• Journal of the Korean Institute of Telematics and Electronics B
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• v.31B no.3
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• pp.24-38
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• 1994

In this paper we develop the software simulator written in a C language for a frequency modulation synthesis and the approximate range of parameters, for a musically satisfactory timbre, obtained by using the software simulator will be applied to develop an algorithm for parameter extraction. For a frequency modulation synthesis, we also develop an algorithm for parameter extraction through waveform analysis in the time domain as well as spectrum analysis using a FFT in the frequency domain. To verify the validity of the developed algorithm as well as software simulator experimentally, we extract parameters for the several music instruments using the suggested algorithm and analyze the synthesized sound by applying the parameters to the software simulator. The evaluation of the synthesized sound is first done by listening the sound directly as a subjective testing. Secondly, to evaluate the synthesized sound objectively with an engineering sense, we compare the synthesized sound with an original one in a time domain and a frequency domain.

• Journal of Power System Engineering
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• v.5 no.4
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• pp.24-30
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• 2001

The substructure synthesis method(SSM) is developed for overcoming disadvantages of the Finite Element Method(FEM). The concept of the SSM is as follows. After dividing a whole structure into several substructures, every substructures are analyzed by the FEM or experiment. The whole structure is analyzed by using connecting condition and the results of substructures. The concept of the transfer stiffness coefficient method(TSCM) is based on the transfer of the nodal stiffness coefficients which are related to force vectors and displacement vectors at each node of analytical mode1. The superiority of the TSCM to the FEM in the computation accuracy, cost and convenience was confirmed by the numerical computation results. In this paper, the author suggests an efficient vibration analysis method of structures by using the TSCM and the SSM. The trust and the validity of the present method is demonstrated through the numerical results for computation models.

• International Journal of Industrial Entomology and Biomaterials
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• v.27 no.2
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• pp.298-302
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• 2013

In this study, the effect of sericin on synthesis of the silica was investigated. Using the mixture of sericin solution and tetraethyl orthosilicate (TEOS), it was confirmed that silica could be synthesized in the presence of sericin, which was verified by thermal gravimetric analysis (TGA), Fourier-transformed infrared spectrometer (FT-IR) and nuclear magnetic resonance spectrometer (NMR) analysis. The TGA and FT-IR data revealed that silica-sericin complex was formed as a final product. Based on the TGA result, the content of silica and sericin in the complex would be 87 and 13%, respectively. The degree of silica condensation was higher than the natural biosilica. It could be concluded that sericin can induce the synthesis of silica directly from TEOS, which is similar to silicatein from marine sponges.

• Journal of Institute of Control, Robotics and Systems
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• v.11 no.6
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• pp.550-557
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• 2005

The multivariate statistical analysis methods, using both multiple linear regression(MLR) and partial least square(PLS), have been applied to predict the reactor properties and the product quality of a direct esterification reactor for polyethylene terephthalate(PET) synthesis. On the basis of the set of data including the flow rate of water vapor, the flow rate of EG vapor, the concentration of acid end groups of a product and other operating conditions such as temperature, pressure, reaction times and feed monomer mole ratio, two multi-variable analysis methods have been applied. Their regression and prediction abilities also have been compared. The prediction results are critically compared with the actual plant data and the other mathematical model based results in reliability. This paper shows that PLS method approach can be used for the reasonably accurate prediction of a product quality of a direct esterification reactor in PET synthesis process.

• Applied Chemistry for Engineering
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• v.28 no.3
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• pp.286-289
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• 2017

Synthesis of zeolite 4A was carried out to optimize the nanoparticle synthesis process using statistical experimental design method. The zeolite 4A was synthesized by controlling the concentration of the silicon precursor, sodium metasilicate (SMS), and characterized by XRD, SEM and nitrogen adsorption. In particular, the property of zeolite 4A can be determined by XRD analysis. Using the general factor analysis in the design of experiments, we analyzed main effects and interactions according to the reactor, reaction temperature and reaction time. The optimum reaction condition for the synthesis of zeolite 4A crystallinity was using an autoclave for 3 hours at $110^{\circ}C$. Furthermore, the optimal synthesis conditions of zeolite 4A with various crystallinity using Ludox as a silicon precursor were presented of what using both the surface and contour plot.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.16 no.7 s.112
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• pp.712-719
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• 2006

This paper is concerned with the comparison of substructure synthesis methods based on global and local coordinates. The substructure synthesis methods based on the global coordinates were first proposed for the dynamic analysis of complex structure and the substructure synthesis method based on the local coordinates was proposed to solve the dynamic problem of tree-like structure. However, the conceptual difference between two methods in solving the dynamic problem has never been explained. In this paper, a structure consisting of two beams is considered to show the conceptual difference of two methods. The dynamic formulation shows the characteristics and differences of two methods explicitly. The procedure for choosing proper substructure modes in each method is also explained in detail. In addition, the advantage of the substructure synthesis method based on the local coordinate system is discussed based on the numerical example. Numerical examples show how two methods are applied to the addressed problem.

