• Title/Summary/Keyword: anode materials

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A Electrochemical Study on the Effect of Post-Weld Heat Treatment about Corrosion Resistance Property of SS400 Steel for Ship's Materials (선박재료용 SS400강의 내식성에 대한 용접후열처리효과에 관한 전기화학적 연구(I))

  • 김진경
    • Journal of Advanced Marine Engineering and Technology
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    • v.23 no.6
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    • pp.806-813
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    • 1999
  • The effect of Post-Weld Heat Treatment(PWHT) of SS400 Steel was investigated with parameters such as micro vickers hardness corrosion potential polarization behaviors galvanic current Al anode generating current Al anode weight loss etc. Hardness of each parts(HAZ, BM, WM)by PWHT is lower than that of each parts by Non Post-Weld Heat Treatment(NPWHT) However hardness of WM of HAZ part was the highest among those three parts and HAZ area were also acted as cathode without any case of heat treatment. Potential difference between each three parts by PWHT was also smaller compared to NPWHT. Therefore it is suggested that Corrosion resistance property is increased by PWHT. However both Al anode generating current and anode weight loss was also decreased by PWHT compared to NPWHT when SS400 steel is cathodically protected by Al anode.

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Electric Conduction Properties of NaCl Electrolyte as a Function of Electrode Materials (전극재료에 따른 NaCl 전해질의 전기전도특성)

  • Kim, Yong-Hyuk
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.11
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    • pp.2026-2031
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    • 2010
  • The electrical characteristics of galvanic cell which is composed of the cathode electrode(graphite, carbon and copper) and the anode electrode(Zn and Mg) were investigated. For this research as electrolyte 2~12 wt% NaCl aqueous solution were used. At graphite cathode electrodes which use Zn and Mg with the anode electrode, the open circuit voltage was 1.3V most highly. The maximum output power increased as the electrolyte concentration increased, due to a increase in ion density. When Zn and Mg with the anode electrode, the maximum output power respectively was evaluated as 2.2mW and 5.5mW about the graphite cathode electrode in the NaCl 4wt%. The research results indicated that the output power of cell which is composed with graphite with the cathode and Mg with the anode was most excellent and the efficiency of the cell could be enhanced by increasing the electrolyte concentration.

Fundamental Studies of the Electrical Characteristics of the Glow Discharge for the Development of HPLC Detector (글로우방전을 이용한 액체크로마토그라피 검출기 개발을 위한 기초특성연구)

  • 이현주;김효진
    • YAKHAK HOEJI
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    • v.39 no.4
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    • pp.427-432
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    • 1995
  • The plasma oscillation has been observed in an argon pressure between a tungsten anode and cathode consisting of an aqueous conducting solution. The effects of experimental parameters on the electrical characteristics of the glow discharge have been studied. The experimental parameters include the anode-cathode distance, pressure, methanol flow rate, and cathode materials. The glow discharge with liquid cathode and solid anode showed the potential sensitive detector for HPLC

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Electrochemical Characteristics of Carbon-coated Si/Cu/graphite Composite Anode

  • Kim, Hyung-Sun;Chung, Kyung-Yoon;Cho, Won-Il;Cho, Byung-Won
    • Bulletin of the Korean Chemical Society
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    • v.30 no.7
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    • pp.1607-1610
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    • 2009
  • The carbon-coated Si/Cu powder has been prepared by mechanical ball milling and hydrocarbon gas decomposition methods. The phase of Si/Cu powder was analyzed using X-ray diffraction (XRD), dispersive Raman spectroscopy, electron probe microanalysis (EPMA) and transmission electron microscope (TEM). The carbon-coated Si/Cu powders were used as anode active material for lithium-ion batteries. Their electrochemical properties were investigated by charge/discharge test using commercial LiCo$O_2$ cathode and lithium foil electrode, respectively. The surface phase of Si/Cu powders consisted of carbon phase like the carbon nanotubes (CNTs) with a spacing layer of 0.35 nm. The carbon-coated Si/Cu/graphite composite anode exhibited a higher capacity than commercial graphite anode. However, the cyclic efficiency and the capacity retention of the composite anode were lower compared with graphite anode as cycling proceeds. This effect may be attributed to some mass limitations in LiCo$O_2$ cathode materials during the cycling.

