• Journal of the Korea Organic Resources Recycling Association
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• v.21 no.2
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• pp.71-78
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• 2013

This study examined the feasibility of phosphorus removal from dewatering centrate/filtrate in wastewater treatment by struvite formation. Since dewatering centrate/filtrate obtained after anaerobic digestion contains a high content of ammonia, magesium addition and pH adjustment could remove phosphorous. The optimum magnesium dose, reaction time, settling time, and pH value was found at 2 mol Mg/mol $PO_4^{3-}$, 10 min, 120 min, and 8.5, respectively. A bench-scale continuous operation at the optimum condition showed 80% of total phosphorus removal and 82% of phosphate removal in dewatering centrate. The elemental composition and crystal structure of the chemical precipitate was similar to the reported values of struvite.

• Journal of Microbiology and Biotechnology
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• v.10 no.4
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• pp.455-461
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• 2000

Abstract Spirulina platensis was grown in SWlUe waste to reduce inorganic compowlds and simultaneously produce feed resources. Spirulina platensis prefers nitrogenous compounds in Ibe order: $NH_4^{+}-N>NO_3^{-}-N>simple-N$ such as urea and simple amino acids. It even consumes $NH_4^{+}-N$ first when urea or nitrate are present. Therefore, the content of residual $NH_4^{+}-N$ in Spimlina platensis cultures can be determined by the relative extent of the following processes: (i) algal uptake and assimilation; (ii) ammonia stripping; and (iii) decomposition of urea to NH;-N by urease-positive bacteria. The removal rates of total nitrogen ffild total phosphorus were estimated as an indicator of the treatment effIciency. It was found that Spirulina platensis was able to reduce 70-93% of $P_4^{3-}-P$, 67-93% of inorganic nitrogen, 80-90% of COD, and 37-56% of organic nitrogen in various concentrations of swine waste over 12 days of batch cultivation. The removal of inorganic compounds from swine waste was mainly used for cell growth, however, the organic nitrogen removal was not related to cell growlb. A maximum cell density of 1.52 dry-g/l was maintained with a dilution rate of 0.2l/day in continuous cultivation by adding 30% swine waste. The nitrogen and phosphorus removal rates were correlated to the dilution rates. Based on the amino acid profile, the quality of the proteins in the Spirulina platensis grown in the waste was the same as that in a clean culture.ulture.

• Environmental Engineering Research
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• v.25 no.2
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• pp.135-146
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• 2020

This study was aimed to investigate the possibility of using raw and anaerobically-digested piggery wastewater as culture media for a green microalga Chlorella vulgaris (C. vulgaris). Due to high concentration of ammonia and dark color, the microalga did not grow well in this wastewater. In order to solve this problem, air stripping and NaOCl-treatment were applied to reduce the concentration of NH₃-N and the color intensity from the wastewater. Algal growth was monitored in terms of specific growth rate, biomass productivity, and nutrient removal efficiency. As a result, C. vulgaris grew without any sign of inhibition in air-stripped and 10-folds diluted anaerobically-digested piggery wastewater with enhanced biomass productivity of 0.57 g/L·d and nutrient removal of 98.7-99.8% for NH₃-N and 41.0-62.5% for total phosphorus. However, NaOCl-treatment showed no significant effect on growth of C. vulgaris, although dark color was removed greatly. Interestingly, despite that the soluble organic concentration after air stripping was still high, the biomass productivity was 4.4 times higher than BG-11. Moreover, air stripping was identically effective for raw piggery wastewater as for anaerobic digestate. Therefore, it was concluded that air stripping was a very effective method for culturing microalgae and removing nutrients from raw and anaerobically-digested piggery wastewaters.

