• 멤브레인
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• 제31권5호
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• pp.327-332
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• 2021

멤브레인 기반의 MBRWG (Membrane Bioreactor for Waste Gas) 처리기술은 폐가스 흐름에 대한 높은 선택성을 바탕으로 효과적인 생물학적 제거를 수행할 수 있다. MBRWG에는 몇 가지 잠재적 이점이 있는데, 이 중 가장 두드러진 점은 기상과 액상이 멤브레인 양쪽으로 명확히 분리되어 액상 내 생물막의 최적제어가 용이하고 이를 통해 효과적인 생분해와 생물막의 활성화를 도모할 수 있다는 것이다. MBRWG 처리기술은 특히 xylene 같은 소수성 독성 기체 성분 제거에 유리한데 이는 소수성 기체의 물질전달속도, 독성 및 제거율이 생물막 인근의 액상흐름 및 수분제어에 민감하게 변화하기 때문이다. MBRWG 처리에 쓰이는 다양한 멤브레인 중에서 PDMS-중공사막(hollow fiber)이 가장 높은 기체 물질 전달을 제공한다고 보고되었다. Capillary 형태도 중공사막형태에 비해 비표면적은 낮지만 비교적 활발한 연구가 진행되고 있다. 소수성 기체성분 제거 외에도 기존 생물학적 폐가스 처리 장치에서 배출된 잔류 기체 혼합물이나 먼지를 제거하기 위한 후단 공정에서 멤브레인 활용을 고려할 수 있다.

• 한국막학회:학술대회논문집
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• 한국막학회 1996년도 추계 총회 및 학술발표회
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• pp.34-39
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• 1996

There is much recent interests in applying membrane separation technologies, especially for organic liquid and vapor separation or removing dissolved organics from water. Pervaporation separation can separate azeotropic mixtures and mixtures close to boiling point, and it has a potential for energy saving process instead of distillation. Removal of chlorinated oraganics from water is other measure application for pervaporation separation. Contaminated pollutant must be removed from water, and a pervaporation can effectively remove the pollutant. Air pollution by organic vapor recently became serious enviromncntal problem, and removing organic vapor from air is important application of the membrane technology.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2001년도 봄 학술발표회 논문집
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• pp.979-984
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• 2001

Poor water-proofing integrity is related to many factors : site procedure, workmanship, weather. substrate conditions, installation(including asphalt application) conditions. The evaluation of adhesive properties tested by concrete surface moisture and asphalt application was based on laboratory test and observations. This report describes the pull-off test results of waterproofing systems currently used for installing and reparing for concrete bridge decks. The test results showed that the moisture condition fully affected the adhesive properties of sheet membranes and sealer but partially for liquid membranes.

• 한국막학회:학술대회논문집
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• 한국막학회 2004년도 Proceedings of the second conference of aseanian membrane society
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• pp.43-46
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• 2004

The large quantity of liquid wastes from nuclear industries such as nuclear power plants would become a serious storage problem in view point of the environmental safety. The liquid wastes should be concentrated to a smallest possible volume before the storage. The use of supported liquid membranes (SLMs) for this purpose is very attractive [1,2], however loss of solvent and carrier in the surrounding solutions limits the stability of SLMs and hinders their commercial application in the industries.(omitted)

• 한국막학회:학술대회논문집
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• 한국막학회 2003년도 The 4th Korea-Italy Workshop
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• pp.51-55
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• 2003

Membranes made with perfluorinated polymers are of particular interest due to the unique features demonstrated by these materials. Both highly hydrophobic and hydrophilic membranes have been developed from appropriate perfluoropolymers, which were in turn obtained by copolymerization of TFE with special monomers available at the industrial scale. Highly hydrophobic membranes obtained from the glassy copolymers of TFE and 2,2,4 trifluoro-5 trifluoromethoxy-1,3 dioxole (Hyflo $n^{ }$ AD) show properties which make them particularly suited for use in the field of gas-liquid contactors and membrane distillation. Hydrophylic highly conductive proton exchange membranes obtained from the copolymer of TFE and a short-side-chain (SSC) perfluorosulfonylfluoridevinylether (Hyflo $n^{ }$ Ion) find interesting application in the field of fuel cells, especially in view of the current tendency to move to high temperature operation.n.

• Membrane and Water Treatment
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• 제2권4호
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• pp.207-223
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• 2011

Supported Liquid Membranes (SLMs) have been widely studied as feasible alternative to traditional processes for separation and purification of various chemicals both from aqueous and organic matrices. This technique offers various advantages like active transport, possibility to use expensive extractants, high selectivity, low energy requirements and minimization of chemical additives. SLMs are not yet used at large scale in industrial applications, because of the low stability. In the present paper, after a brief overview of the state of the art of SLM technology the facilitated transport mechanisms of SLM based separation is described, also introducing the small and the big carrousel models, which are employed for transport modeling. The main operating parameters (selectivity, flux and permeability) are introduced. The problems related to system stabilization are also discussed, giving particular attention to the influence of membrane materials (solid membrane support and organic liquid membrane (LM) phase). Various approaches proposed in literature to enhance SLM stability are also reviewed. Modification of the solid membrane support, creating an additional layer on membrane surface, which acts as a barrier to LM phase loss, increases system stability, but the membrane permeability, and then the flux, decrease. Stagnant Sandwich Liquid Membrane (SSwLM), an implementation of the SLM system, results in both high flux and stability compared to SLM. Finally, possible large scale applications of SLMs are also reviewed, evidencing that if the LM separation process is opportunely carried out (no production of byproducts), it can be considered as a green process.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 봄 학술발표회 논문집
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• pp.373-378
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• 2002