Characteristics of Amorphous IZO Anode Films for Polymer OLEDs Grown by Box Cathode Sputtering (박스 캐소드 스퍼터로 성장시킨 고분자 유기발광소자용 비정질 IZO 애노드 박막의 특성)

  • Moon Jong-Min;Bae Jung-Hyeok;Jung Soon-Wook;Kim Han-Ki
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.6
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    • pp.552-557
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    • 2006
  • Electrical, optical, surface, and structural properties of amorphous indium-zinc-oxide (a-IZO) grown by box cathode sputtering (BCS) were compared with crystalline indium-tin-oxide (c-ITO) anode films grown by conventional DC sputtering (DCS). Although x-ray diffraction plot of BCS-grown IZO film shows amorphous structure, the optical and electrical properties of a-IZO is comparable to those of c-ITO film. In particular, BCS-grown IZO films shows very smooth surface without defects such as pin hole and cracks because most of the energy of the sputtered atoms was confined in high density plasma region in box cathode gun. Furthermore polymer organic light emitting diodes (POLED) with the a-IZO anode film shows better electrical properties than that of POLED with the c-ITO anode film due to high work function and smooth surface of a-IZO. This suggested that BCS-grown a-IZO film is promising anode materials substituting conventional c-ITO anode in OLED and flexible displays.

Direct-Write Fabrication of Solid Oxide Fuel Cell by Robo-Dispensing (로보 디스펜싱을 이용하여 직접묘화방식으로 제조된 고출력 소형 고체산화물 연료전지)

  • Kim, Yong-Bum;Moon, Jooho;Kim, Joosun;Lee, Jong-Ho;Lee, Hae-Weon
    • Journal of the Korean Ceramic Society
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    • v.42 no.6 s.277
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    • pp.425-431
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    • 2005
  • Line Shaped Solid Oxide Fuel Cell (SOFC) with multilayered structure has been fabricated via direct-writing process. The cell is electrolyte of Ni-YSZ cermet anode, YSZ electrolyte and LSM cathode. They were processed into pastes for the direct writing process. Syringe filled with each electrode and electrolyte paste was loaded into the computer-controlled robe-dispensing machine and the paste was dispensed through cylindrical nozzle of 0.21 mm in diameter under the air pressure of 0.1 tow onto a moving plate with 1.22 mm/s. First of all, the anode paste was dispensed on the PSZ porous substrate, and then the electrolyte paste was dispensed. The anode/electrolyte and the PSZ substrate were co-fired at $1350^{\circ}C$ in air atmosphere for 3 h. The cathode layer was similarly dispensed and sintered at $1200^{\circ}C$ for 1 h. All the electrode/electrolyte lines were visually aligned during the direct writing process. The effective reaction area of fabricated SOFC was $0.03 cm^2$, and the thickness of anode, electrolyte and cathode was 20 $\mu$m, 15 $\mu$m, and 10 $\mu$m, respectively. The single line-shaped SOFC fabricated by direct-writing process exhibited OCV of 0.95 V and maximum power density of $0.35W/cm^2$ at $810^{\circ}C$.

