• 대한기계학회:학술대회논문집
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• 대한기계학회 2008년도 추계학술대회A
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• pp.193-197
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• 2008

Array of micro-dimple on polyoxymethylene (POM) surface was fabricated using Q-switched Nd:YAG laser and its characteristics were studied in terms of heat affected zone (HAZ), dimple geometry, and the effect of specimen surface roughness. Process parameters such as lamp current, process time, and the stream of air in order to minimize HAZ and flow of molten polymer into cavity were extensively studied in this work. Dimple geometry was further investigated by 3-D optical microscopy to provide deep insight into morphological analysis near the dimples. This paper also presents the applicapability of micro-dimples in polymeric tribological system, such as a thrust bearing. Micro-dimples were expected to provide low coefficient of friction and enhanced lubricity at the sliding interface.

• Bulletin of the Korean Chemical Society
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• 제16권12호
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• pp.1167-1172
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• 1995

A coverage of about 1 μm-sized pores of a membrane filter by four monolayers of maleic acids copolymers and poly(allylamine) (PAA) was attained by Langmuir-Blodgett (LB) technique through a covalent cross-linking followed a polyion complexation at the air-water interface. The copolymers were prepared to have side chains of hydrocarbon tail, carboxyl, and/or oligoether in the repeat unit. The surface pressure-area isotherms showed that the monolayers on an aqueous PAA have more expanded area than on pure water. The monolayers were transferable on a calcium fluoride substrate and a fluorocarbon membrane filter as Y deposition type, and the resulting LB films were characterized by FT-IR spectroscopy and scanning electron microscopy. A polymer network produced through interchain amide formation was confirmed in as-deposited films. The films were heat-treated in order to complete the cross-linking. SEM observation of the heat-treated film on a porous membrane filter showed that the four layer film was sufficiently stable to cover the filter pore of about 1 μm. Immersion of the film in water or in chloroform did not cause any change in its appearance on SEM and in FT-IR spectra.

• 접착 및 계면
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• 제11권1호
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• pp.26-34
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• 2010

가열에 의해 해체가 가능한 열적특성을 갖는 폴리우레탄 접착제를 합성하였으며 열팽창비드를 혼합하여 해체성 접착제를 제조하였다. Dynamic mechanical thermal analyzer (DMA)를 사용하여 폴리우레탄의 열적특성을 확인하였고 접착강도와 열팽창비드의 함량, 가열 trigger의 종류와 처리조건에 따른 해체특성을 연구하였다. 열풍과 microwave 처리에 의해서 해체성 폴리우레탄 접착제의 부피팽창에 따른 접착된 시편의 해체가 가능하였으며, 열팽창비드의 함량이 증가될수록 접착된 피착재가 더 쉽게 분리되었다. 해체성 접착제에서 접착력과 해체특성 모두를 만족시킬 수 있는 가장 적합한 열팽창비드 사용량은 40%이였으며, 가열 trigger로 열풍을 사용한 경우에는 $160^{\circ}C$, 30 min의 조건에서, 가열 trigger로 microwave를 사용한 경우에는 조사시간 4 min의 조건에서 접착되어 있는 피착재가 완전히 해체되었다.

• Macromolecular Research
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• 제12권1호
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• pp.127-133
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• 2004

We have studied the surface micelle formation of polystyrene-b-poly(2-vinyl pyridine) (PS-b-P2VP) at the air-water interface. A series of four PS-b-P2VPs were synthesized by anionic polymerization, keeping the PS block length constant (28 kg/㏖) and varying the P2VP block length (1, 11, 28, or 59 kg/㏖). The surface pressure-area ($\pi$-A) isotherms were measured and the surface morphology was studied by atomic force microscopy (AFM) after Langmuir-Blodgett film deposition onto silicon wafers. At low surface pressure, the hydrophobic PS blocks aggregate to form pancake-like micelle cores and the hydrophilic P2VP block chains spread on the water surface to form a corona-like monolayer. The surface area occupied by a block copolymer is proportional to the molecular weight of the P2VP block and identical to the surface area occupied by a homo-P2VP. It indicates that the entire surface is covered by the P2VP monolayer and the PS micelle cores lie on the P2VP monolayer. As the surface pressure is increased, the $\pi$-A isotherm shows a transition region where the surface pressure does not change much with the film compression. In this transition region, which displays high compressibility, the P2VP blocks restructure from the monolayer and spread at the air-water interface. After the transition, the Langmuir film becomes much less compressible. In this high-surface-pressure regime, the PS cores cover practically the entire surface area, as observed by AFM and the limiting area of the film. All the diblock copolymers formed circular micelles, except for the block copolymer having a very short P2VP block (1 kg/㏖), which formed large, non-uniform PS aggregates. By mixing with the block copolymer having a longer P2VP block (11 kg/㏖), we observed rod-shaped micelles, which indicates that the morphology of the surfaces micelles can be controlled by adjusting the average composition of block copolymers.

