• Title/Summary/Keyword: anthraquinone dye

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Optimization of Anthraquinone Dyes Decolorization Conditions with Response Surface Methodology by Aspergillus

  • Ge, Yufeng;Wei, Bin;Wang, Siyu;Guo, Zhiguo;Xu, Xiaolin
    • Korean Chemical Engineering Research
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    • v.53 no.3
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    • pp.327-332
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    • 2015
  • A large amount of dye wastewater poses a threat to environmental safety. Disperse blue, an anthraquinone dye that is widely used in textile dyes, is difficult to degrade in wastewater. In this work, one fungus was screened according to the decolorization rate of disperse blue. The fungus was identified and named Aspergillus XJ-2 on the basis of its morphological characteristics and 18s rDNA. Response surface method was used to optimize culture conditions for A. XJ-2. The optimum values of obtained responses were as follows: temperature, $35^{\circ}C$; pH, 5.2; carbon-to-nitrogen ratio, 30:5.5; and rotation ratio, $175r{\cdot}min^{-1}$. Under optimized conditions, the decolorization rate of A. XJ-2 was up to 94.8% in 48 h.

Isolation of a Wood-rotting Fungus to Decolorize a Wide Range of Structurally Different Synthetic Dyes. (다양한 염료의 탈색이 가능한 목재부후균 분리)

    • Microbiology and Biotechnology Letters
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    • v.31 no.3
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    • pp.301-306
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    • 2003
  • Twenty-one different fungi were tested for their ability to decolorize a wide range of structurally different dyes. Twenty fungal strains were isolated from fruiting bodies which were collected at the Kwangneung National Arboretum, Korea. One fungal strain were isolated from a rotting wood at Soongsil University, Korea. Nine kinds of dyes were used: three anthraquinone dyes and six azo dyes. The five fungal strains, Laetiporus sulphureus, Polyporus arcularius. Auricularia polytricha, Stereum ostrea, and Bjerkandera sp. UK-l showed decolorization ability. Except Auricularia polytricha, the four fungal strains were wood rotting fungi, and belonged to Aphyllophorales. Bjerkandera sp. UK-I, which was a white rot fungus, could decolorize all kinds of dyes tested in this study, indicating this fungus is one of candidates for applying in biological methods of dye waste treatment.

Isolation and Growth Characteristics of Alkalophilic Bacillus sp. for Removal of Anthraquinone Dye. (Anthraquinone계 염료의 제거를 위한 호알칼리성 Bacillus sp.의 분리와 성장 특성)

  • 김정목
    • Microbiology and Biotechnology Letters
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    • v.29 no.2
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    • pp.67-71
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    • 2001
  • Isolation and Growth Characteristics of AIkalophilic Bacillus sp. for Removal of Anthraquinone Dye. Kim, Jeong-Mog. School of Environmental Information, Taekyeung College, Kyungsan, 712-850, Korea -Alkalophilic strain degrading and decolorizing anthraquinone dye, Remazol brilliant blue R was isolated from natural system and named as Bacillus sp. ARB!. The optimal temperature and pH of Bacillus sp. ARBI were 35°C and 9.0, respectively. The pH of culture media during the fermentation were changed from 10 and 10.5 of initial values to 9.3 and 9.4 after 40 hrs, respectively. Decolorization efficiency in aerobic shaking culture of Bacillus sp. ARBI was markedly higher than that in standing culture. At the optimal culture condition, decolorization efficiency by the Bacillus sp. ARBl was 93% after 32 hrs batch culture. In the case of batch culture using real dye processing wastewater, dye decolorization efficiency of Bacillus sp. ARBl was 78% after 40 hrs.

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Synthesis and Properties of New Phthaloperinone Dyes (신규 Phthaloperinone 색소의 합성과 특성에 대한 연구)

  • Jun, Kun;Gwon, Seon Yeong;Kim, Sung Hoon
    • Textile Coloration and Finishing
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    • v.27 no.4
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    • pp.275-280
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    • 2015
  • New series of phthaloperinone dyes were synthesized by the condensation reaction between tetrachloro-phthalic anhydride, 2,3-naphthalene dicarboxylic anhydride and o-phenylenediamine, 1,8-diaminonaphthalene, 1,2-diaminoanthraquinone. These dyes absorb at around 370-490nm. It was found that introduction of naphthalene and anthraquinone moiety on the perinone system produces a large bathochromic shift of 100nm. The synthesized dye 7 containing anthraquinone moiety in perinone chromophoric system exhibited superior heat stability and bright color as yellow chromophore. New dye 7 have been investigated in terms of interacting with volatile organic compound(VOC) $EtNH_2$. The sensing behaviour of the dye 7 toward $EtNH_2$ was studied by UV-vis absorption spectroscopy. Sensing mechanism of dye 7 to $EtNH_2$ was supported by theoretical calculations based on DFT method.

