• 대한화학회지
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• 제31권2호
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• pp.143-152
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• 1987

불포화고리 아닌 화합물(unsaturated acyclic hyrocarbons)과 불포화고리 화합물(unsaturated acyclic hyrocarbons) 153가지에 대한 $\pi$-결합에너지를 Huckel 분자궤도 함수론적으로 계산한 $E_{\pi}$값과 Kier의 molecular connectivity index, $\chi$와 비교하여 계산한 값 사이의 관계가 대단히 잘 일치함을 알 수 있고, Molecular Connectivity Index 중 일차 valence connectivity index, $^1{\chi}^v$가 $E_{\pi}$와 좋은 상관관계가 있다.

• Kyungpook Mathematical Journal
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• 제57권2호
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• pp.211-222
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• 2017

In this paper, we consider three inverse eigenvalue problems for a special type of acyclic matrices. The acyclic matrices considered in this paper are described by a graph called a broom on n + m vertices, which is obtained by joining m pendant edges to one of the terminal vertices of a path on n vertices. The problems require the reconstruction of such a matrix from given partial eigen data. The eigen data for the first problem consists of the largest eigenvalue of each of the leading principal submatrices of the required matrix, while for the second problem it consists of an eigenvalue of each of its trailing principal submatrices. The third problem has an eigenvalue and a corresponding eigenvector of the required matrix as the eigen data. The method of solution involves the use of recurrence relations among the leading/trailing principal minors of ${\lambda}I-A$, where A is the required matrix. We derive the necessary and sufficient conditions for the solutions of these problems. The constructive nature of the proofs also provides the algorithms for computing the required entries of the matrix. We also provide some numerical examples to show the applicability of our results.

• 공업화학
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• 제25권5호
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• pp.437-446
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• 2014

비고리 알릴아민 화합물의 이중알코올화 반응은 아미노 다이올 구조를 도입할 수 있는 효율적인 합성법으로 아미노 다이올 구조를 포함하는 다양한 생리활성 천연물의 효율적인 합성에 적용될 수 있다. 본 리뷰에서는 기질 그 자체, 혹은 카이랄 리간드를 이용한 다양한 입체선택적 이중알코올화 반응들을 소개하고 이를 실제 천연물의 합성에 적용한 최근의 반응 결과들을 살펴보고자 한다.

• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 1997년도 한국자동제어학술회의논문집; 한국전력공사 서울연수원; 17-18 Oct. 1997
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• pp.680-683
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• 1997

Fieldbus system should be designed by considering the number of sensors/actors(actuators+ controllers) and their sampling times. But the number of sensors/actors and which are connected to the network bus can be varied by addition and/or fault of the field devices. That variation decreases the efficiency of system which is off-line designed optimally. This paper proposes an algorithm that ensures transmission of cyclic data even though there is the number change in the field devices. We assign the different weight values to cyclic data and acyclic data. By simulation and experiment, the cyclic and acyclic data are processed via the proposed network, and the results are compared with those of the Profibus system. It is shown that the proposed algorithm is more robust with the uncertainties of the field devices of the control system.

• Management Science and Financial Engineering
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• 제13권1호
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• pp.121-126
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• 2007

Among many graphs, directed acyclic graph(DAG) attracts many researchers due to its nice property of existence of topological sort. In some classic graph problems, it is known that, if we use the aforementioned property, then much efficient algorithms can be generated. So, in this paper, new algorithm for the all-pairs shortest path problem in a DAG is proposed. While the algorithm performing the iteration, it identifies the set of essential arcs which requires in a shortest path. So, the proposed algorithm has a running time of $O(m^*n+m)$, where m, n and $m^*$ denote the number of arcs, number of node, and the number of essential arcs in a DAG, respectively.

• 약학회지
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• 제33권6호
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• pp.361-364
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• 1989

The Synthesis of acyclic derivatives of ribavirin (2'-azido and halo seco derivatives) for the development of new antiviral agents is described. These acyclic nucleosides are synthesized from ribavirin by the method of ring opening reaction of sugar moietry.

• Journal of Electrochemical Science and Technology
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• 제8권1호
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• pp.1-6
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• 2017

The conductivity of the electrolyte used plays a critical role in the optimization of the performance of electrochemical double layer capacitors. However, when the difference in the conductivities of different electrolytes is not significant (only 10-20%), the conductivity has little effect on the capacitance. On the other, unlike the conductivity and viscosity of the electrolyte, the cation size directly influences the capacitance. Cyclic ions have a smaller effective radius than that of the corresponding acyclic ions because the acyclic alkyl groups have a greater number of conformational degrees of freedom, such as the rotational, bending, and stretching modes. Consequently, because of the smaller effective size of the cyclic ions, cells containing electrolytes with such ions exhibit higher capacitances than do those with their acyclic counterparts.

• Archives of Pharmacal Research
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• 제22권2호
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• pp.225-227
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• 1999

A new acylcic deterpene (1) and a known acyclic diterpene 12(S)-hydroxygeranyleraniol (2) were isolated form the aerial parts of Carpesium divaricatum. The structure of 1 was determined to be (2E, 10E)-1, 12-dihydroxy-18-acetoxy-3,7,15-trimethylhexadeca-2,10,14-triene (1) on the basis of spectroscopic studies. Compounds 1 and 2 exhibited cytotoxicity against cultured human tumor cell lines, A549, SK-OV-3, SK-MEL-2, XF498, and $HCT_{15}$, with $ED_{50}$ values ranging from 4.3-10.2 ${\mu}g/ml$ and 4.1-8.3 ${\mu}g/ml$, respectively.

• 대한화학회지
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• 제39권1호
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• pp.66-70
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• 1995

토양에서 얻어진 흄산(HA)을 한외 여과법을 이용 분자량에 따라 4개의 소부분(F1 : 100,000 dalton 이상; F2 : 100,000 dalton 이하;10,000 dalton 이하; F4 : 2,000 dalton 이하)으로 분리한 뒤 적외선 분광법과 핵자기 공명 분광법을 통하여 각 소부분들의 분광학적 특성을 규명하고 상호간에 비교 분석하였다. 4개 소부분들의 $1^H$과 $13^C$ NMR 스펙트럼은 전체적인 특성에서 모두 흄산 모액 스펙트럼과 유사하게 나타났다. 이 결과는 분자량이 변하더라도 흄산의 전체적 특성이 그대로 유지됨을 제시한다. 차이점으로는 IR 스펙트럼 결과 분자량이 적어지면서 다당류 성분 함량이 다소 감소된 반면 카르복실기 성분 함량은 조금 증가된 것으로 나타났다.

• Journal of Photoscience
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• 제12권2호
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• pp.63-66
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• 2005

The azomethine ylide forming photoreaction has been explored by probing the excited state chemistry of several N-trimethylsilylmethyl substituted cyclic and acyclic imides and amide analogs. N-[(Trimethylsilyl)methyl]-N-mesylbenzamide (5) undergoes the excited state C to O silyl migration reaction to produce azomethine ylide intermediate 13. This ylide undergoes electrocyclization to form transient aziridine intermediate 14 which react further by ring opening to generate N-phenacylamine product 10. On the other hand, photolysis of N-[N-mesyl-N-(trimethylsilyl)methyl]aminoethyl-N-mesylbenzamide (8) brings about desilylation resulting in the production of dimer 17.