• 접착 및 계면
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• 제2권3호
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• pp.25-32
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• 2001

순간접착제로 사용되고 있는 에틸 시아노아크릴레이트(ECA) 단량체는 개시제 없이 공기중의 수분에 의해서 쉽게 중합이 될 수 있어서 산업용 및 가정용 접착제로 응용되고 있다. 그러나 ECA 단량체는 그 자체가 가지는 저점도성으로 인해서 피착제 내부로 흘러들어가는 단점을 가지고 있다. 이를 보완하기 위해서 상업적으로 폴리메틸메타크릴레이트(PMMA)를 첨가하고 있지만 PMMA의 사용은 순간접착제의 유연성을 감소시키는 결과를 초래한다. 또한 순간접착제의 중합체는 취약하다는 문제점을 가지고 있다. 본 연구에서는 기존 순간접착제 단량체의 중점성과 중합체의 유연성을 동시에 부여할 수 있는 새로운 PMMA 함유 중합체의 기능성 첨가제를 제조하였다. 즉, 유리전이온도(Tg)가 낮은 비닐 아세테이트(VAc)와 에틸비닐에테르(EVE)를 MMA와 라디칼 중합을 행하여 P(MMA-VAc)와 P(MMA-VAc-EVE)의 기능성 첨가제를 얻었다. 제조된 첨가제는 ECA 단량체에 첨가시켜 기능성을 갖는 순간접착제를 제조하였다. 첨가제 및 ECA 중합체의 구조는 $^1H$ NMR 및 FTIR로 확인하였으며 각각의 물리적 및 기계적 물성을 평가하였다. 얻어진 첨가제의 Tg는 VAc나 VAc-EVE가 증가할수록 감소하여 유연성을 나타내었고 첨가제가 함유된 기능성 순간접착제는 기존 PMMA만이 함유된 순간접착제에 비해 더 높은 접착강도를 보였다.

• 폴리머
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• 제37권4호
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• pp.547-552
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• 2013

폴리이미드에 폴리실록산 블록을 포함시키는 형태의 공중합체를 통해 내열 점착특성을 갖는 박막층을 형성하였다. 카르복시기를 포함하는 폴리이미드를 중합하여 디아미노실록산과 반응하면서 필름을 형성하는 제조방법에서 그래프트화 및 가교결합을 형성하였다. 투과전자현미경과 energy dispersive X-ray spectroscopy(EDX)를 통한 모폴로지 조사에서 폴리이미드와 폴리실록산 부분은 각각 100 nm 크기의 구형 도메인과 연속상을 갖는 마이크로 상분리 구조를 갖는 것을 확인하였다. 또한 X-ray photoelectron spectroscopy(XPS) 분석에서는 공기-필름 계면에 폴리실록산 성분이 주로 노출되고 있음이 나타났다. $400^{\circ}C$까지 내열성을 갖는 폴리(이미드실록산) 박막층은 상온에서 $300^{\circ}C$까지 그 점착 특성이 유지됨을 확인하였다. 폴리이미드의 카르복시기와 아미노실록산의 그래프트화가 마이크로도메인 형성과 점착특성을 나타내는데 중요하게 작용함을 비교실험을 통해 확인하였다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1999년도 추계학술대회 논문집
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• pp.111-114
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• 1999

