• Title/Summary/Keyword: adhesive binder

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Property and Polymerization of Hi-solid PSA's using Seeded Polymerization (Seed 중합을 이용한 고고형분 수용성 점착제의 합성과 물성)

  • Jung, Young Sik;Min, Seong-Kee;Seul, Soo Duk
    • Journal of Adhesion and Interface
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    • v.10 no.4
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    • pp.174-181
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    • 2009
  • The viscosity for hi-solid pressure sensitive adhesive to improve water soluble low viscosity pressure sensitive adhesive polymerized using seeded polymerization. While seed binder polymerizing it produces an optimum polymerization condition, and acrylic acid and seed binder concentration changed were measurement of viscosity variation and adhesive power at the substrate (SUS420J) as flowing results. In adhesive polymerization, seed binder concentration 7 wt%/monomer was recovered 60% of solid content, 2,100 cps of low viscosity and clear adhesive film. When acrylic acid content was 4 wt%/monomer, it was turned excellent adhesive power and holding power.

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Compressive and Adhesive Strengths of Mortars using Re-emulsification Type Polymer and Ultra-Rapid-Hardening Cement (재유화형 분말수지와 초속경 시멘트를 혼입한 모르타르의 압축강도 및 접착강도 특성)

  • Lee, Kwang-Il;Yoon, Hyun-Sub;Yang, Keun-Hyeok
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.4
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    • pp.329-335
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    • 2018
  • The objective of this study is to develop a mortar mixture with high workability and adhesive strength for section jacketing in seismic strengthening technology of existing concrete structures. To achieve targeted requirements of the mortars (initial flow exceeding 200 mm, compressive strength of 30MPa, and adhesive strength exceeding 1MPa), step-by-step tests were conducted under the variation of the following mixture parameters: water-to-binder ratio, sand-to-binder ratio, polymer-to-binder ratio, dosage of viscosity agent, and content of ultra-rapid-hardening cement. The adhesive strength of the mortars was also estimated with respect to the various surface treatment states of existing concrete. Based on the test results, the mortar mixture with the polymer-to-binder ratio of 10% and the content of ultra-rapid-hardening cement of 5% can be recommended for the section jacketing materials. The recommended mortar mixture satisfied the targeted requirements as follows: initial flow of 220 mm, high-early strength gain, 28-day compressive strength of 35MPa, and adhesive strength exceeding 1.2MPa.

Plasma Treatment Effect of Organic/Organic Core-Shell Acrylic Adhesive Binder (II) (Organic/Organic Core-Shell 아크릴 접착바인더의 플라즈마 처리영향 (II))

  • Seul, Soo-Duk
    • Polymer(Korea)
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    • v.34 no.2
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    • pp.89-96
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    • 2010
  • Adhesive binders with core-shell structure of organic/organic pair were prepared by emulsion polymerization of acrylic monomers, such as methyl methacrylate(MMA), ethyl acrylate(EA), n-butyl acrylate(BA), and styrene(St). Ammonium persulfate (APS) was used as an water soluble initiator in the presence of an anionic surfactant, sodium dodecyl benzene sulfonate (SDBS). Non-woven fabric and leather were impregnated with the adhesive binder. The surface of the impregnated fabric and leather were treated with plasma technique and then kinetics analysis and mechanical properties were measured. The conversions of the polymerization of core-shell binder (MMA/EA, MMA/BA) were greater than 90%. When the core-shell binder was prepared at equimolar conditions, the increasing effect of the core-shell binder on the state peel strength of the impregnated and plasma-treated non-woven/non-woven fabric has the order of MMA/St, EA/BA, BA/MMA, EA/St, and EA/MMA. When the core-shell binder was prepared at non-equimolar conditions, the increasing effect of the core-shell binder on the state peel strength of the non-woven fabric/leather has the order of MMA/BA, BA/EA, MMA/EA, St/MMA, and EA/St.

