• Title/Summary/Keyword: antimony

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Thermodynamical and Experimental Analyses of Chemical Vapor Deposition of ATO from SnCl4-SbCl5-H2O Gas Mixture ($SnCl_4-SbCl_5-H_2O$ 기체혼합물로부터 ATO(Antimony Tin Oxide) 박막의 화학증착에 관한 열역학 및 실험분석)

  • 김광호;강용관;이수원
    • Journal of the Korean Ceramic Society
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    • v.29 no.12
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    • pp.990-996
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    • 1992
  • Chemical vapor deposition of ATO from SnCl4-SbCl5-H2O gas mixture was investigated with thermodynamic and experimental analyses. Electrical conductivity of the ATO film was much improved under deposition conditions of low input-gas ratio, Psbcl5/Psbcl4. This increase of the conductivity was attributed to donor electrons produced mainly by the pentavalent Sb ions in SnO2 lattice. However high input-gas ratio conditions produced an ATO film consisting of a mixture of SnO2 and very fine Sb2O5 phase. It was found that the deterioration of electrical conductivity and optical transmission of the film was caused by the deposition of fine Sb2O5 phase in the SnO2 matrix.

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A UBET Analysis on the Lateral Extrusion Process of a Spider (스파이더의 측방 압출 공정에 대학 UBET해석)

  • Lee, Hee-In;Bae, Won-Byong
    • Journal of the Korean Society for Precision Engineering
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    • v.18 no.6
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    • pp.174-181
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    • 2001
  • An upper bound elemental technique(UBET) has been carried out to predict the forming load, the deformation pattern and the extrude length of the lateral extrusion of a spider for the automotive universal joint. For the upper bound analysis, a kinematically admissible velocity field(KAVF) is proposed. From the proposed velocity field, the upper bound load, the deformation pattern and the average length of the extruded billets are determined by minimizing the total energy consumption rate which is a function of unknown velocities at each element. Experiments are carried out with antimony-lead billets at room temperature using the rectangular shape punch. The theoretical prediction of the forming load, the deformation pattern and the extruded length are good in agreement with the experimental results.

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Studies on the Inflammability and Heat Resistance of Conveyer Rubber Belts (콘베어 고무벨트의 난연성(難燃性) 및 내열성(耐熱性)에 관(關)한 연구(硏究))

  • Oh, Pyoung-Je
    • Elastomers and Composites
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    • v.16 no.4
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    • pp.211-216
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    • 1981
  • A series of conveyer rubber belts has been made by blending natural rubber(NR), styrene butadiene rubber(SBR), chloroprene rubber(CR) and additives on nylon cords, and their respective flammability has been investigated. It has been observed that: 1. By adding an antiflame agent to the belt, in addition to 70% chlorinated paraffine and antimony oxide($Sb_{2}O_{3}$), the inflammability is improved remarkably to O - 2 seconds due to the synergistic effect, while a sample without antiflame B fails to pass the KS M 6678 test. 2. Physical properties, such as tensile strength, elongation at break and adhesion strength, of the sample belts have been studies by varying ratios of NR/CR from 20 to 100, and it has been observed that the higher ratios have the better physical properties.

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Electrical Characteristics of Flat Cesium Antimonide Photocathode Emitters in Panel Devices

  • Jeong, Hyo-Soo
    • Transactions on Electrical and Electronic Materials
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    • v.17 no.5
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    • pp.306-309
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    • 2016
  • The Cs3Sb photocathode was formed by non-vacuum process technology. An in-situ vacuum device was fabricated successively with flat cesium antimonide photocathode emitters fabricated in a process chamber. The electrical properties of the device were characterized. Electron emission from the devices was induced by photoemitted electrons, which were accelerated by an anode electric field that was shielded from the photoemitter surface. The electrical characteristics of the devices were investigated by measuring the anode current as a function of device operation times with respect to applied anode voltages. Planar blue LED light with a 450 nm wavelength was used as an excitation source. The results showed that the cesium antimonide photocathode emitter has the potential of long lifetime with stable electron emission characteristics in panel devices. These features demonstrate that the cesium antimony photocathodes produced by non-vacuum processing technology is suitable for flat cathodes in panel device applications.

Chalcogenide계 열전재료

  • Kim, Il-Ho
    • Electrical & Electronic Materials
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    • v.24 no.7
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    • pp.10-17
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    • 2011
  • 현재 개발 중인 Chalcogenide계 열전재료 중에서, 이방성 재료인 Thallium chalcogenide, Alkalimetal bismuth chalcogenide, Bismuth telluride와 등방성 재료인 Lead telluride, Silver antimony telluride, TAGS, LAST 및 SALT를 소개하였고, 이 재료들에 대한 연구 동향을 살펴보았다. Chalcogenide는 S, Se, Te 및 다른 원소와의 다양한 조합에 의해, 넓은 온도범위에서 열전재료로 응용하기 위한 밴드갭 에너지의 조절이 가능하다. 또한 합성공정에 따른 상변태, 석출 등 구조변화에 따른 열전특성의 변화를 기대할 수 있어 열전재료 개발 초기부터 활발한 연구가 진행되어 왔다. 과거의 전통적인 Chalcogenide계 열전재료뿐만 아니라, Chalcogenide계 열전 신소재에 대해서도 살펴보았다. Chalcogenide는 전자적, 광학적, 열적 성질 등 특성이 독특하고 변화가 무궁무진하여 아주 매력적이기 때문에, 앞으로도 계속 열전재료로서 각광받는 물질군으로 판단된다. 그림 11에 현재까지 ZT의 최댓값이 1이 넘는다고 보고된 열전재료의 성능지수를 요약하였다.