Electroluminescence(EL) devices based on organic thin films have been attracted lots of interests in large-area light-emitting display. In this stuffy, an emissive layer was fabricated using Langmuir-Blodgett(LB) technique in organic light-emitting (OLEDs). This emissive organic material was synthesized and named PECCP[poly(3.6-N-2-ethylhexyl carbazolyl cyanoterephthalidene)] which has a strong electron donor group and an electron acceptor group in main chain repeated unit. This material has good solubility in common organic solvents such as chloroform. THF, etc, and has a good stability in air. The Langmuir-Blodgett(LB) technique has the advantage of precise control of the thickness down to the molecular scale, In particular, by varying the film thickness it is possible to investigate the metal/polymer interface. Optimum conditions for the LB film deposition are usually determined by investigating a relationship between a surface pressure $\pi$ and an effective are A occupied by one molecule on the subphase. The LB films were deposited on an indium-tin-oxide(ITO) glass at a surface pressure of 10 mN/m and dipping speed of 12 mm/min after spreading PECCP solution on distilled water surphase at room temperature, Cell structure was ITO/PECCP LB film/Alq$_3$/Al. We considered PECCP as a hole -transport layer inserted between the emissive layer and ITO. We also used Alq$_3$ as an emissive layer and an electron transport layer. We measured current-voltage(I-V) characteristics, UV/visible absorption, PL spectrum and EL spectrum of the OLEDs.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1995년도 춘계학술대회 논문집
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• pp.220-223
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• 1995

Stable polyion-complexed polymeric monolayrers were prepared by spreading perfluoroalkyl monomaleatd copolymers. C$_2$F$\_$8/MA-VE$_2$ and C$_2$F$\_$8/Mv-VE$_3$ on aqueous poly(allylamine) subphase. The monolayer properties have been studied by the surface pressure-area($\pi$-A) isotherms. The C$_2$F$\_$8/MA-VE$_3$containing longer oligoethyleneglycol pendant showed more expaned monolayer phase than the C$_2$F$\_$8/MA-VE$_2$ The polyion-complexed monolayers were transferable on various substrates, and the resulting Langmuir-Blodgett(LB) films were characterized b ET-IR spectroscopy and scanning electron microscopy(SEM) Two-dimensional crosslinking to from a polymer network was achieved by amide formation through heat treatment under vacuum with concurrent removel of perfluoroalkyl tails. SEM observation of this film ona porous membrane filter showed that the four layer film was sufficiently stable to cover the filter pore size of 0.1$\mu\textrm{m}$. The C$_2$F$\_$8/MA-VE$_3$revealed better covering capability than the C$_2$F$\_$8/MA-VE$_2$Immersion of this film in water or in benzend did not cause any change in its appearance and in FT-IR spectra.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2011년도 춘계학술발표대회
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• pp.10.2-10.2
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• 2011

The design and synthesis of protein-like polymers is a fundamental challenge in materials science. A biomimetic approach is to explore the impact of monomer sequence on non-natural polymer structure and function. We present the aqueous self-assembly of two peptoid polymers into extremely thin two-dimensional (2D) crystalline sheets directed by periodic amphiphilicity, electrostatic recognition and aromatic interactions. Peptoids are sequence-specific, oligo-N-substituted glycine polymers designed to mimic the structure and functionality of proteins. Mixing a 1:1 ratio of two oppositely charged peptoid 36 mers of a specific sequence in aqueous solution results in the formation of giant, free-floating sheets with only 2.7 nm thickness. Direct visualization of aligned individual peptoid chains in the sheet structure was achieved using aberration-corrected transmission electron microscopy. Specific binding of a protein to ligand-functionalized sheets was also demonstrated. The synthetic flexibility and biocompatibility of peptoids provide a flexible and robust platform for integrating functionality into defined 2D nanostructures. In the later part of my talk, we describe the use of metal ions to construct two-dimensional hybrid films that have the ability to self-heal. Incubation of biomimetic peptoid polymers with specific divalent metal ions results in the spontaneous formation of uniform multilayers at the air-water interface. We anticipate that ease of synthesis and transfer of these two-dimensional materials may have many potential applications in catalysis, gas storage and sensing, optics, nanomaterial synthesis, and environmentally responsive scaffolds.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1999년도 춘계학술대회 논문집
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• pp.345-348
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• 1999

The monolayer behaviors at the air-water interface and the dielectric properties of MI-0 LB films for complex concentration were investigated by the surface pressure-area ($\pi$-A) isotherms and dielectric constant. The molecular area was expanded with increase of metal ions concentration. It is considered that the expansion of molecular area is due to electrostatic repulsion between the polymer chains andhydrophobic increase of ionic strength. In the frequency-dependent complex dielectric constant at room temperature, the real part of dielectric constant($\varepsilon'$) is about 6.0~10.0 in the low-frequency range and is decreasing slowly upto $1O^4$Hz. It decreased abruptly near $1O^5Hz$. It seems to be dielectric dispersion in this frequency range. Also, the imaginary part of dielectric constant ($\varepsilon"$) shows a peak in $1O^5$~$1O^6Hz$. It seems to be dielectric absorption in this frequency range.ange.