• Proceedings of the Membrane Society of Korea Conference
• /
• 1997.10a
• /
• pp.83-84
• /
• 1997

1. INTRODUCTION : Polyimides containing siloxane moiety(poly(imide siloxane), or polysiloxaneimide) have been synthesized because of their some merits over polyimide itseft. Polyimides have excellent thermal and mechanical properties but their poor solubility and processibility in their fullly imidized form give disadvantages in applications. Incorporation of siloxane units make it possible to increase solubility and processibility, and also impart impact resistance, low moisture uptake, low dielectric constant, thermo-oxidative resistance, good adhesion properties to substrate and etc.. Incorporation methods of siloxane groups into the polyimide was mainly copolymerization or terpolymerization between oligomeric dimethylsiloxane and aromatic dianhydride. A few methods of introducing siloxane units in functional groups of polyimide was reported. In our laboratory poly(amideimide siloxane) and poly(imide siloxane) were prepared and the study about their thermal kinetics was performed. In separation membrane area, polysiloxaneimides was utilized in pervaporation and gas separation. Polyimides in gas separation show high selectivity and very low permeability, and introduction of siloxane segments increase permeability with low decrease in selectivity. We aimed to introduce silicone segments into poly(amic acid) state and synthesize polymer partially imidized, and also show the gas separation characteristics of the synthesized polymer.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 1992.11a
• /
• pp.63-66
• /
• 1992

Using an aromatic system, we made a ultra thin insulator through LB-method. We measured and wrote down afternating currant characteristics of ultraviolet rays extincting-spectrum and I.R extincting-spectrum. We surveyed the thickness of a film through X-ray diffracting method and certified about $4{\AA}$ by the layer. Measuring the characteristics of direct current voltage and electric current with this sample, we produced its conductivity and discovered that this sample had a god insulating performance. Addition to this, we measured the characteristics of voltage and electric current, and the temperature dependency of conductivity in a high voltage system and with these results tried to interpret a mechanism of conduction.

• Proceedings of the KIEE Conference
• /
• 2000.07c
• /
• pp.1754-1756
• /
• 2000

Organic semiconductors based on fused-ring polycyclic aromatic hydrocarbon have great potential to be utilized as an active layer for electronic and optoelectronic devices. In this study, pentacene thin films and electrode materials were deposited by Organic Molecular Beam Deposition(OMBD) and vacuum evaporation respectively. For the gate dielectric, polyamic acid was spin-coated and cured into polyimide at 350$^{\circ}C$. Electrical characteristics of the devices were investigated, where the channel length and width was 50${\mu}m$ and 5mm. It was found that field effect mobility was 0.012$cm^{2}/Vs$, and on/off current ratio was $10^5$.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2003.11a
• /
• pp.502-505
• /
• 2003

We synthesized high thermal photoalignment material with hydroxyl aromatic polyimide, and studied the liquid crystal (LC) aligning capabilities on the photopolymer layers. Also, electro-optical (EO) performances for the twisted-nematic (TN)-liquid crystal display (LCD) photoaligned with linearly polarized UV exposure were investigated. A good LC alignment with UV exposure on the photopolymer surface can be obtained. However, the low pretilt angles were obtained below $1^{\circ}$. The Voltage-transmittance (V-T) curve without backflow bounce in the photoaligned TN cell with UV exposure was observed. The response time of photoaligned TN cell was measured about 24 ms.

• 한국정보디스플레이학회:학술대회논문집
• /
• 2003.07a
• /
• pp.600-603
• /
• 2003

VA-LCDs is widely used for recent LCD productions owing to wide viewing angle characteristics with an unusually high contrast ratio. To apply for VA-LCDs, the novel homeotropic alignment materials were synthesized, which have the liquid crystal molecule as a side chain at aromatic diamine in a polyimide structure. These polyimides generated a high pretilt angle $90^{\circ}C$. In this paper, the synthesis and alignment properties of new homeotropic alignment materials will be discussed..

