• Title/Summary/Keyword: adhesive performance

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Research on Flame Retardant Formaldehyde-Free Plywood Glued by Aqueous Polymer Isocyanate Adhesive

  • WEN, Ming-Yu;ZHU, Jia-Zhi;ZHU, Meng;SUN, Yao-Xing;PARK, Hee-Jun;SHI, Junyou
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.5
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    • pp.755-764
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    • 2020
  • Due to pronounced mechanical performance and being environmental friendly, aqueous polymer isocyanate adhesive (API) has been widely applied in the production of formaldehyde-free wood products. In this study, flame retardant formaldehyde-free plywood was prepared by incorporation of flame retardants into the API adhesive. Partially phosphorylated poly (vinyl alcohol) (PPVA) which was prepared by reacting poly (vinyl alcohol) with phosphoric acid was used to replace PVA in API formula. In addition, Mg-Al layered double hydroxides (LDH) was chosen as additive flame retardant, replacing traditional filler CaCO3 in API adhesive formula. And then, the flame retardant API adhesive with main agent (PPVA replacing PVA70wt.%, SBR emulsion 30wt.%), curing agent 10wt.% (accounts for of the main agent), and 20wt.% LDHs (accounts of the main agent) was used to prepare flame retardant plywood. The effect of application of PPVA and Mg-Al LDH on bonding strength of plywood was investigated. The flammability characteristics of the plywood were determined by cone calorimeter test (CCT). The results revealed that compared with the plywood prepared with API adhesive, the use of PPVA and LDH enhanced the flame retardancy of plywood without negatively affecting bonding strength. The CCT tests indicated that the heat release and smoke production flame retardant API plywood were lower than those of the ordinary API glued plywood. Promising developments for flame retardant API adhesive were expected in future applications of flame retardant formaldehyde-free plywood.

A Mechanical Experimental Study for Waterproofing Performance Evaluation of Self Adhesive Sheet Combined Polymer Resin and Poly-Iso Butylene (폴리머수지와 폴리이소부틸렌을 복합한 자착식시트의 방수성능평가를 위한 역학적 실험연구)

  • Min, Inki;Tae, Ghi-Ho
    • Journal of the Korean Society of Safety
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    • v.27 no.5
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    • pp.126-134
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    • 2012
  • The purpose of this study is to investigate waterproofing performance of self adhesive sheet combined polymer resin and poly-iso butylene. For the performance estimation of external waterproofing of concrete underground structures, there can be required various properties such as adhesion strength, hair crack resistance, repeat low and high temperature test, and so on. In this study, there engineering properties of composite system using polymer resin and poly-iso butylene were examined and could be confirmed to satisfy the guidelines of KS. Especially, it was turn out that the adhesion properties was excellent and high crack-resistance up to 1.49mm will be perform.

A Study on the Measurement of the Elastic Moduli and Characteristics for Space Adhesives (우주용 접착제의 탄성계수 측정 및 특성 규명에 관한 연구)

  • Kim, Hyun-Jung;Seo, Yu-Deok;Park, Sang-Hoon;Kim, Ji-Yeon;Uhm, Tae-Kyoung;Lee, Sang-Ryool;Lee, Seung-Hoon;Lee, Deog-Gyu;Lee, Eung-Shik;Jang, Hong-Sul;Jung, Dae-Jun;Youn, Sung-Kie
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.35 no.2
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    • pp.101-106
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    • 2007
  • The optical performance of the mirror for satellite camera is highly dependent on the adhesive properties between the mirror and its support. Therefore, in order to design a mirror with high optical performance, the mechanical properties of adhesives should be well defined. In this paper, the mechanical properties of three kinds of space adhesives are studied. Elastic moduli of the adhesives are determined by tensile tests. Stress-strain relation is obtained by using exponential curve fitting for the adhesive which shows non-linear behavior. In case of the linear behavior material, elastic modulus is calculated through linear curve fitting. For the tensile tests, several points have been selected in the operating temperature range of the adhesive. The elastic modulus of each adhesive is expressed as a function of temperature. Characteristics of the adhesives are discussed regarding their temperature sensitivity.