The waterproofing system's performance is known to show a determining by complex interaction of material factors, design details, and the qualify of construction, and the waterproofing integrity of waterproofing membranes is determined by the bond to the deck and the amount of damage to the waterproofing membrane. In this research, the basic properties of waterproofing membranes on market and the tensile adhesive characteristics of waterproofing systems of concrete bridge deck have also been investigated in the view of the damages frequently reported from job site. As a results of tensile adhesive strength of waterproofing system, tensile strength is decrease with surface moisture contents except for inorganic-elastomeric liquid waterproofing membrane, and increase with strength of deck slab. Also tensile adhesive strength is generally increase in case of moisture curing of specimen because of pore structure and surface leveling. The after asphalt concrete paving tends to increase more than before those. The results of the liquid waterproofing membranes are upside-down, and the more concrete has strength, the more strength of tensile adhesive increase. The ambient temperature and the rolling temperature of asphalt concrete when application of the waterproofing membrane has considerable influence on the performance of waterproofing system.

• 멤브레인
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• 제25권2호
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• pp.171-179
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• 2015

과불소계 술폰화 이오노머(perfluorinated sulfonic acid ionomers; PFSAs)는 뛰어난 수소이온전도성과 높은 내화학성으로 인해 고분자 전해질 연료전지(polymer electrolyte fuel cells)용 고체전해질로 널리 사용되고 있다. 그러나 PFSA 전해질은 가습-건조조건에서 연료전지가 구동에 따라 반복적인 팽윤-수축으로 인해 전극층이 전해질로부터 탈리되어 전기화학적 수명특성이 감소되는 문제점을 가지고 있다. 본 연구에서는 다공성 PTFE support film의 기공특성에 대한 이해를 바탕으로 기공구조 내 나피온 이오노머를 함침시키는 강화막을 제조하였고, 기본특성을 평가하였다. 제조된 강화막은 매우 높은 수소이온전도도(${\sim}~0.5S\;cm^{-1}@90^{\circ}C$ in liquid water)를 나타내었다.

• Macromolecular Research
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• 제16권5호
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• pp.457-466
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• 2008

The relation between the phase separated morphologies and their transport properties in the polymer blend membrane for direct methanol fuel cell application was studied. In order to enhance the proton conductivity and reduce the methanol crossover, sulfonated poly(arylene ether sulfone) copolymer, with a sulfonation of 60 mol% (sPAES-60), was blended with nonsulfonated poly(ether sulfone) copolymer (RH-2000, Solvay). Various morphologies were obtained by varying the drying condition and the concentration of the casting solution (10, 15, 20 wt%). The transport properties of proton and methanol molecule through the polymer blend membranes were studied according to the absorbed water. AC impedance spectroscopy was used to measure the proton conductivity and a liquid permeability measuring instrument was designed to measure the methanol permeability. The state of water in the blend membranes was confirmed by differential scanning calorimetry and was used to correlate the morphology of the membrane with the membrane transport properties.

• 멤브레인
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• 제22권4호
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• pp.235-242
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• 2012

로켓 추진기관의 해체 시 발생하는 고농도 암모늄 퍼클로레이트(AP)를 액상소각 처리 후 추가로 발생하는 저농도의 AP처리를 위해 NF/RO 멤브레인 공정을 적용하였고, 이때 AP제거 특성에 영향을 미치는 인자를 도출하기 위해 다양한 수리화학적 조건에서 전량여과방식으로 실험을 진행하였다. 고체 추진제에서 추출된 용액을 GC/MS와 FTIR분석을 통해 규산염 계열의 실록산 등을 검출하였으나, 이는 극미량이 포함되어 NF/RO 멤브레인 공정에 큰 영향을 미치지 않는 것으로 판단되었다. 상대적으로 낮은 압력의 운용조건에서는 높은 압력조건과 비교하여, 회수율 증가에 따라 농축된 AP의 삼투압 기작이 투과플럭스에 영향을 미치게 되어 13~17% 가량 플럭스가 감소됨을 확인하였다. 또한 AP의 제거율은 수리화학적 운영조건의 변화(압력 및 교반 속도 등)에 따라 크게 좌우됨을 알 수 있었고, 이 경우 NF와 RO 멤브레인 제거율은 각각 10~70%와 26~87% 가량 크게 달라짐을 확인하였다. 본 논문을 통해 NF/RO 멤브레인 공정을 적용한 AP 제거 기작에서 수리화학적 운영조건의 변화에 따른 농도분극, 멤브레인 선택성 및 삼투압 영향이 중요 지배 기작이었으며, 이는 'NF/RO 멤브레인의 물질이동과 선택성'의 기존 이론적 모델과 부합하였다.