chlorine dioxide in P. interpunctella.

• New & Renewable Energy
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• v.4 no.2
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• pp.81-86
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• 2008

Rotary kiln in cement work has been evaluated for a wide variety of organic wastes such as wood, used tyres, plastic wastes and automobile shredder residue (ASR). However the presence of chlorine hampers the use of ASR as fuel in rotary kiln. Therefore, the behavior characteristics of chlorine components in rotary kiln should be considered to develop an effective method for ASR treatment to recovery energy resources. The aim of this paper is to present the chlorine control system applied to a cement manufacturing process for ASR use as an alternative fuel. In this work, the simulation of bypass unit and cyclones for chlorine control in rotary kiln has been studied and compared with the operation results of field test.

• Elastomers and Composites
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• v.48 no.2
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• pp.161-166
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• 2013

Thermal degradation behavior of chlorine cure-site ACM and carboxylic cure-site ACM rubbers was studied by non-isothermal TGA thermal analysis. Carboxylic cure-site ACM rubber exhibited comparatively more thermally stable than chlorine cure-site ACM, showing higher peak temperature, at which maximum reaction rate occurred. Activation energies from Kissinger method were calculated as 118.6 kJ/mol for the chlorine cure-site ACM and 105.5 kJ/mol for the carboxylic cure-site ACM, showing similar values from Flynn-Wall-Ozawa analysis over the conversion range of 0.1~0.2. From the analysis of the reaction order change, both samples seemed thermally decomposed through the multiple reaction mechanism as is the common rubber materials.

• Journal of Korean Society on Water Environment
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• v.21 no.1
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• pp.52-58
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• 2005

The assessment on characteristics of hydraulic behavior and water quality variations of underground reservoirs of buildings were studied. Firstly, it was thought that underground reservoir capacities($m^3$) of buildings should be not determinated by the uniform and same methods but be estimated on the basis of the dwelling areas on dominated households and their residential characteristics, because these characteristics influence significantly on actual water usages and patterns of buildings. Secondly, it was likely that the average reduction rate of residual chlorine in underground reservoirs were affected from the their capacities, because the average reduction rate of residual chlorine in underground reservoirs under $1,000m^3$ was 43 percent, on the other hand, that rate of underground reservoirs over $1,000m^3$ was 60 percent. Thirdly, through the field investigation, the retention time of drinking water in underground reservoirs were in the range from 0.3 day to 3.9 day. In addition to, the average reduction rate of residual chlorine were depended largely on the retention time of drinking water. When the retention time was under 24 hours, the average reduction rate of residual chlorine was 45 percent, and in case of over 24 hours, was 49 percent. Fourth, water level in underground reservoirs was averagely varied in the range from 0.1 m to 2.65 m at the height of underground reservoirs. If considered actual height of underground reservoirs, 37.6 percent of the height of underground reservoirs was only used. Consequently, the frequency of the inflow and outflow of drinking water in underground reservoir were very increased, and had an effect on the reduction of residual chlorine. Lastly, the investigations on hydraulic structure characteristics of underground reservoirs inside showed the locations of inflow and outflow of drinking water almost were in the opposite direction. And some buildings had several baffles in the middle. Nevertheless, their installations had no beneficial for the improvement of water quality.

• Resources Recycling
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• v.6 no.1
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• pp.35-39
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• 1997

This study was carried out to find the existing forms of chlorlnc in EM dust and to understand the valaliliratian behavior and the removal of chlorine from EAF dust with lemperalure and heating almosphere The chemical compositions of dust A are 27.3%Fe. 21.8%3Zn, 3 15%Pb, 3 51%C1 and that of dust B BE 33.92%Fe, 15.94%Zn, 2.73% Pb, 3.98%Cl. The XRD analysis and water leaching test shows that chlorlne in EM dust exist mainly as NaCI, KCI, Pb (0H)Cl. Above 99% of chlorine was volatilized when dust was hentcd in alr atmosphere at 1100$^{\circ}$C h r 1 hour and that was 96% when heated in reduction atmosnherc at 1100$^{\circ}$C for 1 hour.

• Journal of Korean Society of Water and Wastewater
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• v.26 no.5
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• pp.685-692
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• 2012

UV technology is widely used in water and wastewater treatment. Many researches have been conducted on microbial disinfection and micro pollutant reduction with UV treatment. However, the study on NOM with UV has limited because low/medium pressure UV lamp is not sufficient to affect refractory organics such as NOM. Pulsed UV treatment using UV flash lamp can be operated in the pulsed mode with much greater peak intensity. The pulse duration is typically in microseconds, whereas the interval between pulses is in the order of milliseconds. The high intensity of pulsed UV would mineralize NOM itself as well as change the characteristics of NOM. Chlorine demand and DBPs formation is affected on the changed amounts and properties of NOM. The objective of this study is to investigate the effect on NOM, chlorine residual, and chlorinated DBPs formation with pulsed UV treatment.

• Journal of Korean Society of Disaster and Security
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• v.9 no.2
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• pp.63-75
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• 2016

For safe water supply, residual chlorine has to be maintained in tap-water above a certain level from drinking water treatment plants to the final tap-water end-point. However, according to the current literature, approximately 30-60% of residual chlorine is being lost during the whole water supply pathways. The losses of residual chlorine may have been attributed to the current tendency for water supply managers to reduce chlorine dosage in drinking water treatment plants, aqueous phase decomposition of residual chlorine in supply pipes, accelerated chlorine decomposition at a high temperature during summer, leakage or losses of residual chlorine from old water supply pipes, and disappearances of residual chlorine in water storage tanks. Because of these, it is difficult to rule out the possibility that residual chlorine concentrations become lower than a regulatory level. In addition, it is concerned that the regulatory satisfaction of residual chlorine in water storage tanks can not always be guaranteed by using the current design method in which only storage capacity and/or hydraulic retention time are simply used as design factors, without considering other physico-chemical processes involved in chlorine disappearances in water storage tank. To circumvent the limitations of the current design method, mathematical models for aqueous chlorine decomposition, sorption of chlorine into wall surface, and mass-transfer into air-phase via evaporation were selected from literature, and residual chlorine reduction behavior in water storage tanks was numerically simulated. The model simulation revealed that the major factors influencing residual chlorine disappearances in water storage tanks are the water quality (organic pollutant concentration) of tap-water entering into a storage tank, the hydraulic dispersion developed by inflow of tap-water into a water storage tank, and sorption capacity onto the wall of a water storage tank. The findings from his work provide useful information in developing novel design and technology for minimizing residual chlorine disappearances in water storage tanks.