• Proceedings of the Korean Fiber Society Conference
• /
• 2001.10a
• /
• pp.37-40
• /
• 2001

Aromatic polyimides는 다른 고분자 재료에 비해 고온에서의 열 안정성 및 기계적 물성, 내화학성, 전기 절연성, 난연성 등이 매우 탁월하기 때문에, 최근 들어서 고성능 구조재료, 전자재료(microelectronics devices, electrical insulators of semiconduntor packages), 내열성 접착제, 코팅제 등 그 응용 범위가 점차 확대되고 있는 추세이다. (중략)

• Applied Chemistry for Engineering
• /
• v.17 no.2
• /
• pp.177-182
• /
• 2006

In this work, we have prepared organophilic MMT having thermal stability by ion exchange reaction of various aromatic ammonium salts with MMT containing sodium ion. The organic modifiers having alkyl side chains and amine functional group were successfully synthesized by effectively introducing the surfaces of MMT via ion exchange reaction to form organophilic MMTs with a view to improve the reactivity and thermal stability. The WAXD patterns of organophilic MMT showed the more increased gallery spacing by $3.3{\AA}$ than that of the pristine MMT and also the onset of initial decomposition of organophilic MMT was $275^{\circ}C$ as determined by a thermogravimetric analysis. The polyimide (PI) nanocomposite films based on poly(amic acid) and organophilic MMT were prepared by a solution blending followed by cyclodehydration reaction. We have investigated the dispersity of organophilic MMTs in PI matrix by using WAXD and the effect of the organophilic MMT content on the mechanical properties of PI nanocomposite films was studied.

• Membrane Journal
• /
• v.30 no.6
• /
• pp.450-459
• /
• 2020

Membrane-based separations have the potential to reduce energy consumption and environmental impact associated with conventional processes. However, many researches have been done to develop new membrane materials with greater selectivity and permeability. Here, we report highly selective membranes by introducing bulky ethyl substituents into the polyimide. The ethyl group in the ortho position to the imide nitrogen interferes the chain packing and increases chain stiffness and the distance between the polymer chains. The polyimide membranes were synthesized from various aromatic dianhydrides and 4,4'-methylenebis(2,6-diethylaniline) (MDEA). The synthesized membranes with increased gas diffusion length due to bulky substituents showed improved propylene/propane (C3H6/C3H8) selectivity. Single gas permeation showed high C3H6/C3H8 selectivity of 14.5, and C3H6 permeability of 7.0 barrer was found in MDEA-polyimide. Mixed-gas permeation results also demonstrate that MDEA-polyimide can achieve high selectivity in mixed-gas environment. Furthermore, this approach could significantly increase the feasibility of economic propylene separation compared to conventional polymer materials.

• Macromolecular Research
• /
• v.14 no.1
• /
• pp.1-33
• /
• 2006

Polyimides (PIs) exhibit excellent thermal stability, mechanical, dielectric, and chemical resistance properties due to their heterocyclic imide rings and aromatic rings on the backbone. Due to these advantageous properties, PIs have found diverse applications in industry. Most PIs are insoluble because of the nature of the high chemical resistance. Thus, they are generally used as a soluble precursor polymer, which forms complexes with solvent molecules, and then finally converts to the corresponding polyimides via imidization reaction. This complexation with solvent has caused severe difficulty in the characterization of the precursor polymers. However, significant progress has recently been made on the detailed characterization of PI precursors and their imidization reaction. On the other hand, much research effort has been exerted to reduce the dielectric constant of PIs, as demanded in the microelectronics industry, through chemical modifications, as well as to develop high performance, light-emitting PIs and liquid crystal (LC) alignment layer PIs with both rubbing and rubbing-free processibility, which are desired in the flat-panel display industry. This article reviews this recent research progresses in characterizing PIs and their precursors and in developing low dielectric constant, light-emitting, and LC alignment layer PIs.

• Polymer(Korea)
• /
• v.37 no.5
• /
• pp.618-624
• /
• 2013

Hydroquinone bis(trimellitic anhydride) (HQ-TA) was synthesized from trimellitic anhydride chloride and hydroquinone. Poly(amic acid)s (PAAs) were synthesized by reacting a HQ-TA with six different diamines, which were cyclized to yield polyimides (PIs) containing ester linkages by chemical- and thermal-imidization methods. The various PIs were synthesized from structurally different aromatic diamines. The glass transition temperatures ($T_g$) were in the range of 167-$215^{\circ}C$, and the decomposition temperatures (${T_D}^i$) were in the range of $364-451^{\circ}C$. The maximum improvements in coefficient of thermal expansion (CTE) and barrier to oxygen permeation were observed in PIs using TFB (3.23 $ppm/^{\circ}C$) and 4,4-ODA (< $10^{-2}cc/m^2/day$), respectively. The PI films possessed a transmittance of 65-89% at 500 nm and had a yellowish color with a yellow index (YI) of 3.01-69.52.