• Resources Recycling
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• v.15 no.4 s.72
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• pp.44-51
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• 2006

Most electric arc furnace dust (EAFD) treatment processes to recover zinc from EAFD employ carbon as a reducing agent for the zinc oxide in the EAFD. In the present work, the reduction reaction of zinc oxide with carbon in the present of iron oxide was kinetically studied. The experiments were carried out at temperatures between 1173 K and 1373 K under nitrogen atmosphere using a weight-loss technique. From the experimental results, it was concluded that adding the proper amount of iron oxide to the reactant accelerates the reaction rate of zinc oxide with carbon. This is because iron oxide in the reduction reaction of zinc oxide with carbon promotes the carbon gasification reaction. The spherical shrinking core model for a surface chemical reaction control was found to be useful in describing kinetics of the reaction over the entire temperature range. The reaction has an activation energy of 53 kcal/mol (224 kJ/mol) for ZnO-C reaction system, an activation energy of 42 kcal/mol (175 kJ/mol) for $ZnO-Fe_{2}O_{3}-C$ reaction system, and an activation energy of 44 kcal/mol (184 kJ/mol) for ZnO-mill scale-C reaction system.

• Korean Journal of Remote Sensing
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• v.24 no.6
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• pp.535-549
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• 2008

Vicarious calibration for the satellite sensor relies on simulated TOA (Top-of-Atmosphere) radiances over various targets. In this study, TOA visible radiance was calculated over ocean targets which are located in five different regions over the Indian and Pacific ocean, and its possible use for the satellite sensor calibration was examined. TOA radiances are simulated with the 6S radiative transfer model for the comparison with MODIS/Terra and SeaWiFS measurements. Geometric angles and sensor characteristics of the reference satellites were taken into account for the simulation. AOT (Aerosol Optical Thickness) from MODIS/Terra, pigment concentrations from Sea WiFS, and ozone amount from OMI measurements were used as inputs to the model. Other atmospheric input parameters such as surface wind and total column water vapor were taken from NCEP/NCAR reanalysis data. The 5-day averaged radiances over all targets show that the percent differences between simulated and observed radiances are within about ${\pm}5%$ in year 2005, indicating that the calculated radiances are in good agreement with satellite measurements. It has also been shown that the algorithm can produce the SeaWiFS radiances within about ${\pm}5%$ uncertainty range. It has been suggested that the algorithm can be used as a tool for calibrating the VIS bands within about 5% uncertainty range.

• Journal of Environmental Health Sciences
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• v.47 no.2
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• pp.155-165
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• 2021

Objectives: Acute exposure to high concentrations of chemicals can occur when a chemical accident takes place. As such exposure can cause ongoing environmental pollution, such as in the soil and groundwater, there is a need for a tool that can assess health effects in the long term. The purpose of this study was assessing the health risks of residents living near a chemical accident site due to long-term exposure while considering the temporal concentration changes of the toxic chemicals leaked during the accident until their extinction in the environment using a multimedia environmental dynamics model. Methods: A health risk assessment was conducted on three cases of formaldehyde chemical accidents. In this study, health risk assessment was performed using a multimedia environmental dynamics model that considers the behavior of the atmosphere, soil, and water. In addition, the extinction period of formaldehyde in the environment was regarded as extinction in the environment when the concentration in the air and soil fell below the background concentration prior to the accident. The subjects of health risk assessment were classified into four groups according to age: 0-9 years old, 10-18 years old, 19-64 years old, and over 65 years old. Carcinogenic risk assessment by respiratory exposure and non-carcinogenic risk assessment by soil intake were conducted as well. Results: In the assessment of carcinogenic risk due to respiratory exposure, the excess carcinogenic risk did not exceed 1.0×10-6 in all three chemical accidents, so there was no health effect due to the formaldehyde chemical accident. As a result of the evaluation of non-carcinogenic risk due to soil intake, none of the three chemical accidents had a risk index of 1, so there was no health effect. For all three chemical accidents, the excess cancer risk and hazard index were the highest in the age group 0-9. Next, 10-18 years old, 65 years old or older, and 19-64 years old showed the highest risk. Conclusion: This study considers environmental changes after a chemical accident occurs and until the substance disappears from the environment. It also conducts a health risk assessment by reflecting the characteristics of the long-term persistence and concentration change over time. It is thought that it is of significance as a health risk assessment study reflecting the exposure characteristics of the accident substance for an actual chemical accident.

