• 한국자기학회지
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• 제5권5호
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• pp.767-771
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• 1995

The atomic structure and magnetic properties of $LaCo_{13}$ amorphous alloy have been investigated and compared with those of its crystalline counterpart. It has been confirmed that the amorphous alloy is composed of the icosahedral clusters with a $NaZn_{13}$-type structure. The magnetic moment and the spin- wave stiffness constant obtained from the magnetic measurements in the amorphous state are larger than those in the crystalline state. The Curie temperature estimated from the reduced magnetization curve for the former is much higher than the value for the latter. The localized magnetic moment character in the amorphous state is stronger than that in the crystalline state.

• 한국기계가공학회지
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• 제21권4호
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• pp.77-83
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• 2022

Amorphous alloys exhibit excellent mechanical properties; therefore, application technology development is being attempted in various fields. However, industrial use of application technology is limited owing to the limitations in fabrication. In this study, micropattern fabrication of an amorphous alloy was conducted using laser beam machining. Although microhole fabrication is possible without the deformation of the amorphous phase through nanosecond pulsed laser beam machining, there are limitations in the generation of recast layers and spatters. In cover plate laser beam machining (c-LBM), a cover plate is used to reduce the thermal deformation and processing area. Therefore, it is possible to fabricate holes at the level of several micrometers. In this study, it was confirmed that recast layers are hardly generated in c-LBM. Furthermore, square-shaped micropatterns were successfully fabricated using c-LBM.

• Journal of Magnetics
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• 제4권1호
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• pp.10-12
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• 1999

We report the salient features of the magnetic properties of amorphous$ Fe_{84-x}Nb_7B_{8+x}Cu_1$ (x=0, 1, 4) alloys. The study of dc-magnetization properties and the ac-susceptibility was carried out. The temperature dependence of the magnetization follows the predictions of spin wave excitations with long wavelengths. Especially, the addition of boron modifies the magnetic properties: the spin wave stiffness increases from 56.8 to 65.7 meV$\AA$2 and Curie temperature increases from 298 K to 352 K. This result indicates a magnetic hardening of the exchange interaction by higher exchange energy. Thus, the substitution of iron by boron favours the increase of magnetic order in this system.

• Bulletin of the Korean Chemical Society
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• 제17권7호
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• pp.621-625
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• 1996

A variety of metal oxides were coated by sol-gel process from their metal alkoxides on the ribbons of Co-based and Fe-based amorphous alloys, and the effects of surface oxide coating on the magnetic properties of the alloy are investigated. The core loss is found to be reduced significantly by the oxide coating, the loss reduction becoming more prominent at higher frequencies. The shape of the hystersis loop is also dependent upon the kind of the coated metal oxide. The coatings of MgO, SiO2, MgO·SiO2 and MgO·Al2O3 induce tensile stress into the Fe-based ribbon whereas those of BaO, Al2O3, CaO·Al2O3, SrO·Al2O3 and BaO·Al2O3 induce compressive stress. These results may be explained by the modification of domain structures via magnetoelastic interactions with the shrinkage stress induced by the sol-gel coating.

• 한국자기학회지
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• 제5권5호
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• pp.762-766
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• 1995

The coercive field $H_{c}$ of amorphous Y-Fe alloys in the spin-glass state has been investigated. Foramorphous $Y_{10}Fe_{90}$ alloy, the thermal variations of $H_{c}$ in the maximum external field $H_{max}=300,\;600$ and 1 k Oe exhibit a maximum. Since spin-glass behavior is strongly affected by external magnetic fields, the maximum point moves to lower temperature with increasing $H_{max}$. The appearance of the maximum in $H_{c}$ has been discussed in terms of the change of the spin-glass state in the external magnetic field. When the value of $H_{max}$ is 55 kOe, the temperature dependence of $H_{c}$ has no maximum and shows an exponential decrease with increasing temperature. Similar trends have been observed over a wide concentration range. The concentration dependence of $H_{c}$ is associated with the magnetic phase diagram.

• Journal of Magnetics
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• 제10권4호
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• pp.142-144
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• 2005

The Magnetization behaviour has been measured for amorphous $Fe_{80-x}Mn_xZr_{10}$ (x = 4,6,8,10) alloys. The Curie temperature decreased from 236 K to 195 K with increasing Mn concentration (x = 4 to x = 10). The magnetization measurements were conducted at temperatures above the Curie temperature in the paramagnetic region. In all samples, the magnetic properties showed superparamagnetic behavior above $T_c$ where the mean magnetic moment of the superparamagnetic spin clusters decreased with increasing temperature. A large magnetic entropy change, ${\Delta}S_M$, which is calculated from H vs M curves associated with the ferromagnetic-paramagnetic transitions in amorphous, has been observed. With Mn concentration increasing, ${\Delta}S_M$ decreases 1.04, 0.95, 0.87 J/kg K at 222, 210, 195 K (the Curie temperature), respectively.

• Transactions on Electrical and Electronic Materials
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• 제12권1호
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• pp.20-23
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• 2011

Amorphous Ti-(50-x)Ni-xCu (at%) (x = 20, 25, 27, 30) alloy ribbons were prepared by melt spinning. Subsequently, the crystallization behavior of the alloy ribbons was investigated by X-ray diffraction and differential scanning calorimetry. ${\Delta}T$ (the temperature gap between $T_g$ and $T_x$) increased from 33 K to 47 K and the wavenumber ($Q_p$) decreased from 29.44 $nm^{-1}$ to 29.29 $nm^{-1}$ with increasing Cu content from 20 at% to 30 at%. The activation energy for crystallization decreased from 188.5 kJ/mol to 170.6 kJ/mol with increasing Cu content from 20 at% to 25 at%; afterwards, the activation energy remained near constant. Crystallization occurred in two-stage: amorphous-B2-$TiCu_2$ in Ti-Ni-Cu alloys with Cu content less than 25 at%, while it occurred in three-stage; amorphous-B2-TiCu-$TiCu_2$ in Ti-Ni-Cu alloys with Cu content more than 27 at%.

• 한국자기학회:학술대회 개요집
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• 한국자기학회 1998년도 춘계연구발표회 논문개요집
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• pp.110-111
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• 1998

• 한국자기학회:학술대회 개요집
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• 한국자기학회 1993년도 추계연구발표회 논문개요집
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• pp.76-77
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• 1993

• 한국자기학회:학술대회 개요집
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• 한국자기학회 1993년도 추계연구발표회 논문개요집
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• pp.74-75
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• 1993