• Journal of the Korean Applied Science and Technology
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• v.34 no.3
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• pp.436-442
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• 2017

This study was conducted to develop a wastewater treatment system to remove organic matter, nitrate nitrogen, and phosphate ion in synthetic wastewater. COD was removed almost 100% by the oxidation reaction of HClO and nitrate nitrogen was reduced to ammonia by electrolysis treatment, but ammonia was reoxidized into nitrate nitrogen by HClO treatment. Ammonia was removed almost 100% by heating evaporation and no ammonia was reoxidized into nitrate by HClO treatment. Phosphate ion could be removed by precipitation treatment by forming metal complex according to pH. Through electrolysis treatment and HClO treatment, removal efficiencies of COD 99.5%, nitrogen 97.3% and phosphorus 91.5% were obtained.

• Journal of Korean Society on Water Environment
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• v.22 no.2
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• pp.203-208
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• 2006

A continuous feed and cyclic draw SBR process was developed to overcome flow rate fluctuation and to maximize organic matters utilization efficiency for nitrogen and phosphorus removal. The developed SBR process was operated with two parallel reactors. Influent was supplied to one reactor which was not obligately aerated. At the same time, the other reactor was just aerated without supplying influent. In addition this mode was changed periodically. Cycle time was 6hr and aeration time ratio($t_{aer}/t_{total}$) was 0.33, respectively. $COD_{cr}$ and SS removal efficiencies of 95% or higher were achieved. Nitrogen removal was so greatly influenced by influent $COD_{cr}/T-N$ ratio. At influent $COD_{cr}/T-N$ ratio of 5.7, removal efficiencies of ammonia-N, T-N and T-P were 96%, 78% and 55%, respectively. Influent $COD_{cr}/T-N$ of 4 or higher ratio was necessary to achieve 60% or higher nitrogen removal. Organic matters of influent was efficiently utilized in denitrification reaction and consumed COD has a good correlation with removed T-N(about 6.5 mgCOD/mgTN). Continuous feed and cyclic draw SBR process could be one of alternative processes for the removal of nutrients in rural area where $COD_{cr}/T-N$ ratio was low and fluctuation of flow rate was severe.

• Environmental Engineering Research
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• v.11 no.3
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• pp.134-142
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• 2006

The treatment of high-strength swine wastewater by anaerobic digestion combined with an aquatic plant system was investigated. Anaerobic digestion of swine wastewater gave volatile solids (VS) removal efficiencies of 43.3%, 52.1% and 54.5% for hydraulic retention times (HRTs) of 20, 30, 40 days, respectively. The removal efficiencies of VS, total chemical oxygen demand (TCOD) and soluble chemical oxygen demand (SCOD) decreased with increasing VS volumetric loading rate (VLR). Higher organic removal efficiency was observed at longer HRTs for the same VS volumetric loading rate. As VS volumetric loading rate increased, biogas production increased and the methane content of the biogas decreased. Experiments using duckweed (Lemna species) as an aquatic macrophyte gave the following results. In the case of nitrogen, removal efficiency was above 60% and effluent concentration was below 10.0 mg/L when the influent ammonia-N loading was about $1.0\;g/m^2/day$. In the case of phosphorus, removal efficiency was above 55% and effluent concentration was below 2.0 mg/L when the influent $PO_4$-P loading was about $0.15\;g/m^2/day$. In addition, crude protein and phosphorus content of duckweed biomass increased from 15.6% to 41.6% and from 0.8% to 1.6%, respectively, as the influent nutrient concentration increased. The treatment of high-strength swine wastewater by anaerobic digestion combined with an aquatic plant system offers good performance in terms of organics and nutrient removal for relatively low operation and maintenance costs. The results indicate that under appropriate operational conditions, the effluent quality is within the limits set by Korean discharge criteria.

• Progress in Superconductivity and Cryogenics
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• v.23 no.3
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• pp.20-25
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• 2021

Milking parlor wastewater contains high concentration suspended solid (SS), nitrogen, and/or phosphate as well as organic compounds. A new biological wastewater process by magnetic separation, magnetic activated sludge (MAS) process, was applied to milking parlor wastewater treatment process. A three step wastewater treatment process of coagulation sedimentation / ammonia stripping (C/S), magnetic activated sludge process and contact oxidation (CO) was proposed for removal of these pollutants. First step, C/S process recovered 96% TN and 96% PO₄^3--P as resource for fertilizer from the wastewater. 81% biochemical oxygen demand (BOD) in wastewater was removed after MAS process. As a results, all pollutant concentrations satisfied Japanese effluent standards. Most of residual BOD and SS were removed by the CO process. It was estimated that the proposed process could reduce the process space to 1/7.

