• Clean Technology
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• v.19 no.2
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• pp.128-133
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• 2013

Catalytic combustion of benzene over $CeO_2$-supported copper oxides has been investigated. The supported copper oxides catalysts were prepared using ball mill method and characterized by XRD, FT-IR, TEM and TPR. In the CuO/$CeO_2$ catalysts prepared using ball mill method, highly dispersed copper oxide species were shown at high loading ratio. The CuO/$CeO_2$ prepared using ball mill method showed the higher activity than those prepared using impregnation method. The catalytic activity increased with an increase in the CuO loading ratio, 10 wt% loaded CuO/$CeO_2$ catalyst giving the highest activity. In addition, the promoting of 10 wt% loaded CuO/$CeO_2$ catalyst with $Fe_2O_3$ and CoO enhanced the dispersion of CuO and then increased the catalytic activity.

• Korean Journal of Materials Research
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• v.31 no.5
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• pp.286-295
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• 2021

This study attempts to find optimal conditions of the friction coefficient using a discrete element method (DEM) simulation with various friction coefficient conditions and three different grinding media with various ball sizes in a traditional ball mill (TBM). Using ball motion of the DEM simulation are obtained using the optimal friction coefficient compared with actual motion; photographs are taken by the digital camera and the snapshot images are analyzed. In the simulation, the rotation speed of the mill, the materials and velocity of the grinding media, and the friction coefficient between the balls and the wall of the pot are fixed as the actual experimental conditions. We observe the velocity according to the friction coefficient from the DEM simulation. The friction coefficient is found to increase with the velocity. Milling experiments using a traditional ball mill with the same experimental conditions as those of the DEM simulation are conducted to verify the simulated results. In addition, particle morphology change of copper powder is investigated and analyzed using scanning electron microscopy (SEM) for the milling experiment.

• Korean Journal of Materials Research
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• v.26 no.11
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• pp.611-622
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• 2016

Particle morphology change and different experimental condition analysis during composite fabrication process by traditional ball milling with discrete element method (DEM) simulation were investigated. A simulation of the three dimensional motion of balls in a traditional ball mill for research on the grinding mechanism was carried out by DEM simulation. We studied the motion of the balls, the ball behavior energy and velocity; the forces acting on the balls were calculated using traditional ball milling as simulated by DEM. The effect of the operational variables such as the rotational speed, ball material and size on the flow velocity, collision force and total impact energy were analyzed. The results showed that increased rotation speed with interaction impact energy between balls and balls, balls and pots and walls and balls. The rotation speed increases with an increase of the impact energy. Experiments were conducted to quantify the grinding performance under the same conditions. Furthermore, the results showed that ball motion affects the particle morphology, which changed from irregular type to plate type with increasing rotation speed. The evolution was also found to depend on the impact energy increase of the grinding media. These findings are useful to understand and optimize the particle motion and grinding behavior of traditional ball mills.

• Korean Journal of Materials Research
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• v.23 no.11
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• pp.625-630
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• 2013

In this study, intermediate-mixed powders were prepared by loading zirconia powders initially in a ball-mill jar and loading alumina powders afterward; the initial-mixed powders were produced by loading zirconia and alumina powders together in the ball-mill jar. The effect of such differences in mixing method on the mechanical properties was investigated. In intermediate-mixed powders, the volume fraction of large particles slightly increased and, simultaneously, zirconia particles formed agglomerates that, due to early ball-mill loading of the zirconia powders only, were more dispersed than were the initial-mixed powders. For the intermediate-mixed powders, zirconia agglomerates were destroyed more quickly than were initial-mixed powders, so the number of dispersed zirconia particles rose and the inhibitory effect of densification due to the addition of a second phase was more obvious. In the microstructure of intermediate-mixed powders, zirconia grains were homogeneously dispersed and grain growth by coalescence was found to occur with increasing sintering temperature. For the initial-mixed powders, large zirconia grains formed by localized early-densification on the inside contacts of some zirconia agglomerates were observed in the early stages of sintering. The intermediate-mixed powders had slightly lower hardness values as a whole but higher fracture toughness compared to that of the initial-mixed powders.

• Korean Journal of Materials Research
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• v.28 no.3
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• pp.148-158
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• 2018

This study investigated the effect of the grinding media of a ball mill under various conditions on the raw material of copper powder during the milling process with a simulation of the discrete element method. Using the simulation of the three-dimensional motion of the grinding media in the stirred ball mill, we researched the grinding mechanism to calculate the force, kinetic energy, and medium velocity of the grinding media. The grinding behavior of the copper powder was investigated by scanning electron microscopy. We found that the particle size increased with an increasing rotation speed and milling time, and the particle morphology of the copper powder became more of a plate type. Nevertheless, the particle morphology slightly depended on the different grinding media of the ball mill. Moreover, the simulation results showed that rotation speed and ball size increased with the force and energy.

