• Title/Summary/Keyword: ambient $CO_2$

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Process Diagnosis of Reactive Deposition of MgO by ICP Sputtering System (유도결합 플라즈마 스퍼터링 장치에서 MgO의 반응성 증착 시 공정 진단)

  • Joo, Junghoon
    • Journal of the Korean institute of surface engineering
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    • v.45 no.5
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    • pp.206-211
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    • 2012
  • Process analysis was carried out during deposition of MgO by inductively coupled plasma assisted reactive magnetron sputtering in Ar and $O_2$ ambient. At the initiation of Mg sputtering with bipolar pulsed dc power in Ar ambient, total pressure showed sharp increase and then slow fall. To analyse partial pressure change, QMS was used in downstream region, where the total pressure was maintained as low as $10^{-5}$ Torr during plasma processing, good for ion source and quadrupole operation. At base pressure, the major impurity was $H_2O$ and the second major impurity was $CO/N_2$ about 10%. During sputtering of Mg in Ar, $H_2$ soared up to 10.7% of Ar and remained as the major impurity during all the later process time. When $O_2$ was mixed with Ar, the partial pressure of Ar decreased in proportion to $O_2$ flow rate and that of $H_2$ dropped down to 2%. It was understood as Mg target surface was oxidized to stop $H_2$ emission by Ar ion sputtering. With ICP turned on, the major impurity $H_2$ was converted into $H_2O$ consuming $O_2$ and C was also oxidized to evolve CO and $CO_2$.

A Study on the Silicidation of Thick Co/Ti Bilayer (두꺼운 이중층 Co/Ti 막의 실리사이드화에 관한 연구)

  • 이병욱;권영재;이종무;김영욱
    • Journal of the Korean Ceramic Society
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    • v.33 no.9
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    • pp.1012-1018
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    • 1996
  • To investigate the final structures and reactions of silicides a somewhat thick Ti monolayer Co monolayer and Co/Ti bilayer films were deposited on single Si(100) wafer by electron beam evaporation followed by heat treatment using RTA system in N2 ambient. TiO2 film formed between Ti and TiSi2 layers due to oxgen or moisture in the Ti monolayer sample. The final layer structure obtained after the silicidation heat-treatment of the Co/Ti bilayer sample turned out to be TiSi2/CoSi2/Ti-Co-Si alloy/CoSi2/Si sbustrate. This implies that imperfect layer inversion occurred due to the formation of Ti-Co-Si intermediate phase.

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Photosynthetic and Growth Responses of Chinese Cabbage to Rising Atmospheric CO2 (대기 중 CO2 농도의 상승에 대한 배추의 광합성과 생장 반응)

  • Oh, Soonja;Son, In-Chang;Wi, Seung Hwan;Song, Eun Young;Koh, Seok Chan
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.18 no.4
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    • pp.357-365
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    • 2016
  • The effects of elevated atmospheric $CO_2$ on photosynthesis and growth of Chinese cabbage (Brassica campestris subsp. napus var. pekinensis) were investigated to predict productivity in highland cropping in an environment where $CO_2$ levels are increasing. Vegetative growth, based on fresh weight of the aerial part, and leaf characteristics (number, area, length, and width) of Chinese cabbage grown for 5 weeks, increased significantly under elevated $CO_2$ ($800{\mu}mol{\cdot}mol^{-1}$) compared to ambient $CO_2$ ($400{\mu}mol{\cdot}mol^{-1}$). The photosynthetic rate (A), stomatal conductance ($g_s$), and water use efficiency (WUE) increased, although the transpiration rate (E) decreased, under elevated atmospheric $CO_2$. The photosynthetic light-response parameters, the maximum photosynthetic rate ($A_{max}$) and apparent quantum yield (${\varphi}$), were higher at elevated $CO_2$ than at ambient $CO_2$, while the light compensation point ($Q_{comp}$) was lower at elevated $CO_2$. In particular, the maximum photosynthetic rate ($A_{max}$) was higher at elevated $CO_2$ by 2.2-fold than at ambient $CO_2$. However, the photosynthetic $CO_2$-response parameters such as light respiration rate ($R_p$), maximum Rubisco carboxylation efficiency ($V_{cmax}$), and $CO_2$ compensation point (CCP) were less responsive to elevated $CO_2$ relative to the light-response parameters. The photochemical efficiency parameters ($F_v/F_m$, $F_v/F_o$) of PSII were not significantly affected by elevated $CO_2$, suggesting that elevated atmospheric $CO_2$ will not reduce the photosynthetic efficiency of Chinese cabbage in highland cropping. The optimal temperature for photosynthesis shifted significantly by about $2^{\circ}C$ under elevated $CO_2$. Above the optimal temperature, the photosynthetic rate (A) decreased and the dark respiration rate ($R_d$) increased as the temperature increased. These findings indicate that future increases in $CO_2$ will favor the growth of Chinese cabbage on highland cropping, and its productivity will increase due to the increase in photosynthetic affinity for light rather than $CO_2$.

