• Bulletin of the Korean Chemical Society
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• 제34권6호
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• pp.1625-1631
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• 2013

We report a facile synthetic approach of high-quality chromium(III) terephthalate [MIL-101(Cr)] by acetate-assisted method in the absence of toxic HF. Results indicate that the morphology and surface area of the MIL-101(Cr) can be tuned by modifying the molar ratio of acetate/$Cr(NO_3)_3$. The Brunauer-Emmett-Teller (BET) surface area of MIL-101(Cr) synthesized at the optimized condition can exceed 3300 $m^2/g$. It is confirmed that acetate could promote the dissolution of di-carboxylic linker and accelerate the nucleation ratio. So the pure and small size of MIL-101(Cr) with clean pores can be obtained. $CO_2$, $CH_4$ and $N_2$ adsorption isotherms of the samples are studied at 298 K and 313 K. Compared with the traditional method, MIL-101(Cr) synthesized by acetate-assisted method possess enhanced $CO_2$ selective adsorption capacity. At 1.0 bar 298 K, it exhibits 47% enhanced $CO_2$ adsorption capacity. This may be attributed to the high surface area together with clean pores of MIL-101(Cr).

• 산업기술연구
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• 제21권B호
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• pp.133-139
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• 2001

Generally $PbTiO_3$ is manufactured in a form of thin films which is useful for the application of infrared sensors and non-volatile memory devices. Moreover $PbTiO_3$ has a characteristic of adsorption for organic acid as well as electronic property. Organic acid adsorption properties of $PbTiO_3$ powder prepared by sol-gel method was compared with the powder purchased from Aldrich Co. Crystallization and particle size of $PbTiO_3$ are influenced by process variables, such as dilution of sol solution, catalysis, calcination temperature, calcination time, etc. As the size of $PbTiO_3$ power decreased until several nanometers, adsorption of acetic acid and formic acid was increased 1.5-fold and 1.2-fold respectively.

• Membrane and Water Treatment
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• 제9권5호
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• pp.363-371
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• 2018

In this work, it was investigated the usability of artificial bee colony (ABC) and genetic algorithm (GA) in modeling adsorption of Co(II) onto drinking water treatment sludge (DWTS). DWTS, obtained as inevitable byproduct at the end of drinking water treatment stages, was used as an adsorbent without any physical or chemical pre-treatment in the adsorption experiments. Firstly, DWTS was characterized employing various analytical procedures such as elemental, FT-IR, SEM-EDS, XRD, XRF and TGA/DTA analysis. Then, adsorption experiments were carried out in a batch system and DWTS's Co(II) removal potential was modelled via ABC and GA methods considering the effects of certain experimental parameters (initial pH, contact time, initial Co(II) concentration, DWTS dosage) called as the input parameters. The accuracy of ABC and GA method was determined and these methods were applied to four different functions: quadratic, exponential, linear and power. Some statistical indices (sum square error, root mean square error, mean absolute error, average relative error, and determination coefficient) were used to evaluate the performance of these models. The ABC and GA method with quadratic forms obtained better prediction. As a result, it was shown ABC and GA can be used optimization of the regression function coefficients in modeling adsorption experiments.

• Journal of the Korean Wood Science and Technology
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• 제26권3호
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• pp.16-25
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• 1998

This study was carried out to compare vibrational properties and adsorption among shellac, cashew finished plate and untreated plate of Sitka spruce(Picea sitchensis Carr). By the method of statistical regression modeling, the fundamental resonance frequency of finished plate was higher than that of untreated plate. The fundamental resonance frequency of cashew finished plate was higher than that of shellac finished plate. By the method of modal analysis, mode frequency ratio of cashew finished plate was higher than that of shellac finished plate. Amounts of adsorption of finished plate was lower than that of untreated plate, and amount of adsorption of cashew finished plate was lower than that of shellac finished plate. It was clarified that the vibrational properties and adsorption of finished plate were superior to those of untreated plate. The vibrational properties and adsorption of cashew finished plate was superior to those of shellac finished plate.

• 펄프종이기술
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• 제35권2호
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• pp.46-51
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• 2003

The charcoal is known to have gas adsorption capability and is used frequently to mitigate the unpleasant smells from food and clothing. It is also used to treat water to remove dissolved organic and inorganic substances. In this paper, we applied the several different kinds of charcoals to the papers in three different ways to investigate if charcoal application method affects its gas adsorption capability. Wet end addition, making multiply, and coating method were tested. Specific ethylene gas adsorption capabilities were measured. Experimental results shows that manufacturing conditions of the charcoal itself changed its gas adsorption properties. The boxes used for agricultural produces, and the packaging paper for flowers are to be well fitted application for the charcoal added paper. Mulch paper, which needs opacity and air permeability with proper strength properties, is another candidate for the application of charcoal added paper.