• Advances in nano research
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• v.2 no.2
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• pp.77-88
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• 2014

Solvothermal treatment of late transition metal acetylacetonates in a novel medium composed either of pure acetophenone or acetophenone mixtures with amino alcohols offers a general approach to uniform hydrophilic metal nanoparticles with high crystallinity and low degree of aggregation. Both pure metal and mixed-metal particles can be accesses by this approach. The produced materials have been characterized by SEM-EDS, TEM, FTIR in the solid state and by Nanoparticle Tracking Analysis in solutions. The chemical mechanisms of the reactions producing nanoparticles has been followed by NMR. Carrying out the process in pure acetophenone produces palladium metal, copper metal with minor impurity of $Cu_2O$, and NiO. The synthesis starting from the mixtures of Pd and Ni acetylacetonates with up to 20 mol% of Pd, renders in minor yield the palladium-based metal alloy along with nickel oxide as the major phase. Even the synthesis starting from a mixed solution of $Cu(acac)_2$ and $Ni(acac)_2$ produces oxides as major products. The situation is improved when aminoalcohols such as 2-aminoethanol or 2-dimethylamino propanol are added to the synthesis medium. The particles in this case contain metallic elements and pairs of individual metals (not metal alloys) when produced from mixed precursor solutions in this case.

• Proceedings of the Acoustical Society of Korea Conference
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• 1998.06c
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• pp.147-150
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• 1998

In the case of speech synthesis, the waveform coding method with high quality is mainly used to the synthesis by analysis. Because the parameters of this coding method are not classified as both excitation and vocal tract parameters, it is difficult to apply the waveform coding method to the synthesis by rule. Thus, in order to apply the waveform coding method to the synthesis by rule, a pitch alteration is required for the prosody control. In the speech synthesis method by the conventional PSOLA technique, applying symmetric window function to asymmetric speech waveform, it occurs the unbalance phenomenon of energy according to the overlapped degree of pitch interval adjustment. In this paper to overcome the unbalance phenomenon of energy, we proposed a new method that can convert asymmetric waveform to symmetric one by time-frequency conversion. As a result, we can obtain an average spectrum distortion ratio with 6.38% according to the pitch alteration ratio.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2001.11a
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• pp.161-166
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• 2001

This study intends to reduce the weight of structure without changing the dynamic characteristics. At first, the Vibration analyses by the Substructure Synthesis Method and FEM using the ANSYS are performed for the engine speed converter to confirm the reliability of the analyzing tools. Weight minimization is performed by the Sensitivity Analysis and the Optimum Structural Modification. To decrease the converter weight ideally, the parts with low sensitivity are to be cut mainly, and the changing quantity of the natural frequency by the cut is to be recovered by the weight modification of the parts with high sensitivity. As the unique mathematical solution for the homogeneous problem( i.e. 0 object function problem) does not exist, the converter is redesigned with much thinner initial thickness. The goal of this study is to recover the dynamic characteristics of redesigned structure to those of the original one. To say in the other words, the modified structure has the same dynamic characteristics and the more lighter weight to compare with the original one. In this analysis, the modification was performed with the redesigned initial thickness of 60 mm and 70 mm. And the numbers of the interesting natural frequencies are 1, 2, 4 respectively. Consequently 27％ of weight reduction effects were earned.

• Resources Recycling
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• v.18 no.6
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• pp.18-23
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• 2009

An investigation on the synthesis of aluminum citrate, one of the aluminum organic compounds, has been performed using aluminum chloride solutions as a starting material. For the synthesis of aluminum citrate, citric acid was added to aluminum solutions with the mole ratio of citric acid to aluminum to be 2.5 and aluminum citrate synthesized was also characterized in terms of chemical analysis, X-ray diffraction, particle size measurement and SEM analysis. As a result, it was found that the ratio of ethanol/Al solution more than 4.0 was required for the synthesis of aluminum citrate from aluminum solutions. Furthermore, the pH should be controlled to be more than 7.0 in order to obtain the recovery of aluminum citrate higher than 97%. From the chemical analysis of aluminum citrate synthesized in this work, the content of $NH_4$, Al and C was found to be 17.0, 4.01 and 25.7%, respectively. Accordingly, the aluminum citrate synthesized from aluminum solutions was confirmed to be $(NH_4)_5Al(C_6H_4O_7)_2{\cdot}2H_2O$.