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http://dx.doi.org/10.5764/TCF.2013.25.1.13

Anthraquinone-carbamodithiolate Assembly as Selective Chromogenic Chemosensor for Fe3+  

Bae, Jin-Seok (Department of Textile System Engineering, Kyungpook National University)
Gwon, Seon-Yeong (Department of Advanced Organic Materials Science and Engineering, Kyungpook National University)
Kim, Sung-Hoon (Department of Textile System Engineering, Kyungpook National University)
Publication Information
Textile Coloration and Finishing / v.25, no.1, 2013 , pp. 13-17 More about this Journal
Abstract
A new assembly derived from 2,3-dibromo-5,6,7,8-tetrafluoroquinizarin and sodium diethyl-carbamodithiolate, was prepared as an efficient $Fe^{3+}$ colorimetric chemosensor with high selectivity over other cations $Fe^{3+}$, $Na^+$, $Mg^{2+}$, $Pb^{2+}$, $Cd^{2+}$, $Ni^{2+}$, $Ca^{2+}$, $Cu^{2+}$, $Hg^{2+}$, $Zn^{2+}$ : from the dark blue to brown color change that is visible by eyes. This assembly produced large bathochromic shift of 228 nm in the presence of $Fe^{3+}$ compared with the corresponding absorption maximum of the parent dye.
Keywords
anthraquinone; $Fe^{3+}$ sensing; colorimetric; chemosensor; carbamodithiolate; intramolecular charge-transfer dye;
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Times Cited By KSCI : 2  (Citation Analysis)
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