EFFECTS OF WATERY VAPOR CONCENTRATION ON DROPLET EVAPORATION IN HOT ENVIRONMENT

  • Lee, M.J.;Kim, Y.W.;Ha, J.Y.;Chung, S.S.
    • International Journal of Automotive Technology
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    • v.2 no.3
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    • pp.109-115
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    • 2001
  • A study has been conducted to clarify the effect of watery vapor concentration in hot ambient on droplet evaporation. Droplets of water, ethanol, n-hexadecaneand n-heptane were used in this experimental study. Ambient conditions are fixed at 470 K in temperature, 0.1 MPa in pressure and 2 m/s in velocity of ambient air. Watery vapor concentration was changed 0%~40% by 10% by add water to air. To obtain the time histories of droplet diameter after exposed in ambient, a suspended droplet in hot and humid ambient stream was synchronized with a back flash light, and enlarged droplet images were taken by a CCD camera. The evaporation rate constant of water droplet decreases slightly with the vapor concentration because diffusion velocity reduction of droplet vapor occurs on the surface. The values of ethanol and n-heptane droplet actively increase by effect that water from condensation of vapor flows into the droplet. The evaporation rate constant of n-hexadecane which has higher boiling point than water increases within around 30% of the concentration.

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Oxidation Reaction of silicon Oxids fabricated by Rapid Thermal Process in $N_2$O ambient ($N_2$O 분위기에서 RTP로 제조한 실리콘 산화막의 산화 반응)

  • Park, Jin-Seong;Lee, U-Seong;Sim, Tae-Eon
    • Korean Journal of Materials Research
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    • v.3 no.1
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    • pp.7-11
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    • 1993
  • Abstract Oxidation kinetics of silicon oxide films formed by rapid thermal oxidizing Si substrate in $N_2$O ambient studied. The data on $N_2$0 oxidation shows that the interfacial nitrogen-rich layers results in oxide growth in the parabolic regime by impeding oxidant diffusion to the Si$O_2$-Si interface even for ultrathin oxides. The activation energy of parablic rate constant, B, is about 1.5 eV, and the energy increses with oxide thickness.

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Rotational Distribution of $CO_2$($00^00)after Collisions with Hot Atoms

  • Kim, U Hang
    • Bulletin of the Korean Chemical Society
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    • v.21 no.5
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    • pp.493-496
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    • 2000
  • By use of the rotational distribution expression previously derived based on the collisional time correlation function formalism, the rotational distributions of $CO_2$ vibrational ground state (00°0) after collisions with hot H, D, or Cl atom have been constructed. Energy and rotational quantum number parameters which can characterize the rotational distributions are also calculated and compared with those deduced from the experimental distribution. The results from this work would be very useful in predicting the rotational distributions in the lower J region for which experimental data are not available due to the interference from the ambient $CO_2$.

Effects of Elevated CO2 Concentration on Leaf Phenology of Quercus acutissima (이산화탄소 농도 증가가 상수리나무 잎의 계절현상에 미치는 영향)

  • Seo, Dong-Jin;Oh, Chang-Young;Han, Sim-Hee;Lee, Jae-Cheon
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.16 no.3
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    • pp.213-218
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    • 2014
  • Effects of elevated $CO_2$ on leaf phenology of Quercus acutissima were examined using open-top chambers, which had ambient and elevated $CO_2$ concentrations (ambient ${\times}1.4$, ambient ${\times}1.8$). To analyze the effect of chamber, non-treatment block was established near outside of the chambers. In 2013, budburst, leaf unfolding, coloring, and shedding were surveyed, and spring phenology was surveyed in 2014. Thermal sum (base temperature $+5^{\circ}C$) of each phenological event occurred was recorded. In addition, bud samples were collected and analyzed for carbohydrate contents in March 2014. Elevated $CO_2$ concentration advanced budburst and leaf unfolding, and delayed shedding in 2013. However, in 2014, the temperature of the spring season was high, and there was no significant effect of elevated $CO_2$ concentration on spring phenology. Carbohydrates content, such as starch, total non-structural carbohydrate and total soluble sugar, were significantly increased in response to elevated $CO_2$ concentration. It has been proposed that elevated $CO_2$ concentration could extend the growing season of temperate species with increased possibility of frost damage due to early bud opening and leaf unfolding. However, our analysis showed that the increased carbohydrate concentration in bud under elevated $CO_2$ would reduce the possibility of early spring frost damage by acting as cryoprotectant.