Tensile Adhesive Chracteristics of Waterproofing System for Concrete Bridge Decks (교량 바닥판 조건에 따른 교면방수 시스템의 인장접착 특성)

  • Lee, Byung-Duck;Shim, Jae-Won;Park, Sung-Ki;Kim, Kwang-Woo
    • International Journal of Highway Engineering
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    • v.4 no.3 s.13
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    • pp.15-23
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    • 2002
  • The waterproofing system's performance is known to show a determing by complex interaction of material factors, design details, and the quality of construction, and the waterproofing integrity of waterproofing membranes is determined by the bond to the deck and the amount of damage to the waterproofing membrane. In this research, the basic properties of waterproofing membranes on market and the tensile adhesive chracteristics of waterproofing systems of concrete bridge deck have also been investigated in the view of the damages frequently reported from job site. For the tensile adhesive strength of sheet waterproofing membranes, the results after asphalt concrete paving tends to increase more than before those. The results of the liquid waterproofing membranes are upside-down, and the more concrete has strength, the more strength of tensile adhesive increase. The ambient temperature of asphalt concrete when application of the waterproofing membrane has considerable influence on the performance of waterproofing system. As described above, waterproofing system can be influenced by several factors. If they are not considered under construction, the overlooking will cause the damages of pavement and waterproofing system after traffic opening.

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Isogeometric Analysis of Electrostatic Adhesive Forces in Two-Dimensional Curved Electrodes (2차원 곡면형 전극에서 정전기 흡착력의 아이소-지오메트릭 해석)

  • Oh, Myung-Hoon;Kim, Jae-Hyun;Kim, Hyun-Seok;Cho, Seonho
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.34 no.4
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    • pp.199-204
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    • 2021
  • In this study, an isogoemetric analysis (IGA) method that uses NURBS (Non-Uniform Rational B-Spline) basis functions in computer-aided design (CAD) systems is employed to account for the geometric exactness of curved electrodes constituting an electro-adhesive pad in electrostatic problems. The IGA is advantageous for obtaining precise normal vectors when computing the electro-adhesive forces on curved surfaces. By performing parametric studies using numerical examples, we demonstrate the superior performance of the curved electrodes, which is attributed to the increase in the normal component of the electro-adhesive forces. In addition, concave curved electrodes exhibit better performance than their convex counterparts.

Use of Polyethylene as an Additive in Plywood Adhesive (합판 접착제의 첨가제로서 폴리에틸렌의 이용)

  • Oh, Yong-Sung
    • Journal of the Korean Wood Science and Technology
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    • v.26 no.1
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    • pp.14-18
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    • 1998
  • A low density polyethylene(LDPE) was examined as an additive in phenol-formaldehyde(PF) resin adhesive for bonding radiata pine plywood. The LDPE was supplied by the commercial manufacturer. The LDPE was compared to a commercial filler commonly used in structural plywood adhesives in the United States. The adhesive mixes were made by following the recommended procedure of Georgia-Pacific Resins Inc.. using plywood-type PF resin. A total of 48 three-ply plywoods. 6.3 mm nominal thickness and 30 by 30 em in size, were made at two press times (4 and 5 min). two press temperatures (150 and $160^{\circ}C$) and 30 minute assembly times for four adhesive mixing types. Evaluations of the LDPE addition were carried out by performance tension shear tests after two cycle boil aging tests on plywood per the U.S. Product Standard PS I-83. After accelerated-aging tests. plywoods were exhibited no delamination. The test results included tension shear strength and estimated wood failure values. The plywood test results support the use of polyethylene as an additive in plywood adhesives.

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Development of Adhesive Resins Formulated with Rapeseed Flour Hydrolyzates for Laminated Veneer Lumber and Its Performance Evaluation (유채박을 이용한 단판적층재용 접착제의 개발 및 성능평가)

  • Yang, In;Han, Gyu-Seong;Choi, In-Gyu;Kim, Yong-Hyun;Ahn, Sye-Hee;Oh, Sei-Chang
    • Journal of the Korean Wood Science and Technology
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    • v.39 no.3
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    • pp.221-229
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    • 2011
  • Due to the increase of oil price and the environmental issue such as the emission of volatile organic compounds, the necessity for developing alternative resins of petroleum-based adhesive resins, which have extensively been used for the manufacture of wood-based products, has been speculation since the early 1990. In our study, rapeseed flour (RSF), which is the by-product of bio-diesel produced from rapeseed, were hydrolyzed by enzymes. As a crosslinking agents of the RSF hydrolyzates, phenol-formaldehyde prepolymers (PF) were prepared. The RSF hydrolyzates and PF were mixed to complete the formulation of RSF-based adhesive resins, and the resins were applied to make the laminated veneer lumber (LVL). The physical and mechanical properties of the LVL were measured to examine whether RSF can be used as raw materials of adhesive resins for the fabrication of LVL or not. The average moisture content and soaking delamination rate of the LVL bonded with RSF-based adhesive resins exceeded the minimum requirement of KS standard. Moreover, thermal analysis of the RSF-based resins showed similar tendencies except for the RSF-based adhesive resins formulated with pectinase-hydrolyzed RSF. The bending strengths of the LVL were higher than that of the LVL made with commercial PF resins. These results showed the potential of RSF as a raw material of alternative adhesives for the production of LVL. Further works on the optimal conditions of RSF hydrolysis and spreading characteristics for RSF-based adhesive resins is required to improve the adhesive performance of RSF-based resins.