• 한국염색가공학회지
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• 제11권5호
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• pp.38-43
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• 1999

A calculation method of optimum parameters on dual adsorption isotherm system was examined. The optimum parameters were obtained by non-linear regression analysis based upon a limited solute concentration of dual adsorption isotherm. The results were analyzed with adducing experimental data of formerly reported treaties. The percentage mean deviation of dual adsorption equation calculated with optimum parameters was less than about 5% of experimental data, which was far less than results obtained with parameters of the adduced treatises.

• 한국식품과학회지
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• 제40권1호
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• pp.111-114
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• 2008

데옥시리보뉴클레오사이드(deoxyribonucleosides)의 혼합물을 크로마토그래피 공정을 사용하여 분리함에 있어 최적의 조건을 구하기 위하여 dUrd과 dCyd의 흡착 평형식을 구하여 서로 비교하여 보았다. 이동상과 고정상의 농도를 가장 적합한 흡착 평형식으로 표시하기 위하여 네 가지 모델의 평형식을 선정하고 회귀분석에 의해 각각의 매개변수 값과 실험치와의 표준편차를 구하였다. dUrd의 경우 Radke-Prausnitz 식을 적용하였을 때 표준편차가 가장 작았으며, dCyd의 경우에는 Sips식을 적용하였을 때 계산값과 실험값이 가장 잘 일치하였다.

• 대한화학회지
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• 제61권3호
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• pp.89-96
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• 2017

This study proposed adsorption of Pb(II) ions from aqueous solution using activated carbon prepared from areca catechu shell (ACS AC) using Timphan Method. The effects of independent variables on adsorption kinetic and isotherm have been investigated by conducting experiments in batch mode at neutral pH. The structural characterization of adsorbent was done by FT-IR and SEM analysis. The Pb(II) adsorption was correlated very well with the pseudo second-order kinetic (PSOKM) and Langmuir isotherm models (LIM). Increasing NaOH mass for activation and adsorption temperature increased weakly all the parameters of adsorption kinetic and isotherm. The Pb(II) ions adsorption capacity of the ACS AC at 27 and $45^{\circ}C$ was 50.51 and 55.25 mg/g, respectively. Thermodynamic parameters were determined, and the results confirmed the Pb(II) ions adsorption should be endothermic and spontaneous process, and both physical and chemical adsorption should be taken place.

• 펄프종이기술
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• 제29권4호
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• pp.45-52
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• 1997

This study was carried out to investigate the adsorption characteristics of cationic starches onto BKP, BCTMP and talc. Concentration of the unadsorbed cationic starch contained in the supernatant of the pulp or talc slurries was determined using a spectoscopy method and the adsorption isotherm of cationc starch was constructed. When the equilibrium concentration of the cationic starch was low, almost complete adsorption of the starch onto BKP and BCTMP was observed. This indicates that electrostatic attraction is the main driving force for the adsorption of cationc starches onto pulps. BCTMP adsorbed greater amount of cationic starches than BKP since it contained more anionc functional groups on its surface. The adsorption amount of the cationic starch increased as the cationicity of the starches decreased. Surface charge density of the pulp and starch adsorption increased as the pH of the pulp slurry increased. Adsorption amount of the cationic starch onto talc was lower than that onto the pulp due to its low charge density and hydrophobic surface property.

• 한국환경과학회지
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• 제30권9호
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• pp.719-726
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• 2021

In this study, zeolitic materials were synthesized from Jeju Volcanic Rocks (JVR) using a fusion/hydrothermal method at NaOH/JVR ratios of 0.6 and 1.2. The crystallinities of the zeolitic materials at NaOH/JVR ratios of 0.6 and 1.2 were 25.5% and 59.0%, respectively. It was confirmed through the SEM image that the zeolitic materials covered the zeolite particle with a cube-shaped crystals. The Co ions adsorption by the zeolitic materials were to reach the adsorption equilibrium at 120 min. It could be better simulated in the pseudo-second order adsorption kinetic equation than in the pseudo-first order adsorption kinetic equation. The adsorption capacities (q_m) of Co ions could be to estimate Langmuir isotherm better than Freundlich isotherm. The maximum adsorption capacities (q_m) at NaOH/JVR ratios of 0.6 and 1.2 were 55.3 mg/g and 68.7 mg/g, respectively. It was found that there was a high correlation between the crystallinity of zeolitic materials and the adsorption capacity of Co ions adsorption.