Effect of Carbon Filler and Ester Type Binder on the Reactivity and Adhesive Properties with PET Film of Conductive Paste (탄소필러와 에스테르계 바인더가 전도성 페이스트의 반응성 및 PET 필름과의 접착특성에 미치는 영향)

  • Shim, Chang Up;Ku, Hyo Sun;Kim, Youn Cheol
    • Applied Chemistry for Engineering
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    • v.33 no.4
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    • pp.381-385
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    • 2022
  • It is very important to secure the adhesion durability between the base film and the conductive paste for the development of a sensor for detecting hazardous chemicals. In this study, an ester binder was used to improve the adhesive properties which can be a problem when applying the sensor to the cross cut 0B or 1B grade. This problem was found while evaluating the adhesive properties by coating the polyaniline/graphene nano plate (GNP) paste on the polyethylene terephthalate (PET) film. When 10 wt% or more of the ester-based binder was added, the cross cut grade to which the sensor can be applied was 3B or higher. It was confirmed that the excessive addition of the binder may affect the electrical properties of the conductive paste and actually decrease the reactivity to sulfuric acid. To improve the electrical property, a carbon black (CB) content was varied resulting in the optimum electrical property observed at 2 wt% of CB.

Development of Environmental Rubber Interphase Adhesive by use of Oligomer of Hydrocarbon (탄화수소계 올리고머를 이용한 환경친화적 고무계면 접착제 개발)

  • Jang, Byung-Man;Jang, Jeong-Seog;Park, Sung-Soo;Choi, Dug-Jai;Kim, Su-Kyung
    • Polymer(Korea)
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    • v.25 no.1
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    • pp.142-150
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    • 2001
  • Until now rubber industry field has used organic solvent base adhesive, there was always existed a fire risk, variety of quality and harmfulness of human body. To solve this problem we were developed a new adhesive that was maked by raw materials of hydrocarbon series which has the properties of nonvolatile and high flash point. Because of this new adhesive has the properties of nonvolatile and non-harmfulness to the human body, we expected to solve the problems of a fire hazard and the pollution of the environmental. Instead of the rubber binder that is used to a present adhesive, the new idea is adopted in a new type of adhesive. Nonvolatile solvent penetrated to the rubber surface and caused the swelling in rubber surface and as a result of this action, it has the self-adhesive power. In comparision with the present adhesive a new type of adhesive remarkably improved the maintenance time of adhesion and the durability of this adhesive showed similar aspect. Because it did not exhibit a drop of physical properties of rubber which was caused by swelling effect, we estimate that new type adhesive are very stable and not reacted to several rubber additives. While present adhesive appear the crack at cutting surface of curing rubber that caused by gas, new type adhesive not exist these crack.

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Characteristics of Hybrid Protective Materials with CNT Sheet According to Binder Type

  • Jihyun Kwon;Euisang Yoo
    • Elastomers and Composites
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    • v.57 no.4
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    • pp.197-204
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    • 2022
  • Recently, the demand has increased for protective clothing materials capable of shielding the wearer from bullets, fragment bullets, knives, and swords. It is therefore necessary to develop light and soft protective clothing materials with excellent wearability and mobility. To this end, research is being conducted on hybrid design methods for various highly functional materials, such as carbon nanotube (CNT) sheets, which are well known for their low weight and excellent strength. In this study, a hybrid protective material using CNT sheets was developed and its performance was evaluated. The material design incorporated a bonding method that used a binder for interlayer combination between the CNT sheets. Four types of binders were selected according to their characteristics and impregnated within CNT sheets, followed by further combination with aramid fabric to produce the hybrid protective material. After applying the binder, the tensile strength increased significantly, especially with the phenoxy binder, which has rigid characteristics. However, as the molecular weight of the phenoxy binder increased, the adhesive force and strength decreased. On the other hand, when a 25% lightweight-design and high-molecular-weight phenoxy binder were applied, the backface signature (BFS) decreased by 6.2 mm. When the CNT sheet was placed in the middle of the aramid fabric, the BFS was the lowest. In a stab resistance test, the penetration depth was the largest when the CNT sheet was in the middle layer. As the binder was applied, the stab resistance improvement against the P1 blade was most effective.

