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http://dx.doi.org/10.7317/pk.2013.37.4.547

Preparation of Aminosiloxane-grafted Poly(imidesiloxane) Copolymer and its Morphology and Adhesive Properties in Film  

Lee, Ji Mok (Department of Applied Chemistry, Kumoh National Institute of Technology)
Kwon, Eunjin (Department of Applied Chemistry, Kumoh National Institute of Technology)
Lee, Sunyoung (Department of Applied Chemistry, Kumoh National Institute of Technology)
Jung, Hyun Min (Department of Applied Chemistry, Kumoh National Institute of Technology)
Publication Information
Polymer(Korea) / v.37, no.4, 2013 , pp. 547-552 More about this Journal
Abstract
Polyimide (PI) containing carboxyl functional group was prepared and reacted with diaminosiloxane during high temperature film casting. The morphology of resulting film was observed by using transmission electron microscopy (TEM) and energy dispersive X-ray spectroscopy (EDX), which revealed that globular 100 nm-sized PI domains and continuous polysiloxane phase were formed. X-ray photoelectron spectroscopy (XPS) study indicated that air-film interface mainly consisted of polysiloxane blocks. Poly(imidesiloxane) thin layer was thermostable until $400^{\circ}C$ and its pressure- sensitive adhesive property was retained up to $300^{\circ}C$. The comparative experiments revealed that grafting between carboxyl groups of polyimide and aminosiloxane was crucial for formation of microdomain structure and pressure-sensitive adhesive property.
Keywords
polyimide; poly(imidesiloxane); pressure-sensitive adhesion; thermostable; grafting copolymer;
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