• Title/Summary/Keyword: annealing ambient

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High-k Gate Dielectric for sub-0.1$\mu\textrm{m}$ MOSFET (차세대 sub-0.1$\mu\textrm{m}$급 MOSFET소자용 고유전율 게이트 박막)

  • 황현상
    • Proceedings of the IEEK Conference
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    • 2000.06b
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    • pp.20-23
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    • 2000
  • We have investigated a process for the preparation of high-quality tantalum oxynitride ( $T_{a}$ $O_{x}$ $N_{y}$) via the N $H_3$ annealing of 7$_{a2}$ $O_{5}$, for use in gate dielectric applications. Compared with tantalum oxide (7$_{a2}$ $O_{5}$), a significant improvement in the dielectric constant was obtained by the N $H_3$ treatment. In addition, light reoxidation in a wet ambient at 45$0^{\circ}C$ resulted in a significantly reduced leakage current. We confirmed nitrogen incorporation in the tantalum oxynitride ( $T_{a}$ $O_{x}$ $N_{y}$ by Auger Electron Spectroscopy. By optimizing the nitridation and reoxidation process, we obtained an equivalent oxide thickness as thin as 1.6nm and a leakage current of less than 10mA/$\textrm{cm}^2$ at 1.5V..5V..5V..5V..5V..5V.

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선형대향타겟 스퍼터를 이용하여 성막시킨 InSnTiO 박막의 특성 연구

  • Sin, Hae-In;Kim, Han-Gi
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.245-245
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    • 2016
  • 본 연구에서는 선형 대향 타겟 스퍼터 (Linear Facing Target Sputtering: LFTS) 시스템을 이용하여 ITO와 Ti doped $In_2O_3$ (TIO) 타겟을 Co-sputtering한 InSnTiO 투명 전극의 전기적, 광학적 특성을 연구하였다. InSnTiO 투명전극의 전기/광학적 및 구조적 특성은 Hall measurement, UV/Vis spectrometry, X-ray Diffraciton 분석법을 통해 최적화 하였고, DC power, substrate to target distance (TSD), target to target distance (TTD), ambient treatment 변수 조절을 통해 최적화된 LFTS InSnTiO 투명전극을 제작하였다. LFTS 공정을 이용한 InSnTiO 투명전극의 성막 공정 중 DC파워와 공정압력 변화에 따른 구조적, 표면적 특성 변화는 Field-Emission Scanning Electron Microscopy (FE-SEM) 과 X-ray Diffractometer (XRD) 분석을 통해 관찰하였다. 이렇게 증착된 InSnTiO 투명전극은 급속열처리 시스템으로 (Rapid Thermal Annealing system) 후열처리를 진행하여 투과도의 향상과 면저항의 감소를 확인하였다. 본 연구에서는 다양한 분석을 통해 Co-sputtering한 InSnTiO 박막의 특성과 다양한 장점을 소개한다.

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Hall mobility in $Si_{1-x}Ge_{x}$/Si structure ($Si_{1-x}Ge_{x}$/Si 구조에서의 Hall 이동도)

  • 강대석;신창호;박재우;송성해
    • Proceedings of the IEEK Conference
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    • 1998.06a
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    • pp.453-456
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    • 1998
  • The electrical properties of $Si_{1-x}Ge_{x}$ samples have been investigated. The sample structures were grown by MBE (molecular geam epitaxy) with Ge mole-fraction of x=0.0, x=0.05, x=0.1, and x=0.2. To examine the influence of the thermal processing, the $O_{2}$ and N$_{2}$ process were performed at 800[.deg. C] and 900[.deg. C], respectively. After this thermal process, hall measurements have been done over a wide range of the ambient temperature between 320[.deg. K] and 10[.deg. K] to find the temperature dependence using the comparessed-He gas system. The Ge-rich layer has been formed at the $SiO_{2}$/SiGe interface and it has an effect on the hall mobility. And it has been found that hall mobility was increased by the $N_{2}$ annealing process comparing with dry oxidation process at both 800[.deg.C] and900[.deg. C].

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Effect of Oxygen Contents in Thermal Annealed ZnO films on Structural and Optical Properties (열처리한 ZnO 박막 내의 산소 농도 변화에 따른 구조적, 광학적 특성 연구)

  • Lee, Ju-Young;Kim, Hong-Seung;Jung, Eun-Soo;Jang, Nak-Won
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.7
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    • pp.600-604
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    • 2005
  • We studied that structural and optical properties of ZnO films depend on oxygen contents. ZnO films were deposited on Si (111) substrates at room temperature by rf sputtering system and the thickness of films was 100 nm. The ZnO films were annealed in thermal furnace for 2 h at 800 and $900^{\circ}C$ in $H_2O,\;N_2$, and air ambient gases to control oxygen contents. We used AES, PL, XRD, AFM. As our result, crystal quality and luminescence improved until O/Zn is 1. However, when O/Zn ratio Is larger than 1, the structural and optical properties were getting worse.