A Study on Water Contact Angle and Peel Strength by Anti- Adhesion Coating on Die Blade Materials for Adhesive Film Cutting (점착필름 절단용 다이 칼날 소재에 적용된 점착 방지 코팅의 물 접촉각 및 박리강도에 관한 연구)

  • Yujin Ha;Min-Wook Kim;Wook-Bae Kim
    • Tribology and Lubricants
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    • v.39 no.5
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    • pp.190-196
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    • 2023
  • Anti-adhesion coatings are very important in the processing of adhesive materials such as optical clear adhesive (OCA) films. Choosing the appropriate release coating material for dies and tools can be quite challenging. Hydrophobic surface treatment is usually performed, and its performance is often estimated by the static water contact angle (CA). However, the relationship between the release performance and the CA is not well understood. In this study, the water CAs of surfaces coated with anti-adhesion materials and the peel strengths of the acrylic-based adhesive films are evaluated. STC5 and SUS304 are selected as the base materials. Base materials with different surface roughnesses are produced by hairline finishing, mirror-polishing, and end milling. Four fluoropolymer compounds, including a self-assembled monolayer, are selected to make the base surface hydrophobic. Static, advancing, and receding CAs are mostly increased due to the coating, but the CA hysteresis is found to increase or decrease depending on the coating material. The peel strengths all decreased after coating and are largely dependent on the coating material, with significantly lower values observed for fluorosilane and perfluoropolyether silane coatings. The peel strength is observed to correlate better with the static CA and advancing CA than with the receding CA or hysteresis. However, it is not possible to accurately predict the anti-adhesion performance based on water CA alone, as the peel strengths are not fully proportional to the CAs.

Comparative Analysis of Fire Resistance in Glued Laminated Timber: The Impact of Adhesives and Surface Direction (구조용 집성재의 접착제 종류 및 접착면 방향성에 따른 내화성능 비교 분석)

  • Choi, Yun-Jeong;An, Jae-Hong;Baik, Kwon-hyuk
    • Journal of the Korea Institute of Building Construction
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    • v.23 no.6
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    • pp.761-772
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    • 2023
  • The fire resistance design of timber structures involves calculating the residual section based on charring depth, which is then utilized in structural design. Charring depth is determined from fire-resistance test results in Korea, which currently do not account for the charring properties of the adhesive used in Glued Laminated Timber(GLT) production. This study fabricated GLT using various adhesives employed in domestic GLT production, comparing the charring properties by adhesive type and the fire resistance performance relative to the directionality of the laminated surface. Melamine demonstrated the most advantageous fire resistance performance, followed by resorcinol and polyurethane. Furthermore, it was established that the laminated section exhibited a higher charring rate, influenced by the adhesive, compared to the laminated surface, which significantly impacts the fire resistance performance.

Fabrication and characterization of polymer-based carbon nanomaterial composites for thermal conductive adhesive application (열전도성 점착제 응용을 위한 고분자 기반 탄소나노소재 복합체 제조 및 특성 평가)

  • Lee, Byeong-Joo;Jo, Sung-Il;Yoon, Eun-Hye;Lee, Ae-Ri;Lee, Woo-Young;Heo, Sung-Gyu;Hwang, Jae-Sung;Jeong, Goo-Hwan
    • Journal of the Korean institute of surface engineering
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    • v.53 no.4
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    • pp.160-168
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    • 2020
  • A polymer-based carbon nanomaterial composite was fabricated and characterized for the application of a thermal conductive adhesive. Low-dimensional carbon nanomaterials with excellent thermal conductivity such as carbon nanotube (CNT) and graphene were selected as a filler in the composite. Thermal, electrical and adhesive properties of the composite were investigated with respect to the morphology and content of the low-dimensional carbon nanomaterials. As a result, the composite-based adhesive fabricated by the loading of surface-treated MWCNTs of 0.4 wt% showed uniform dispersion, moderate adhesion and effective heat dissipation properties. Finally, it was confirmed through the thermal image analysis of LED module that the temperature reduction of 10℃ was achieved using the fabricated composite adhesive with MWCNT-6A. Expecially, heat dissipation performance of the optimized composite adhesive was evident at the hot spot in the module compared to other samples mixed with graphene or different MWCNT loading ratios.