Anthraquinone-carbamodithiolate Assembly as Selective Chromogenic Chemosensor for Fe3+

  • Bae, Jin-Seok;Gwon, Seon-Yeong;Kim, Sung-Hoon
    • Textile Coloration and Finishing
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    • v.25 no.1
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    • pp.13-17
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    • 2013
  • A new assembly derived from 2,3-dibromo-5,6,7,8-tetrafluoroquinizarin and sodium diethyl-carbamodithiolate, was prepared as an efficient $Fe^{3+}$ colorimetric chemosensor with high selectivity over other cations $Fe^{3+}$, $Na^+$, $Mg^{2+}$, $Pb^{2+}$, $Cd^{2+}$, $Ni^{2+}$, $Ca^{2+}$, $Cu^{2+}$, $Hg^{2+}$, $Zn^{2+}$ : from the dark blue to brown color change that is visible by eyes. This assembly produced large bathochromic shift of 228 nm in the presence of $Fe^{3+}$ compared with the corresponding absorption maximum of the parent dye.

Purification of Aldose Reductase and Decolorization of Dye by the Enzyme

  • Jang, Mi;Kim, Kyung-Soon
    • Preventive Nutrition and Food Science
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    • v.14 no.4
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    • pp.358-361
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    • 2009
  • Aldose reductase was purified to electrophoretic homogeneity from porcine liver. The purified enzyme was a monomer of 36 kDa. The enzyme was strongly inhibited by $Cu^{2+}\;and\;Mg^{2+}$ ions. Incubation of the enzyme with pyridoxal 5'-phosphate led to complete inhibition of enzymatic activity, suggesting that lysine residue is involved at or near the active site of the enzyme. The enzyme exhibited a broad substrate specificity. Furthermore, the enzyme was capable of decolorizing Alizarin, an anthraquinone dye.

A Study of Thermal-stability of Blue Dyes Depending on Dye Chromophore and Substituents (Blue dye의 Chromophore와 치환기에 따른 열안정성 특성 연구)

  • Kim, Tae Hyeon;Lee, Ju Hong;Kang, Eun Jin;Choi, Jae Hong
    • Textile Coloration and Finishing
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    • v.33 no.4
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    • pp.169-181
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    • 2021
  • Five dyes based on phthalocyanine, a dye on azo, and a dye on anhraquinone were prepared from corresponding starting material to investigate the effects of substituent on thermal-stability of dyes which is essentially required to apply to the color filters. Synthesized dyes were confirmed their chemical structure using by 1H-NMR, MASS and Elemental analysis. The thermal-stability was evaluated by the weight reductions measured by TGA analysis comparing to that of conventional C.I. Pigment Blue 15:6. The absorption maxima were measured by UV-VIS spectrophotometer then the effects of substituent on absorption maximum was also investigated.

Optical Studies of a Pure and Dye Doped Nematic Liquid Crystal E-24

  • Chandel, V.S.;Manohar, S.;Shukla, J.P.;Manohar, R.
    • Transactions on Electrical and Electronic Materials
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    • v.13 no.5
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    • pp.221-224
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    • 2012
  • The present paper reports the comparative optical behavior of a pure nematic mixture E-24 and its anthraquinone dye doped sample. The variation in the ordinary and extraordinary refractive index ($n_o$, $n_e$) of the pure and dye doped samples with temperature has been discussed and it has been found that doped sample have a less refractive index compared to the pure sample. The variation in the order parameter for pure and doped samples with temperature has been discussed and it has been seen that the doped sample has a higher order parameter; the possible reasons have been discussed. The variations in birefringence and optical transmittance have also been presented here.

The dyeability and light fastness of amino azobenzene derivatives disperse dye( I ) (아미노 아조벤젠계 분산염료의 염색성 및 내광성(I))

  • Choi, Chang Nam;Lim, Seung Hee;Ryu, Hee Seok;Park, Hyung In;Hong, Sung Hak
    • Textile Coloration and Finishing
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    • v.8 no.3
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    • pp.24-30
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    • 1996
  • In order to investigate the light fastness of amino azo disperse dyes, some kinds of disperse dyes were prepared and dyed to polyester fabric under the different conditions, such as single or mixture state. After the dyed fabric was irradiated with carbon arc light for several hours, the color differences and K/S values of fabric were measured. The light fastness of amino azo disperse dye was decreased by the introduction of OH group to the dye molecule. But when the amino azo dye was mixed with the anthraquinone disperse dye, the light fastness was increased. It was considered that the dye molecules were aggregated on account of hydrogen bonding via OH groups, resulting the decrease of surface area of dye molecule which might be irradiated by the light.

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The Effect of Permanent Pleats Finish on the Color Change of Acid dyed Wool Fabrics (Permanent Pleats 가공이 산성염료로 염색된 모직물의 색변화에 미치는 영향)

  • Yoo Hwa Sook;Kim Eun Ae
    • Journal of the Korean Society of Clothing and Textiles
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    • v.13 no.4
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    • pp.380-387
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    • 1989
  • The Purpose of this study was to investigate the color changes of acid dyed wool fabrics after imparting permanent pleats with si-ro-set finish. Monoethanolamine sulfite was used as a reducing agent. Color changes were determined by measuring CIELAB values after treating the dyed fabrics with various setting temperatures, times and concentrations of MEAS. Setting temperature affected the color changes: in the order of $150^{\circ}C>130^{\circ}C>170^{\circ}C$ Setting time had a tendency to increase the color change. As the concentration of MEAS increased, $\delta$ E was increased. Azo dye was more affected than anthraquinone dye by MEAS treatment. Color changes were mainly due to $\delta$ L.

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