Optical and textural properties of AZO:H thin films by RF magneton sputtering system with various working pressures

  • Hwang, Seung-Taek;So, Soon-Jin;Park, Choon-Bae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.165-165
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    • 2010
  • AZO:H films were prepared by RF magnetron sputtering system with a AZO (2wt% $Al_2O_3$) ceramic target at a temperature of $150^{\circ}C$. The annealing treatments were carried out in hydrogen ambient for 1hr at a temperature of $400^{\circ}C$. The AZO:H films were etched with 1 % HCl. The influence of the properties of AZO:H films deposited in various working pressures is investigated. As a result, the AZO:H film deposited in 4mTorr showed excellent electrical property of $\rho=5.036{\times}10^{-4}{\Omega}cm$ and strongly oriented (002) peak. The transmittance in the wavelength of 450nm was above 80%. It can be used as front electrode for increasing efficiency of GaN LED.

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A Study on the Properties and Formation of Mo-Silicides on Si-Substrate (Si 기판위에 Mo-silicides의 형성과 그 특성에 관한 연구)

  • 조한수;조현춘;최진성;백수현
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.28A no.1
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    • pp.85-90
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    • 1991
  • MoSi$_2$ was formed by RTA (Rapid Thermal Annealing at 600-1200$^{\circ}C$) under Ar ambient from the Mo-Si mixture film which was deposited on single and poly-Si substrates. The MoSi$_2$ film was investigated by SEM, X-ray diffractometer, four-points probe and AES profile. It was found that the resistivity, the surface roughness, and the formation temperature of MoSi$_2$ were independent on the type of Si substrates. The formation of MoSi$_2$ started from 800$^{\circ}C$ and the phse transformation was completed at 1000$^{\circ}C$. The stable MoSi$_2$ with the resistivity of 74${\mu}{\Omega}$-cm was formed at 1200$^{\circ}C$.

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A Study on the double-layered dielectric films of tantalum oxide and silicon nitride formed by in situ process (연속 공정으로 형성된 탄탈륨 산화막 및 실리콘 질화막의 이중유전막에 관한 연구)

  • 송용진;박주욱;주승기
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.30A no.1
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    • pp.44-50
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    • 1993
  • In an attempt to improve the electrical characteristics of tantalum pentoxide dielectric film, silicon substrate was reacted with a nitrogen plasma to form a silicon nitride of 50.angs. and then tantalum pentoxide thin films were formed by reactive sputtering in the same chamber. Breakdown field and leakage current density were measured to be 2.9 MV/cm and 9${\times}10^{8}\;A/cm^{2}$ respectively in these films whose thickness was about 180.angs.. With annealing at rectangular waveguides with a slant grid are investigated here. In particular, 900.deg. C in oxygen ambient for 100 minutes, breakdown field and leakage current density were improved to be 4.8 MV/cm and 1.61.6${\times}10^{8}\;A/cm^{2}$ respectively. It turned out that the electrical characteristics could also be improved by oxygen plasma post-treatment and the conduction mechanism at high electric field proved to be Schottky emission in these double-layered films.

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Annealing effect of Si nanocrystallites thin films (실리콘 나노결정 박막의 후열처리 효과 연구)

  • Jeon, Kyung-Ah;Kim, Jong-Hoon;Choi, Jin-Baek;Lee, Sang-Yeol
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.04a
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    • pp.88-91
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    • 2003
  • Si nanocrystallites thin films have been fabricated by pulsed laser deposition using a Nd:YAG laser. After deposition, samples were annealed at the temperature range of 400 to $800^{\circ}C$. Hydrogen passivation was then performed in the forming gas ($95%N_{2}+5%H_{2}$) at $500^{\circ}C$. Strong violet-indigo photoluminescence has been observed at room temperature on nitrogen ambient-annealed Si nanocrystallites. As a result of photoluminescence spectra and infrared absorption spectra, we conclude that the violet-indigo PL efficiency is related with oxygen vacancy in the $SiO_x$(x= 1.6-1.8) matrix.

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열처리된 HgCdTe 박막의 Geometric Phase Strain 분석법에 의한 응력 변화 연구

  • Kim, Gwang-Cheon;Choe, Won-Cheol;Kim, Hyeon-Jae;Kim, Jin-Sang
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.122-122
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    • 2011
  • HgCdTe는 고성능 적외선 센서 재료로 널리 사용되고 있다. 현재 상용화된 HgCdTe 소재는 통상적으로 액상 에피 성장법으로 제조 되고 있다. 액상 에피 성장법에 의해 제조된 HgCdTe는 갓 성장 상태에서 많은 양의 Hg-공공(vacancy)을 함유하게 되며 적외선 소자의 응용을 위해서는 이러한 Hg-공공을 채우기 위한 Hg-분위기 열처리 공정을 거치게 된다. 열처리 혹은 성장 공정 시 HgCdTe 소재 내에 발생하는 마이크로 혹은 나노스케일의 조성의 변화는 응력의 집중을 가져오며 이는 전자, 혹은 정공의 응집을 가져와 소자 동작의 불균일성을 야기한다. 본 연구에서는 액상 에피 성장법으로 성장 된 HgCdTe 박막내에 존재하는 응력의 분포와 Hg-공공을 채우기 위한 열처리 과정에서 생성 또는 소멸되는 응력의 변화를 Geometric phase strain 분석법으로 관찰하였다. 분석결과, 응력의 집중된 부분은 주로 성장 시 석출된 Te 및 Hg-공공으로 부터 기인함을 확인하였다. Hg-분위기 열처리를 통하여 석출된 Te 제거 및 Hg-공공의 감소를 확인하였고 이에 따른 응력의 집중 부분도 해소됨을 알 수 있었다.

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