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Growing High-Quality Ir-Sb Nanostructures by Controlled Electrochemical Deposition

  • Nisanci, Fatma Bayrakceken
    • Journal of Electrochemical Science and Technology
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    • v.11 no.2
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    • pp.165-171
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    • 2020
  • The electrochemical preparation and spectroscopic characterisation of iridium-antimony (Ir-Sb) species is important owing to their potential applications as nanostructure materials. Nanostructures, i.e. nanoflower and nanodisk, of Ir-Sb were electrodeposited on conductive substrates using a practical electrochemical method based on the simultaneous underpotential deposition (UPD) of Ir and Sb from the IrCl3 and Sb2O3 at a constant potential. Electrochemical UPD mechanism of Ir-Sb was studied using cyclic voltammetry and potential-controlled electrochemical deposition techniques. Herein, X-ray diffraction, scanning electron microscopy, energy dispersive spectroscopy, X-ray photoelectron and Raman spectroscopy were used to determine the morphological and structural properties of the electrochemically-synthesised Ir-Sb nanostructures.

A UBET Analysis on the Lateral Extrusion Process of a Spider (스파이더의 측방 압출 공정에 대한 UBET 해석)

  • 황범철;이희인;배원병
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2001.04a
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    • pp.1129-1133
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    • 2001
  • An upper bound elemental technique(UBET) has been carried out to predict the forming load, the deformation pattern and the extruded length of the lateral extrusion of a spider for the automotive universal joint. For the upper bound analysis, a kinematically admissible velocity field(KAVF) is proposed. From the proposed velocity field, the upper bound load, the deformation pattern and the average length of the extruded billets are determined by minimizing the total energy consumption rate which is a function of unknown velocities at each element. Experiments are carried out with antimony-lead billets at room temperature using the rectangular shaped punch. The theoretical prediction of the forming load, the deformation pattern and the extruded length are good in agreement with the experimental results.

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PRAM Switching Device By Using Current Pulse Modulation

  • Lee, Seong-Hyun;Gil, Gyu-Hyun;Lee, Jung-Min;Song, Yun-Heup
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.384-384
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    • 2012
  • PRAM switching device by using current pulse modulation was investigated to verify its possibility for 3D architecture. In this work, two phase change materials connected in series having a different crystallization temperature are used. Its structural for different phase change material was evaluated by electrical resistance. We confirmed that Germanium-Antimony-Tellurium (GST) alloy and Germanium- Copper-Tellurium (GCT) alloy material were selected according to crystallization temperature, ${\sim}180^{\circ}C$ for switching and ${\sim}240^{\circ}C$ for memory devices, respectively. From this research, it is expected that phase change switching device could have advantages of process in terms of material similarity and structural simplification.

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The Effect of Arsenic on Copper Electrodeposition in Copper-Sulfate Solutions in Copper-Electrorefining (동 전해정련시 황산구리 수용액 중의 Arsenic이 구리의 전해전착에 미치는 영향)

  • Kim, Do-Hyung;Kim, Yong-Hwan;Chung, Won-Sub
    • Journal of Surface Science and Engineering
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    • v.42 no.3
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    • pp.103-108
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    • 2009
  • The effect of Arsenic in copper-sulfate solutions during electrorefining of copper was investigated using scanning electron microscopy, X-ray diffraction and cyclic voltammetry analysis. Electrodeposition was carried out using Arsenic, Antimony and bismuth addition to sulfate electrolytes: 45 g/l $Cu^{2+}$ and 170 g/l $H_2SO_4$. Arsenic in sulfate electrolytes changed the morphology and structure of the copper deposits as compared with those obtained from impurity free solutions. When arsenic was present in the sulfate electrolytes, $Cu-3$As intermetallic phase was formed locally on the deposits.

Electrodeposition of p-type oxide Cu2O thin films and their doping properties (p-형 산화물 반도체 Cu2O 박막의 전기화학증착 및 도핑 연구)

  • Baek, Seung-Gi;Jo, Hyeong-Gyun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.107-107
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    • 2014
  • p형 자원 친화형 산화물 기반 능동형 층 성장에 대한 연구는 아직 개발 초기 단계이다. $Cu_2O$는 이러한 자원 친화형 저가 p형 산화물 중 하나로서 다양한 광학 응용분야에 있어 적용되고 있으며 특히 저가형 증착법인 전기증착법을 통해 형성시킨다면 가격 절감을 극대화 시킬 수 있다. 하지만 낮은 전도성으로 인해 전자소자에는 적용시키기 어렵다는 단점이 있기 때문에 본 연구팀은 5족 물질인 Antimony 를 $Cu_2O$의 p형 도펀트로 적용시켜 전기적 구조적 특성을 개선시키고자 하였다. 결과적으로 [111] 방향으로 높은 우선배향성을 갖고 전도성이 향상된 Sb-Cu2O 박막을 확인하였다.

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