• Environmental Engineering Research
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• v.20 no.3
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• pp.277-284
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• 2015

Experiments for highly concentrated contaminants in pig waste slurry were carried out for the feasibility test of a pilot-scale innovative process scheme of engaging autothermal thermophilic aerobic digestion (ATAD) and expended granular sludge bed (EGSB) followed by sequencing batch reactor (SBR) system. Contaminants in pig waste slurry such as organic substance, total nitrogen (TN), ammonia nitrogen and total phosphorus (TP) contents were successfully reduced in the system. Total volatile solids (TVS) and chemical oxygen demands (COD) for organic matter in the feed were 32.92 g/L and 42.55 g/L respectively, and they were reduced by about 98.7% and 99.2%, respectively in the system. The overall removal efficiencies for TN and ammonium nitrogen were found to be 98.1 and 98.5%, respectively. The overall removal efficiency for total phosphorus was also found to be 92.5%. Faecal coliform density was reduced to <$1.2{\times}10^4CFU/g$ total solids. Biogas and $CH_4$ were produced in the range of 0.39-0.85 and $0.25-0.62m^3/kg$ [VS removed], respectively. The biogas produced in the system comprised of $295{\pm}26ppm$ (v/v) [$H_2S$].

• Journal of Wetlands Research
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• v.20 no.3
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• pp.263-271
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• 2018

In this study, we analyzed the removal efficiency of ammonia nitrogen and phosphate dependant on the column depths using various absorbents such as zeolite silica sand, and activated carbon through the column test. In addition, we analyzed electrochemical adsorption behaviors of ammonia nitrogen and phosphate through the quantum mechanical calculation based on density functional theory calculation. Experimental results represent the removal efficiency of ammonia nitrogen and phosphate are zeolite > activated carbon > silica sand, and activated carbon > zeolite > silica sand, respectively. Zeolite shows high adsorption property for ammonia nitrogen over 90%, regardless of the column depth, while activated carbon exhibits high adsorption property for both ammonia nitrogen and phosphate as the column depth for filter media increases. Theoretical findings using DFT calculation for the adsorption behaviors of adsorbents (activated carbon and silica sand) and nutrients ($PO_4{^{3-}}$, $NH_4{^{+}}$) show that activated carbon represented narrower HOMO-LUMO band gap with high adsorption energy, and even more favorable environment for electron adsorption than silica sand, which leads to the effective removal of nutrients.

• Korean Journal of Soil Science and Fertilizer
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• v.39 no.2
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• pp.73-79
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• 2006

Aeration is the most important and indispensable operation unit for the treatment of swine manure using aerobic liquid-composting process. The composting of swine manure depends on biological treatment process, but the highly concentrated ammonia nitrogen is required a pretreatment to expect the appropriate efficiency of the biological treatment process. In this study, pilot experiments have been carried out to estimate of the fit condition about ammonia stripping process as a pretreatment to aerobic liquid- composting. pH adjustment with $Ca(OH)_2$ was economically superior to use of NaOH and optimum pH of ammonia stripping was 12.3, ammonia nitorgen was rapidly removed as pH were increased at $$35^{\circ}C$$. When air stripping is performed before aerobic liquid-stripping, a high initial pH is required for complete ammonia removal and is additional effects such as organic substances, phosphorus, turbidity, and color removal. Stripping process was very efficient in the pretreatment of highly concentrated ammonia nitrogen for composting of swine manure. Emission rate of gaseous ammonia was $0.5355mole\;s^{-1}$ at initial time and $0.0253mole\;s^{-1}$ at finitial time. The fit condition of ammonia stripping in this study were at the temperature of $$35^{\circ}C$$, and the pH of 12.3 during 48 hours.