• Bulletin of the Korean Chemical Society
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• v.25 no.4
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• pp.529-532
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• 2004

Cesium-133 NMR spectra of a single crystal of tetragonal $Cs^+ (15-crown-5)_2I^-$ were obtained as a function of crystal orientation in an applied magnetic field of 9.40T and analyzed to provide the magnitudes and orientations of the $^{133}Cs$ chemical shift and quadrupolar tensors for two magnetically nonequivalent and symmetry related sites. Chemical shift tensor components and parameters of quadrupolar interactions are obtained as ${\delta}_{11}=46(1),\;{\delta}_{22}=60(1),\;{\delta}_{33}=-30(1)$ ppm, quadrupole coupling constant QCC = 581(1) kHz, and asymmetry parameter ${\eta}$ = 0.481(1), respectively. The nonaxially symmetric NMR parameters imply that the local environment of the cesium nuclei is nonaxially symmetric. The DANTE experiment burned holes in the $^{133}Cs$ NMR line of the title compound. The hole burning of the single crystal and powder $^{133}Cs$ NMR lines showed that the NMR lines are not homogeneously broadened.

• Transactions of Materials Processing
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• v.28 no.6
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• pp.335-346
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• 2019

Thick plate forming is presented to manufacture a large and curved member of steam turbine diaphragm. Due to three-dimensional asymmetry of target geometry, it is hard to consistently keep the blank position in die cavity between forming punch and die. In order to relieve the position instability of the blank during the thick plate forming, a blank support structure is proposed to be composed of guide pins and linear bearing, and blank guide arm enlarged from both longitudinal ends of the thick blank. In this study, parametric investigations with regard to the geometric position and width of the blank guide arm are carried out. As main geometric parameters, 2 positions such as maximum curvature region and minimum one on a curved cross-section profile of the target shape are selected, and 14 widths of the blank guide arm are considered. Using 28 variable combinations, three-dimensional numerical simulations are performed to predict the appropriate range of the process parameters. The compatibility and validity of the blank support structure with the blank guide arm for the thick plate forming is verified through the thick plate forming experiments.

• Journal of Photoscience
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• v.8 no.3_4
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• pp.87-92
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• 2001

Intramolecular excimer formation of 1,3-di(1-pyrenyl)propane (Py-3-Py) and fluorescence polarization of 1,6-diphenyl-1,3,5-hexatriene (DPH) were used to investigate the effects of parathyroid hormone (PTH) on the bulk bilayer fluidity of the plasma membrane vesicles isolated from cultured osteoblasts (OB-PMV). In a dose-dependent manner, rat PTH-(1-34) [rPTH-(1-34)] increased the excimer to monomer fluorescence intensity ratio (I'/I) of Py-3-Py and decreased the anisotropy (r) of DPH in OB-PMV. This indicates that PTH increased both the lateral and rotational diffusion of the probes in OB-PMY. Selective quenching of DPH fluorescence by trinitrophenyl groups was utilized to examine the transbilayer fluidity asymmetry of OB-PMV. The anisotropy, limiting anisotropy, and order parameter of DPH in the inner monolayer were 0.024, 0.032, and 0.062 greater than calculated for the outer monolayer of OB-PMY. Selective quenching of DPH fluorescence by trinitrophenyl groups was also utilized to examine the transbilayer effects of PTH on the fluidity of OB-PMV. rPTH-(1-34) had a greater fluidizing effect on the outer monolayer as compared to the inner monolayer of OB-PMV. Thus, it has been proven that PTH exhibits a selective rather than nonselective fluidizing effect within transbilayer domains of OB-PMV.

• Journal of Welding and Joining
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• v.19 no.6
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• pp.622-629
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• 2001

The aim of this experiment is to establish the method that obtains symmetrically two nuggets in microresistance series spot welding. The sheets of austenite stainless steel STS304 applied to various electronic parts were experimented by the inverter welding power source of polarity controllable type and by the twin head for left and right electrode force to be controlled separately. The experimental results were obtained as follows : 1) When series spot welding was carried out by DC 1 pulse as welding current with same electrode force at left and right, the asymmetry of nuggets was resulted from the larger nugget of the (-) pole because of the Peltier effect. The dynamic resistance of weld spot at left and right was appeared differently according to the growth of nuggets. 2) When AC 1 cycle by welding power source of polarity controllable type was applied, the nuggets were almost symmetrically formed. 3) In a twin head, if the electrode force of (-) pole was larger than that of (+) pole, the diameters of two nuggets became to same. It was confirmed that the dynamic resistance of (-) pole was decreased to the same level as it of (+) pole. 4) Although the forces of left and right electrode were same, and only DC 1 pulse was applied, symmetric nuggets were obtained if the conductivity of (+) pole was lower than it of (-) pole.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.19 no.4
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• pp.303-312
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• 2007

There is still a controversy going on about how to model energy dissipation due to breaking over frequency domain. In this study, we unveil the exact structure of energy dissipation using stochastic wave breaking model. It turns out that contrary to our present understanding, energy dissipation is cubically distributed over frequency domain. The verification of proposed model is conducted using the acquired data during SUPERTANK Laboratory Data Collection Project (Krauss et al., 1992). For further verification, we numerically simulate the nonlinear shoaling process of Conoidal wave over a beach of uniform slope, and obtain very promising results from the viewpoint of a skewness and asymmetry of wave field, usually regarded as the most fastidious parameter to satisfy.