Influence of top AZO electrode deposited in hydrogen ambient on the efficiency of Si based solar cell

  • Chen, Hao;Jeong, Yun-Hwan;Chol, Dai-Seub;Park, Choon-Bae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.321-322
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    • 2009
  • Al doped ZnO films deposited on glass substrate using RF magnetron sputtering in Ar and $Ar+H_2$ gas ambient at $100^{\circ}C$. The films deposited in $Ar+H_2$ were hydrogen-annealed at the temperature of $150\sim300^{\circ}C$ for 1hr. The lowest resistivity of $4.25\times10^{-4}{\Omega}cm$ was obtained for the AZO film deposited in $Ar+H_2$ after hydrogen annealing at $300^{\circ}C$ for 1hr. The average transmittance is above 85% in the range of 400-1000 nm for all films. The absorption efficiency of solar cell was improved by using the optimized AZO films as a top electrode.

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Effect of Elevated CO2 Concentration and Temperature on the Growth and Ecophysiological Responses of Ginseng (Panax ginseng C. A. Meyer) (CO2농도와 온도증가에 따른 인삼의 생육 및 생리.생태학적 반응 연구)

  • Lee, Kyoung-Mi;Kim, Hae-Ran;Lim, Hoon;You, Young-Han
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.57 no.2
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    • pp.106-112
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    • 2012
  • In order to understand the growth and ecophy -siological response of ginseng to global warming condition, we cultivated one and two year ginseng seedlings in control (ambient $CO_2$ + ambient temperature) and global warming treatment (elevated $CO_2$ + elevated temperature) from March 2010 to July 2011. Shoot appearance and initiation of flowering were advanced by 3-4 days in global warming treatment than in control. However, timing of fruit setting and seed ripeness was similar in both control and global warming treatment. Shoot length was longer in global warming treatment than in control, and also the number of leaves was much in global warming treatment. Fresh root weight was not different between control and global warming treatment. Photosynthetic rate was higher in global warming treatment than at control. Photosynthetic rate and transpiration rate were higher in two year seedlings than in one year seedlings at control, but was not different between seedling age of ginseng in global warming treatment. Water use efficiency was higher in one year seedlings than two year seedlings at control and global warming treatment. These results demonstrated that Korean ginseng more or less positively responds to global warming situation.

Spatial, Vertical, and Temporal Variability of Ambient Environments in Strawberry and Tomato Greenhouses in Winter

  • Ryu, Myong-Jin;Ryu, Dong-Ki;Chung, Sun-Ok;Hur, Yun-Kun;Hur, Seung-Oh;Hong, Soon-Jung;Sung, Je-Hoon;Kim, Hak-Hun
    • Journal of Biosystems Engineering
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    • v.39 no.1
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    • pp.47-56
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    • 2014
  • Purpose: In protected crop production facilities such as greenhouse and plant factory, farmers should be present and/or visit frequently to the production site for maintaining optimum environmental conditions and better production, which is time and labor consuming. Monitoring of environmental condition is highly important for optimum control of the conditions, and the condition is not uniform within the facility. Objectives of the paper were to investigate spatial and vertical variability in ambient environmental variables and to provide useful information for sensing and control of the environments. Methods: Experiments were conducted in a strawberry-growing greenhouse (greenhouse 1) and a cherry tomato-growing greenhouse (greenhouse 2). Selected ambient environmental variables for experiment in greenhouse 1 were air temperature and humidity, and in greenhouse 2, they were air temperature, humidity, PPFD (Photosynthetic Photon Flux Density), and $CO_2$ concentration. Results: Considerable spatial, vertical, and temporal variability of the ambient environments were observed. In greenhouse 1, overall temperature increased from 12:00 to 14:00 and increased after that, while RH increased continuously during the experiments. Differences between the maximum and minimum temperature and RH values were greater when one of the side windows were open than those when both of the windows were closed. The location and height of the maximum and minimum measurements were also different. In greenhouse 2, differences between the maximum and minimum air temperatures at noon and sunset were greater when both windows were open. The maximum PPFD were observed at a 3-m height, close to the lighting source, and $CO_2$ concentration in the crop growing regions. Conclusions: In this study, spatial, vertical, and temporal variability of ambient crop growing conditions in greenhouses was evaluated. And also the variability was affected by operation conditions such as window opening and heating. Results of the study would provide information for optimum monitoring and control of ambient greenhouse environments.