• Korean Chemical Engineering Research
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• v.55 no.4
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• pp.456-466
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• 2017

This work investigated the particle morphology change to difference in milling media in a metal based composite fabrication process using a stirred ball mill with ball behavior of DEM simulation. A simulation of the three dimensional motion of grinding media in the stirred ball mill for the research of grinding mechanism to clarify the force, kinetic energy, and medium velocity of grinding media were calculated. In addition, the rotational speed of the stirred ball mill was changed to the experimental conditions for the composite fabrication, and change of the input energy was also calculated while changing the ball material, the flow velocity, and the friction coefficient under the same conditions. As the rotating speed of the stirred ball mill increased, the impact energy between the grinding media to media, media to wall, and media and the stirrer increased quantitatively. Also, we could clearly analyze the change of the particle morphology under the same experimental conditions, and it was found that the ball behavior greatly influences in the particle morphology changes.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.19 no.12
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• pp.98-104
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• 2020

In this work, a study on the 5-axis machining of ball gear cam is conducted which is a continuation of reference [1]. The ball gear cam used in this study delivers motion in conjunction with the ball supported by the turret. Therefore, it requires carbonizing heat treatment and is usually completed using a 4-axis machining with a carbide ball end mill. If the nose part of the ball end mill is not allowed to participate in the machining, then CBN tools without the nose part can be used. However, machining of certain shapes can be carried out only by contacting the ball in some of the areas on either side which can improve the surface of the machining. This requires a 5-axis machining in order to maintain a constant angle for the processing path. Therefore, in this work, the 5-axis machining method is studied in order to maintain the direction of the cutter axis at a constant angle with the tangent direction of the curve-ball gear cam. Furthermore, the 5-axis machining program for the ball gear cam was developed and the machining experiment was completed and verified.

• Korean Journal of Materials Research
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• v.28 no.10
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• pp.539-543
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• 2018

We report the structural, morphological and magnetic properties of the $Ni_{70}Mn_{30}$ alloy prepared by Planetary Ball Mill method. Keeping the milling time constant for 30 h, the effect of different ball milling speeds on the synthesis and magnetic properties of the samples was thoroughly investigated. A remarkable variation in the morphology and average particle size was observed with the increase in milling speed. For the samples ball milled at 200 and 300 rpm, the average particle size and hence magnetization were decreased due to the increased lattice strain, distortion and surface effects which became prominent due to the increase in the thickness of the outer magnetically dead layer. For the samples ball milled at 400, 500 and 600 rpm however, the average particle size and hence magnetization were increased. This increased magnetization was attributed to the reduced surface area to volume ratio that ultimately led to the enhanced ferromagnetic interactions. The maximum saturation magnetization (75 emu/g at 1 T applied field) observed for the sample ball milled at 600 rpm and the low value of coercivity makes this material useful as soft magnetic material.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.19 no.4
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• pp.71-78
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• 2020

The rotary feed axes of a 5-axis machine tool can increase the freedom of the tool posture, while reducing feed speed and rigidity. In addition, as a ball-end mill is inevitably used during machining by rotational feed, the step-over length is reduced compared to the flat-end mill, thereby reducing the material removal rate. Therefore, this study attempts to improve the material removal rate, feed speed, and machining stability using the corner radius flat-end mill and a fixed controlled machining method for the rotary feed axes during roughing. In addition, the tapered ball-end mill and simultaneously controlled machining method for the rotary feed axes were used for finishing to improve the propeller's 5-axis machining efficiency by enhancing the surface quality. In order to create the tool path effectively and easily, we propose a specific approach for using the propeller's geometric properties and evaluate the effectiveness of the proposed method by comparing it with the method of the dedicated module.

• Journal of Industrial Technology
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• v.25 no.B
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• pp.127-133
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• 2005

Manufacturing methods of Nano particles can be distinguished by top-down technology as physical method and bottom-up technology as chemical synthetic method. Top-down technology is a kind of method for making microstructure as like carving after forming a macroscopic structure in advance and its typical methods are ball milling, gas condensation method and so on. Nano Particles synthesized by bottom-up method have got to do dispersing process for using them as actual nano particles because their viscosity are very strong and so easy to shape cohesive substances. Therefore, this study is about a particle separating device which separates a certain constant size of grains processed already in mill and mixer because we mostly use media agitating mill as a device of milling and dispersing and we necessarily use very slight balls as media for manufacturing nano particles in the machine. The centrifugal device has been designed for passing and separating below a certain type of grain size after final process of particles in the mill.