Browse > Article
http://dx.doi.org/10.5012/bkcs.2013.34.6.1625

Acetate-assisted Synthesis of Chromium(III) Terephthalate and Its Gas Adsorption Properties  

Zhou, Jing-Jing (School of Chemistry and Chemical Engineering, Central South University)
Liu, Kai-Yu (School of Chemistry and Chemical Engineering, Central South University)
Kong, Chun-Long (Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences)
Chen, Liang (Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences)
Publication Information
Bulletin of the Korean Chemical Society / v.34, no.6, 2013 , pp. 1625-1631 More about this Journal
Abstract
We report a facile synthetic approach of high-quality chromium(III) terephthalate [MIL-101(Cr)] by acetate-assisted method in the absence of toxic HF. Results indicate that the morphology and surface area of the MIL-101(Cr) can be tuned by modifying the molar ratio of acetate/$Cr(NO_3)_3$. The Brunauer-Emmett-Teller (BET) surface area of MIL-101(Cr) synthesized at the optimized condition can exceed 3300 $m^2/g$. It is confirmed that acetate could promote the dissolution of di-carboxylic linker and accelerate the nucleation ratio. So the pure and small size of MIL-101(Cr) with clean pores can be obtained. $CO_2$, $CH_4$ and $N_2$ adsorption isotherms of the samples are studied at 298 K and 313 K. Compared with the traditional method, MIL-101(Cr) synthesized by acetate-assisted method possess enhanced $CO_2$ selective adsorption capacity. At 1.0 bar 298 K, it exhibits 47% enhanced $CO_2$ adsorption capacity. This may be attributed to the high surface area together with clean pores of MIL-101(Cr).
Keywords
MIL-101(Cr); Acetate-assisted synthesis; Gas adsorption; $CO_2$;
Citations & Related Records
연도 인용수 순위
  • Reference
1 Ma, S. Q.; Sun, D. F.; Wang, X. S.; Zhou, H. C. Angew. Chem. Int. Ed. 2007, 46, 2458.   DOI   ScienceOn
2 Lebedev, O. I.; Millange, F.; Serre, C.; Van Tendeloo, G.; Ferey, G. Chem. Mater. 2005, 17, 6525.   DOI   ScienceOn
3 Li, Y. W.; Yang, R. T. AIChE J. 2008, 54, 269.   DOI   ScienceOn
4 Jiang, D.; Burrows, A. D.; Edler, K. J. CrystEngComm 2011, 13, 6916.   DOI   ScienceOn
5 Liu, Y. Y.; Ju-Lan, Z.; Jian, Z.; Xu, F.; Sun, L. X. Int. J. Hydrogen Energy 2007, 32, 4005.   DOI   ScienceOn
6 Llewellyn, P. L.; Bourrelly, S.; Serre, C.; Vimont, A.; Daturi, M.; Hamon, L.; De Weireld, G.; Chang, J. S.; Hong, D. Y.; Hwang, Y. K.; Jhung, S. H.; Ferey, G. Langmuir 2008, 24, 7245.   DOI   ScienceOn
7 Senkovska, I.; Kaskel, S. Micropor. Mesopor. Mater. 2008, 112, 108.   DOI   ScienceOn
8 Chowdhury, P.; Bikkina, C.; Gumma, S. J. Phys. Chem. C 2009, 113, 6616.   DOI   ScienceOn
9 Khan, N. A.; Jun, J. W.; Jhung, S. H. Eur. J. Inorg. Chem. 2010, 2010, 1043.   DOI   ScienceOn
10 Yang, J.; Zhao, Q.; Li, J.; Dong, J. Micropor. Mesopor. Mater. 2010, 130, 174.   DOI   ScienceOn
11 Sumida, K.; Rogow, D. L.; Mason, J. A.; McDonald, T. M.; Bloch, E. D.; Herm, Z. R.; Bae, T. H.; Long, J. R. Chem. Rev. 2012, 112, 724.   DOI   ScienceOn
12 Zhang, Z.; Huang, S.; Xian, S.; Xi, H.; Li, Z. Energy Fuels 2011,25, 835.   DOI   ScienceOn
13 Maksimchuk, N. V.; Timofeeva, M. N.; Melgunov, M. S.; Shmakov, A. N.; Chesalov, Y. A.; Dybtsev, D. N.; Fedin, V. P.; Kholdeeva, O. A. J. Catal. 2008, 257, 315.   DOI   ScienceOn
14 Chen, Y. F.; Babarao, R.; Sandler, S. I.; Jiang, J. W. Langmuir 2010, 26, 8743.   DOI   ScienceOn
15 Serre, C.; Millange, F.; Surble, S.; Férey, G. Angew. Chem. Int. Ed.2004, 43, 6285.   DOI   ScienceOn
16 Saha, D.; Bao, Z. B.; Jia, F.; Deng, S. G. Environ. Sci. Technol.2010, 44, 1820.   DOI   ScienceOn
17 Zheng, B.; Bai, J.; Duan, J.; Wojtas, L.; Zaworotko, M. J. J. Am. Chem. Soc. 2011, 133, 748.   DOI   ScienceOn
18 Chowdhury, P.; Mekala, S.; Dreisbach, F.; Gumma, S. Micropor. Mesopor. Mater. 2012, 152, 246.   DOI   ScienceOn
19 Rowsell, J. L. C.; Yaghi, O. M. Angew. Chem. Int. Ed. 2005, 44, 4670.   DOI   ScienceOn
20 Rowsell, J. L. C.; Spencer, E. C.; Eckert, J.; Howard, J. A. K.; Yaghi, O. M. Science 2005, 309, 1350.   DOI   ScienceOn
21 Chen, B. L.; Yang, Y.; Zapata, F.; Lin, G. N.; Qian, G. D.; Lobkovsky, E. B. Adv. Mater. 2007, 19, 1693.   DOI   ScienceOn
22 Huang, Y.; Zheng, Z.; Liu, T.; Lü, J.; Lin, Z.; Li, H.; Cao, R. Catal. Commun. 2011, 14, 27.   DOI   ScienceOn
23 Horcajada, P.; Surble, S.; Serre, C.; Hong, D. Y.; Seo, Y. K.; Chang, J. S.; Greneche, J. M.; Margiolaki, I.; Ferey, G. Chem. Commun. 2007, 27, 2820.