• The Journal of the Acoustical Society of Korea
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• v.27 no.7
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• pp.325-332
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• 2008

The prediction method of TS parameters, frequency response, and electrical input impedance is proposed with physical properties of parts and results of electromagnetic FEA(Finite Element Analysis) in a loudspeaker driver design. In design for weight reduction and improvement of flux density asymmetry, the prediction results are well coincided with measurement ones. As the applications, it can be applied in design for improvement of the $2^{nd}$ harmonic distortion with flux density distribution analysis. The proposed method is expected to be utilized for reducing trial-and-error process in electromagnetic parts design. It can also be used for providing guidelines for parts selection in the early stages.

• The Korean Journal of Pharmacology
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• v.28 no.2
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• pp.191-199
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• 1992

Selective quenching of 1,6-diphenyl-1,3,5-hexatriene (DPH) by trinitrophenyl groups was utilized to examine the transbilayer fluidity asymmetry of model membranes of total lipids (SPMVTL) extracted from synaptosomal plasma membrane vesicles (SPMV). The polarization (P), anisotropy (r), limiting anisotropy $(r_{\infty})$, and order parameter (S) of DPH in the inner monolayer were 0.031, 0.025, 0.033, and 0.070, respectively, greater than calculated for the outer monolayer of SPMVTL. Selective quenching of DPH by trinitrophenyl groups was also utilized to examine the effects of n-alkanols on the individual monolayer structure of SPMVTL. n-Alkanols fluidized the hydrocarbon region of bulk SPMVTL, and the potencies of n-alkanols up to 1-nonanol increased with carbon chain length. It appears that the potencies in bilayer fluidization increase by 1 order of magnitude as the carbon chain length increases by two carbon atoms. The cut-off phenomenon was reached at 1-decanol, where further increase in hydrocarbon length resulted in a decrease in pharmacological activity. The n-alkanols had greater fluidizing effects on the outer monolayer as compared to the inner monolayer of SPMVTL, even though these selective effects tended to become weaker as carbon chain length increased. Thus, it has been proven that n-alkanols exhibit selective rather than nonselective fluidizing effects within transbilayer domains of SPMVTL.

• Journal of the Korean Society of Radiology
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• v.83 no.3
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• pp.620-631
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• 2022

Purpose This study aimed to investigate the diagnostic performance of features suggestive of nodal metastasis on preoperative MRI in patients with invasive breast cancer. Materials and Methods We retrospectively reviewed the preoperative breast MRI of 192 consecutive patients with surgically proven invasive breast cancer. We analyzed MRI findings of axillary lymph nodes with regard to the size, long/short ratio, cortical thickness, shape and margin of the cortex, loss of hilum, asymmetry, signal intensity (SI) on T2-weighted images (T2WI), degree of enhancement in the early phase, and enhancement kinetics. Receiver operating characteristic (ROC) analysis, chi-square test, t test, and McNemar's test were used for statistical analysis. Results Increased shorter diameter, uneven cortical shape, increased cortical thickness, loss of hilum, asymmetry, irregular cortical margin, and low SI on T2WI were significantly suggestive of metastasis. ROC analysis revealed the cutoff value for the shorter diameter and cortical thickness as 8.05 mm and 2.75 mm, respectively. Increased cortical thickness (> 2.75 mm) and uneven cortical shape showed significantly higher sensitivity than other findings in McNemar's test. Irregular cortical margins showed the highest specificity (100%). Conclusion Cortical thickness > 2.75 mm and uneven cortical shape are more sensitive parameters than other findings, and an irregular cortical margin is the most specific parameter for predicting axillary metastasis in patients with invasive breast cancer.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.32 no.7A
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• pp.657-665
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• 2007

In this paper, it is investigated that the limitation due to the asymmetry of optical power and chromatic dispersion with respect to optical phase conjugator (OPC) for compensating optical signal distortion of WDM channels in mid-span spectral inversion (MSSI) technique is overcame by using OPC position offset and optimal dispersion coefficients of fiber sections, which depend on OPC position offset. It is confirmed that overall WDM channels are efficiently compensated by applying the optimal parameter values obtained from the proposed method into 24 channels ${\times}\;40\;Gbps$ WDM system with non zero - dispersion shifted fiber (NZ-DSF) of 1,000 km, such as power penalties of inter-channel are reduce to almost 3.5 dB from the infinite value. It is also confirmed that the flexible design of WDM system with OPC is possible by using the optimal parameters, in which OPC is placed at ${\pm}15\;km$ from 500 km for efficiently compensating overall channels.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.36 no.9
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• pp.825-834
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• 2008

Nose chine shape optimization study has been performed to maximize the directional stability at high angle of attack supersonic flow. Various chine shapes are generated using super ellipse equation. By numerically investigating the directional stability characteristics of those shapes, the baseline configuration for the shape optimization has been selected using the three-dimensional Navier-Stokes equations. The configuration is represented by the NURBS curves which can adjust the surface geometry by the control points. The response surfaces are constructed to obtain optimum shape which has high directional stability characteristics and lift-to-drag ratio. From this study, an efficient configuration design and optimization process which utilizes the parameter-based configuration generation techniques and approximation method has been established, then 29% improvement of the directional stability by strong vortexes from chine nose is accomplished.