• Atmosphere
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• v.28 no.4
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• pp.369-382
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• 2018

Planetary boundary layer height (PBLH), produced by the Local Data Assimilation and Prediction System (LDAPS), was verified using RawinSonde (RS) data obtained from observation at Daegwallyeong (DGW) and Sokcho (SCW) during the International Collaborative Experiments for Pyeongchang 2018 Olympic and Paralympic winter games (ICE-POP 2018). The PBLH was calculated using RS data by applying the bulk Richardson number and the parcel method. This calculated PBLH was then compared to the values produced by LDAPS. The PBLH simulations for DGW and SCW were generally underestimation. However, the PBLH was an overestimation from surface to 200 m and 450 m at DGW and SCW, respectively; this result of model's failure to correctly simulate the Surface Boundary Layer (SBL) and the Mixing Layer (ML) as the PBLH. When the accuracy of the PBLH simulation is low, large errors are seen in the mid- and low-level humidity. The highest frequencies of Planetary boundary layer (PBL) types, calculated by the LDAPS at DGW and SCW, were presented as types Ι and II, respectively. Analysis of meteorological factors according to the PBL types indicate that the PBLH of the existing stratocumulus were overestimated when the mid- and low-level humidity errors were large. If the instabilities of the surface and vertical mixing into clouds are considered important factors affecting the estimation of PBLH into model, then mid- and low-level humidity should also be considered important factors influencing PBLH simulation performance.

• Korean Journal of Remote Sensing
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• v.34 no.6_1
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• pp.925-939
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• 2018

Absorbed shortwave radiation at the surface is an important component of energy analysis among the atmosphere, land, and ocean. In this study, the absorbed shortwave radiation was calculated using a radiation model and surface broadband albedo data for application to Geostationary Earth Orbit Korea Multi-Purpose SATellite (GEO-KOMPSAT-2A; GK-2A). And the results (GWNU algorithm) were compared with CERES data and calculation results using pyranometer and MODIS (Moderate Resolution Imaging Spectroradiometer) data to be selected as the reference absorbed shortwave radiation. This GWNU algorithm was also compared with the physical and statistical algorithms of GOSE-R ABI and two algorithms (Li et al., 1993; Kim and Jeong, 2016) using regression equation. As a result, the absorbed shortwave radiation calculated by GWNU algorithm was more accurate than the values calculated by the other algorithms. However, if the problem about computing time and accuracy of albedo data arise when absorbed shortwave radiation is calculated by GWNU algorithm, then the empirical algorithms explained above should be used with GWNU algorithm.

• Journal of the Korean Association of Geographic Information Studies
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• v.21 no.4
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• pp.158-174
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• 2018

The leaf area index (LAI) is a major factor explaining the photosynthesis of vegetation, evapotranspiration, and energy exchange between the earth surface and atmosphere, and there have been studies on accurate and applicable LAI estimation methods. This study aimed to investigate the relationship between the actual LAI data, UAV image-based vegetation index, canopy height and satellite image (Sentinel-2) LAI and to present an effective LAI estimation method using UAV. As a result, among the six vegetation indices in this study, NDRE ($R^2=0.496$) and CIRE ($R^2=0.443$), which contained red-edge band, showed a high correlation. The application of the canopy height model data to the vegetation index improved the explanatory power of the LAI. In addition, in the case of NDVI, the saturation problem caused by the linear relationship with LAI was addressed. In this study, it was possible to estimate high resolution LAI using UAV images. It is expected that the applicability of such data will be improved if calibration and correction steps are carried out for various vegetation and seasonal images.

• Atmosphere
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• v.29 no.3
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• pp.257-267
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• 2019

This study is to assess the applicability of the Extreme Forecast Index (EFI) algorithm of the ECMWF seasonal forecast system to the Global Seasonal Forecasting System version 5 (GloSea5), operational seasonal forecast system of the Korea Meteorological Administration (KMA). The EFI is based on the difference between Cumulative Distribution Function (CDF) curves of the model's climate data and the current ensemble forecast distribution, which is essential to diagnose the predictability in the extreme cases. To investigate its applicability, the experiment was conducted during the heat-wave cases (the year of 1994 and 2003) and compared GloSea5 hindcast data based EFI with anomaly data of ERA-Interim. The data also used to determine quantitative estimates of Probability Of Detection (POD), False Alarm Ratio (FAR), and spatial pattern correlation. The results showed that the area of ERA-Interim indicating above 4-degree temperature corresponded to the area of EFI 0.8 and above. POD showed high ratio (0.7 and 0.9, respectively), when ERA-Interim anomaly data were the highest (on Jul. 11, 1994 (> $5^{\circ}C$) and Aug. 8, 2003 (> $7^{\circ}C$), respectively). The spatial pattern showed a high correlation in the range of 0.5~0.9. However, the correlation decreased as the lead time increased. Furthermore, the case of Korea heat wave in 2018 was conducted using GloSea5 forecast data to validate EFI showed successful prediction for two to three weeks lead time. As a result, the EFI forecasts can be used to predict the probability that an extreme weather event of interest might occur. Overall, we expected these results to be available for extreme weather forecasting.