24 Bromberg, L.; Diao, Y.; Wu, H.; Speakman, S. A.; Hatton, T. A. Chem. Mater. 2012, 24, 1664.   DOI   ScienceOn
25 Luo, J. H.; Xu, H. W.; Liu, Y.; Zhao, Y. S.; Daemen, L. L.; Brown, C.; Timofeeva, T.V.; Ma, S. Q.; Zhou, H. C. J. Am. Chem. Soc. 2008, 130, 9626.   DOI   ScienceOn
26 Stock, N.; Biswas, S. Chem. Rev. 2012, 112, 933.   DOI   ScienceOn
27 Friscic, T.; Reid, D. G.; Halasz, I.; Stein, R. S.; Dinnebier, R. E.; Duer, M. J. Angew. Chem. Int. Ed. 2010, 49, 712.   DOI   ScienceOn
28 Jhung, S. H.; Lee, J. H.; Yoon, J. W.; Serre, C.; Ferey, G.; Chang, J. S. Adv. Mater. 2007, 19, 121.   DOI   ScienceOn
29 Khan, N. A.; Kang, I. J.; Seok, H. Y.; Jhung, S. H. Chem. Eng. J. 2011, 166, 1152.   DOI   ScienceOn
30 Son, W. J.; Kim, J.; Kim, J.; Ahn, W. S. Chem. Commun. 2008, 47, 6336.
31 Klimakow, M.; Klobes, P.; Thunemann, A. F.; Rademann, K.; Emmerling, F. Chem. Mater. 2010, 22, 5216.   DOI   ScienceOn
32 Hartmann, M.; Kunz, S.; Himsl, D.; Tangermann, O.; Ernst, S.; Wagener, A. Langmuir 2008, 24, 8634.   DOI   ScienceOn
33 Ahmed, I.; Jeon, J.; Khan, N. A.; Jhung, S. H. Cryst. Growth Des. 2012, 12, 5878.   DOI   ScienceOn
34 Pham, M. H.; Vuong, G. T.; Vu, A. T.; Do, T. O. Langmuir 2011, 27, 15261.   DOI
35 Barthelet, K.; Adil, K.; Millange, F.; Serre, C.; Riou, D.; Ferey, G. J. Mater. Chem. 2003, 13, 2208.   DOI   ScienceOn
36 Ferey, G.; Mellot-Draznieks, C.; Serre, C.; Millange, F.; Dutour, J.; Surble, S.; Margiolaki, I. Science 2005, 309, 2040.   DOI   ScienceOn
37 Huang, L. M.; Wang, H. T.; Chen, J. X.; Wang, Z. B.; Sun, J. Y.; Zhao, D. Y.; Yan, Y. S. Micropor. Mesopor. Mater. 2003, 58, 105.   DOI   ScienceOn
38 Loiseau, T.; Lecroq, L.; Volkringer, C.; Marrot, J.; Ferey, G.; Haouas, M.; Taulelle, F.; Bourrelly, S.; Llewellyn, P. L.; Latroche, M. J. Am. Chem. Soc. 2006, 128, 10223.   DOI   ScienceOn
39 Liu, X.; Zhou, H.; Zhang, Y.; Liu, Y.; Yuan, A. Chin. J. Chem. 2012, 30, 2563.   DOI   ScienceOn
40 Bernt, S.; Guillerm, V.; Serre, C.; Stock, N. Chem. Commun. 2011, 47, 2838.   DOI   ScienceOn
41 Li, J. R.; Sculley, J.; Zhou, H. C. Chem. Rev. 2012, 112, 869.   DOI   ScienceOn