A Study on the Degradation of Isopropyl Alcohol with $TiO_2-Coated$ Plastic Optic Fibers (광촉매 코팅 광섬유의 IPA 분해 특성 연구)

  • Yu Dong-Sik;Joo Hyun-Ku;Ha Jin-Wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.6 no.4
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    • pp.337-341
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    • 2005
  • The degradation of IPA according to coating conditions was examined by $TiO_2/P-25-coated$ POF. In the photoactivity of $TiO_2-coated$ POF, ethanol solvent was higher activity than other solvents. Inorganic(KR-400), organic(A-9540) and inorganic$\cdot$organic hybrid(GPTMS, TMOS) resins were used as binder. Organic binder(A-9540) showed the highest activity for degradation of IPA, but organic binder was decomposed by $TiO_2$. Inorganic binder had lower binder ability than others, and lower adhesive than organic binders. In TMOS as inorganic · organic hybrid binder, activity of IPA degradation was decreased by addition of TMOS when the ratio of TMOS and P-25 was changed from 0.05 to 1.

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A Study on the Process for Improving Mechanical Property of Sand Casting by Using the Binder Jetting Method (사형 주조에서 바인더 젯 3D 프린터를 이용한 기계적 물성 향상을 위한 공정 연구)

  • Jung-Chul Hwang;Tae-Sung Kim
    • Journal of the Korea Safety Management & Science
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    • v.25 no.1
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    • pp.23-29
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    • 2023
  • Among the Additive Manufacturing (AM) technologies, the Binder-Jetting printing technology is a method of spraying an adhesive on the surface of powder and laminate layer by layer. Recently, this technique has become a major issue in the production of large casting products such as ship-building, custom vehicles and so on. In this study, we performed research to make actual mold castings and increase mechanical property by using special sand and water-based binders. For use as a mold, it has a strength of more than 3MPa and permeability. Various experiments were carried out to obtain suitable them. The major process parameters were binder jetting volume, binder types, layer thickness and heat treatment condition. As a result of this study, the binder drop quantity was measured to be about 60 pico-liter, layer thickness was 100㎛ and the heat treatment condition was measured about 1,000℃ and compressive strength were measured to be more than 5MPa. The optimum condition of this experiment was established through actual casting of aluminum. The equipment used in this study was a Freeforms T400 model (SFS Co., Ltd.), and the printing area of 420 * 300 * 250mm and resolution of 600dpi can be realized.

Activation Characteristics of Metal Hydride Chemical-Treated and Fixed in an Adhesive (화성처리 및 성형화에 따른 금속수소화물의 활성화거동)

  • Han, H.K.;Park, C.K.
    • Transactions of the Korean hydrogen and new energy society
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    • v.6 no.2
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    • pp.85-90
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    • 1995
  • Activation behavior, hydriding rate and disintegration were tested for hydrogen storage alloy particles fixed in an adhesive after treating with inorganic solution. Commertial adhesive as a binder was used. Chemical-treated particles showed the best characteristics for activation and a little effect of prevention the break down of the powders themselves after several repeated operations. Furthermore activation characteristics were found to show a similar trend to chemical-treated powders even in the fixed one with an adhesive, except for a slight decrease in reaction velocity.

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A Study on the Weathering Resistance of Fixatives Used on Conservation of Painting Layer of Korea Wooden Painting (한국 판벽화 채색층 보존처리 고착제의 내후성 연구)

  • Lee, Seul;Han, Kyeong Soon
    • Journal of Conservation Science
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    • v.34 no.5
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    • pp.397-405
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    • 2018
  • Currently, there are very few studies on Korean wall paintings. Therefore, this study discusses the current conditions of wooden paintings and the characteristics of the adhesive agent in the painting layer separation. Korean land pine was chosen as the support, while white oysters shells, orpiment, red ocher, Noerok, and azurite were used as pigments. With four adhesive agents, including animal glue, Gelidium, methyl cellulose, and PVAc (caparol binder), a comparative experiment was conducted, by dividing them into two concentrations, of 0.5% and 1.5%. The temperature, humidity, and ultraviolet rays, which are contributing environmental factors in cultural assets after fixing, were artificially investigated. After deterioration, observed color difference, fixing, and the surface. Results showed that the animal glue strongly fixing all the colored layers compared to the other adhesives; however, azurite had a partial change when used outdoors. With Gelidium, which functioned similar to animal glue, the azurite was affected by the ultraviolet rays; nevertheless, despite the variations in temperature and humidity, it had the best gripping force compared to the other adhesive agents. Methyl cellulose was glossy at a high concentration, and was relatively strong against rapid changes in temperature and humidity. PVAc significantly reduced the binding force, compared to other adhesive agents.