• Title/Summary/Keyword: aerogel

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Ambient Pressure Dried Silica Aerogel Thin Film from Water Glass

  • Cha, Young-Chul;Yoon, Jong-Seol;Lee, Jun;Hwang, Hae-Jin;Moon, Ji-Woong
    • Journal of the Korean Ceramic Society
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    • v.45 no.2
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    • pp.87-89
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    • 2008
  • A nano structured silica aerogel thin film was manufactured from inexpensive sodium silicate (water glass) using an ambient pressure drying method. High purity silicic sol was prepared by passing a water glass solution through an ion exchange resin, and the gel films were prepared on a modified glass substrate via dip coating. The dip coating conditions, such as coating time and solvent, were optimized. The optical and physical properties of the obtained silica aerogel thin film were characterized using a UV-visable spectrometer and a scanning electron microscope.

The Fire Resistant Performance of the High-Strength Concrete Column Covered with Aerogel Compound Inorganic Blanket and Gypsum board (에어로젤 복합 무기질 블랭킷 및 석고보드 피복 고강도콘크리트 기둥의 내화성능)

  • Yeo, In-Hwan;An, Jae-Hong
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.11a
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    • pp.201-203
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    • 2011
  • The purpose of this study was to develop and evaluate of fire resistive cladding systems for HSC(high-strength concrete) column, which was mainly constructed with aerogel blanket insulation material. The aerogel blanket-fire protective gypsum board cladding system showed that it clearly secure the fire resistance performance of HSC column when the reinforcing measures had achieved for four cross-sectional edge sides of structure and the system is well continued during the test period with no significant deformation or separation etc. It was checked out the 20mm thickness cladding system consist with AG(5mm)+FGB(15mm) can secure 3hour-fire resistance performance adequately.

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A Study on Properties of Thermal Insulation Board Prepared by Porous Silica Aerogel (다공성 실리카 에어로겔을 이용한 복합단열재의 특성에 관한 연구)

  • Yoon, Jong-Kuk;Koo, Kyung-Wan
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.61 no.9
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    • pp.1362-1367
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    • 2012
  • High porous silica aerogel/polyurethane polymer composite was manufactured by cross-linking polymerization of polyurethane foaming process. The properties of microstructure, mechanical strength, and thermal properties were investigated for its various applications. The superhydrophobic silica aerogel powders were used for highly thermal insulation filler materials. The thermal conductivities can be resulted 0.07 W/mK to 0.13 W/mK, by decreasing the contents of silica aerogels in composite materials. It is found that the polymerization formulation by organic binders can be applied to heavy industires, building materials, and various industries.

Preparation and Thermal Insulation Property of UV Curable Hybrid Coating Materials Based on Silica Aerogel (실리카 에어로겔을 이용한 자외선 경화형 복합 코팅 물질의 제조 및 단열 특성)

  • Kim, Nam-Yi;Kim, Seong-Woo
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.1
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    • pp.141-148
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    • 2012
  • In this study, the composite coating materials with improved thermal insulation property were prepared by incorporating the hydrophobic silica aerogel. The surface modification of silica aerogel was performed to obtain UV curable urethane acrylate hybrid coating sols with good compatibility by using surfactant(Brij 56). The polycarbonate substrates were coated by the prepared composites and cured under UV radiation. The incorporation of aerogel with only 10 vol% of content resulted in remarkable improvement by about 28% in the thermal insulation property of the coated film, as compared with substrate. In addition, increasing aerogel content was found to give minor effect on the variation of optical transparency, adhesion, and surface hardness of the coated film.

Introduction to Thermal Insulating Materials and Silica Aerogels (열 차단 소재와 실리카 에어로젤 개요)

  • Hong, Jin-Ho;Kim, Il;Yun, Ju-Ho;Shim, Sang-Eun
    • Elastomers and Composites
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    • v.46 no.1
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    • pp.29-36
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    • 2011
  • The term 'thermal insulating materials' describes a class of materials which can improve the thermal efficiency by reducing the thermal conduction, convention and radiation between the inside and outside of the system. As a thermal insulating material, numerous industrial applications are possible including the automobile, aerospace, aviation, and petrochemical. Especially, the silica aerogel, with their superior thermal insulating behavior, has been widely used as thermal insulating materials. Because the mechanical properties of the silica aerogel cannot meet the industrial demand, use of the silica aerogel is limited. This article aims to review the thermal insulating materials and silica aerogel, and to introduce the silica aerogel/polymer composites.