• Journal of Korean Tunnelling and Underground Space Association
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• v.21 no.1
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• pp.137-153
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• 2019

Estimating tunnel construction time and costs are the most fundamental part of a tunnel project planning, which has been generally assessed on a deterministic basis until now. In this paper, excavation cycle time was investigated for two road tunnels and one subway tunnel, and the results were compared with the Standard of Construction Estimate (SE), which is made for the estimation of construction time and cost in a design stage. The results show that the difference in cycle time between SE and actual cycle time is 50%, 7% and 31% respectively for the three tunnels, which means that SE does not reflect practical operation time. The major reasons of the difference are skilled level of tunneling workers, the change of operation sequences for more effective operations, much more complicated working atmosphere in a tunnel than the assumption of SE etc. Finally, even though the results can not be generalized since investigated tunnels are only 3, but it is thought that SE needs to be upgraded into the model able to consider quite common situations through additional tunnel investigation and studies in the future.

• Atmosphere
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• v.30 no.4
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• pp.377-390
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• 2020

Not only emissions, but also atmospheric circulation is a key factor that affects local particulate matters (PM) concentrations in Korea through ventilation effects and transboundary transports. As part of the atmospheric circulation, air stagnation especially adversely affects local air quality due to weak ventilation. This study investigates the large-scale circulation related to air stagnation over Korea during winter and projects the climate change impacts on atmospheric patterns, using observed PM data, reanalysis and regional climate projections from HadGEM3-RA with Modified Korea Particulate matter Index. Results show that the stagnation affects the PM concentration, accompanied by pressure ridge at upper troposphere and weaken zonal pressure gradient at lower troposphere. Downscaling using HadGEM3-RA is found to yield Added-Value in the simulated low tropospheric winds. For projection of future stagnation, SSP5-8.5 and SSP1-2.6 (high and low emission) scenarios are used here. It has been found that the stagnation condition occurs more frequently by 11% under SSP5-8.5 and by 5% under SSP1-2.6 than in present-day climate and is most affected by changes in surface wind speed. The increase in the stagnation conditions is related to anticyclonic circulation anomaly at upper troposphere and weaken meridional pressure gradient at lower troposphere. Considering that the present East Asian winter monsoon is mainly affected by change in zonal pressure gradient, it is worth paying attention to this change in the meridional gradient. Our results suggest that future warming condition increase the frequency of air stagnation over Korea during winter with response of atmospheric circulation and its nonlinearity.

• Atmosphere
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• v.30 no.4
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• pp.439-454
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• 2020

This study investigates the change in the fine particulate matter (PM2.5) concentration and World Health Organization (WHO) air quality index (AQI) in East Asia (EA) under Shared Socioeconomic Pathways (SSPs). AQI is an indicator of increasing levels about health concern, divided into six categories based on PM2.5 annual concentrations. Here, we utilized the ensemble results of UKESM1, the climate model operated in Met Office, UK, for the analysis of long-term variation during the historical (1950~2014) and future (2015~2100) period. The results show that the spatial distributions of simulated PM2.5 concentrations in present-day (1995~2014) are comparable to observations. It is found that most regions in EA exceeded the WHO air quality guideline except for Japan, Mongolia regions, and the far seas during the historical period. In future scenarios containing strong air quality (SSP1-2.6, SSP5-8.5) and medium air quality (SSP2-4.5) controls, PM2.5 concentrations are substantially reduced, resulting in significant improvement in AQI until the mid-21st century. On the other hand, the mild air pollution controls in SSP3-7.0 tend to lead poor AQI in China and Korea. This study also examines impact of increased in PM2.5 concentrations on downward shortwave energy at the surface. As a result, strong air pollution controls can improve air quality through reduced PM2.5 concentrations, but lead to an additional warming in both the near and mid-term future climate over EA.