Preparation of Electrolytic Tungsten Oxide Thin Films as the Anode in Rechargeable Lithium Battery (리튬 이차전지용 텅스텐 산화물 전해 도금 박막 제조)

  • Lee, Jun-Woo;Choi, Woo-Sung;Shin, Heon-Cheol
    • Korean Journal of Materials Research
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    • v.23 no.12
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    • pp.680-686
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    • 2013
  • Tungsten oxide films were prepared by an electrochemical deposition method for use as the anode in rechargeable lithium batteries. Continuous potentiostatic deposition of the film led to numerous cracks of the deposits while pulsed deposition significantly suppressed crack generation and film delamination. In particular, a crack-free dense tungsten oxide film with a thickness of ca. 210 nm was successfully created by pulsed deposition. The thickness of tungsten oxide was linearly proportional to deposition time. Compositional and structural analyses revealed that the as-prepared deposit was amorphous tungsten oxide and the heat treatment transformed it into crystalline triclinic tungsten oxide. Both the as-prepared and heat-treated samples reacted reversibly with lithium as the anode for rechargeable lithium batteries. Typical peaks for the conversion processes of tungsten oxides were observed in cyclic voltammograms, and the reversibility of the heat-treated sample exceeded that of the as-prepared one. Consistently, the cycling stability of the heat-treated sample proved to be much better than that of the as-prepared one in a galvanostatic charge/discharge experiment. These results demonstrate the feasibility of using electrolytic tungsten oxide films as the anode in rechargeable lithium batteries. However, further works are still needed to make a dense film with higher thickness and improved cycling stability for its practical use.

Development of Electrode Materials for Li-Ion Batteries and Catalysts for Proton Exchange Membrane Fuel Cells (리튬 이차전지용 전극 및 연료전지 촉매 소재 연구 개발 동향)

  • Yun, Hongkwan;Kim, Dahee;Kim, Chunjoong;Kim, Young-Jin;Min, Ji Ho;Jung, Namgee
    • Ceramist
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    • v.21 no.4
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    • pp.388-405
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    • 2018
  • In this paper, we review about current development of electrode materials for Li-ion batteries and catalysts for fuel cells. We scrutinized various electrode materials for cathode and anode in Li-ion batteries, which include the materials currently being used in the industry and candidates with high energy density. While layered, spinel, olivine, and rock-salt type inorganic electrode materials were introduced as the cathode materials, the Li metal, graphite, Li-alloying metal, and oxide compound have been discussed for the application to the anode materials. In the development of fuel cell catalysts, the catalyst structures classified according to the catalyst composition and surface structure, such as Pt-based metal nanoparticles, non-Pt catalysts, and carbon-based materials, were discussed in detail. Moreover, various support materials used to maximize the active surface area of fuel cell catalysts were explained. New electrode materials and catalysts with both high electrochemical performance and stability can be developed based on the thorough understanding of earlier studied electrode materials and catalysts.

Effect of a Reciprocating Paddle on the Electrodeposit Uniformity of Patterned Cathodes (왕복패들이 패턴화된 음극의 전착균일성에 미치는 영향)

  • Oh Young-joo;Chung Soon-hyo
    • Korean Journal of Materials Research
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    • v.14 no.3
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    • pp.196-202
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    • 2004
  • A numerical simulation based on the finite element method is used to investigate the effect of a reciprocal paddle on the uniformity of deposition rates at a patterned electrode. The calculated deposition rates agreed well with the measured values. The influences of the paddle velocity, the gap between cathodes and paddles, anode size and the distance between the anode and cathode have been studied. The optimum conditions on the paddle and geometric factors for electrodeposit uniformity could be obtained.

The Lithium Ion Battery Technology

  • Lee, Ki-Young
    • Carbon letters
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    • v.2 no.1
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    • pp.72-75
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    • 2001
  • The performance of Li-ion system based on $LiCoO_2$ and Graphite is well optimized for the 3C applications. The charge-discharge mode, the manufacturing process, the cell performance and the thermal reactions affecting safety has been explained in the engineering point of view. The energy density of the current LIB system is in the range of 300~400 Wh/l. In order to achieve the energy density higher than 500 Wh/l, the active materials should be modified or changed. Adopting new high capacity anode materials would be effective to improve energy density.

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