Effect of Graphene Oxide Addition to Tin Oxide Aerogel for Photocatalytic Rhodamine B Degradation (주석산화물 에어로겔의 Graphene Oxide 첨가에 따른 광촉매적 Rhodamine B 분해)

  • Kim, Taehee;Choi, Haryeong;Kim, Younghun;Lee, Jihun;Park, Hyung-Ho
    • Journal of the Microelectronics and Packaging Society
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    • v.28 no.1
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    • pp.61-66
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    • 2021
  • SnO2 has the wide bandgap which allows it to be used as the photocatalyst. There are many studies to enhance the photocatalytic properties of SnO2. In this study, 3-dimensional SnO2 aerogel was synthesized using epoxide-initiated sol-gel method for the optimal specific surface area. Also, graphene oxide (GO) was added before the gelation process of the aerogel to maximize the specific surface area. Addition of 0.5 wt% of GO would possibly enhance the specific surface area by 1.7 times compared with the bare tin oxide aerogel. Furthermore, enhanced specific surface area could degrade 67.3% of initial Rhodamine B in 120 minutes. To compare with the bare SnO2 aerogel, 0.5 wt% GO addition to SnO2 could double the reaction rate of the photocatalytic degradation.

Characteristics of Cellulose Aerogel Prepared by Using Aqueous Sodium Hydroxide-urea (Sodium Hydroxide-urea 수용액을 이용하여 제조한 셀룰로오스계 에어로겔의 특성)

  • Kim, Eun-Ji;Kwon, Gu-Joong;Kim, Dae-Young
    • Journal of the Korean Wood Science and Technology
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    • v.41 no.4
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    • pp.302-309
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    • 2013
  • The highly porous cellulosic aerogels were prepared by freeze-drying method using sodium hydroxide-urea aqueous solution in the process of dissolution, gelation, regeneration and organic solvent substitution. The structural characteristics of porous aerogel were analyzed using scanning electron microscopy and nitrogen adsorption apparatus. As a result, the dissolving pulp was completely dissolved, but filter papers and holocellulose were divided into two layers (dissolved and undissolved parts) in the process of centrifugation. The structure of aerogel from dissolved pulp showed porous pores in the surface and net-shaped network in the inner part. Aerogels from filter paper and holocellulose had the condensed porous network surface and the open-pore nano-fibril network inner structure. Undissolved form of fibers was observed in the aqueous solution of aerogel from holocellulose. The BET value ($S_{BET}$) of aerogel from dissolved pulp was ranged in 260~326 $m^2/g$, and it was decreased with the increase of concentration. Whereas, the $S_{BET}$ value of aerogel from filter paper (198~418 $m^2/g$) was increased with the increase of concentration. The $S_{BET}$ value of aerogel from holocellulose were 137 $m^2/g$ at 2% (w/w) of cellulose, and it was increased to maximum 401 $m^2/g$ at 4% (w/w) of cellulose. Then, it was decreased at 5% (w/w) of cellulose.

Synthesis of Polyimide Crosslinked Silica-based Aerogel with Enhanced Mechanical Properties and Its Physico-chemical Properties (폴리이미드 가교로 기계적 강도가 향상된 실리카 기반 에어로겔의 합성 및 물리화학적 특성 분석)

  • Kim, Jiseung;Choi, Haryeong;Kim, Taehee;Lee, Wonjun;Lee, Hong-Sub
    • Journal of the Microelectronics and Packaging Society
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    • v.29 no.4
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    • pp.9-14
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    • 2022
  • Silica aerogel is a porous material with a very low density and high specific surface area. Still, its application is limited due to its weak mechanical properties due to structural features. To solve this problem, a method of complexing it with various polymers has been proposed. We synthesized polyimide cross-linked silica aerogel by the sol-gel process to obtain high mechanical properties. Tetraethyl orthosilicate (TEOS) was used as a precursor to make silica aerogel, and 3- aminopropyltriethoxysilane (APTES) was used as a coupling agent for cross-linking polyimide. Polyimide was synthesized using pyromellitic dianhydride and 3,5-diaminobenzoic acid, and mechanical properties were improved by crosslinking polyimide with 10 repeating units in the polyimide chain using the reaction formula ${\frac{n_1}{n_2}}={\frac{n}{n+1}}$ To realize silica aerogel, polyimide having various weight ratios was added before gelation, resulting in a 19-fold or greater increase in maximum compressive strength compared to pure silica aerogel. From this study, an enhancement of silica aerogel could be enhanced through polymer cross-linking bonds.