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http://dx.doi.org/10.14478/ace.2014.1113

Stereocontrolled Dihydroxylation Reactions of Acyclic Allylic Amines  

Jeon, Jongho (Research Division for Biotechnology, Advanced Radiation Technology Institute, Korea Atomic Energy Research Institute)
Shin, Nara (Department of Chemical and Biological Engineering, Seoul National University)
Kim, Young Gyu (Department of Chemical and Biological Engineering, Seoul National University)
Publication Information
Applied Chemistry for Engineering / v.25, no.5, 2014 , pp. 437-446 More about this Journal
Abstract
The dihydroxylation reaction of allylic amines is a facile and useful synthetic method to obtain amino diol structures that are widely found in lots of biologically important natural products. This review will focus on the recent methods of both substrate-controlled and ligand-controlled dihydroxylation reactions of acyclic allylic amines. In addition, several applications of the diastereoselective dihydroxylation methods to asymmetric syntheses of natural products are presented.
Keywords
Dihydroxylation; Acyclic conformation; Asymmetric synthesis; Natural product; Osmium tetroxide;
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