• Title/Summary/Keyword: active surface

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Copper micro/nanostructures as effective SERS active substrates for pathogen detection

  • Ankamwar, Balaprasad;Sur, Ujjal Kumar
    • Advances in nano research
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    • v.9 no.2
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    • pp.113-122
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    • 2020
  • Surface-Enhanced Raman Scattering (SERS) spectroscopy is a multifaceted surface sensitive methodology which exploits spectroscopy-based analysis for various applications. This technique is based on the massive amplification of Raman signals which were feeble previously in order to use them for appropriate identification at qualitative and quantitative in chemical as well as biological systems. This novel powerful technique can be utilized to identify pathogens such as bacteria and viruses. As far as SERS is concerned, one of the most studied problems has been functionalization of SERS active substrate. Metal colloids and nanostructures or microstructures synthesized using noble metals such as Au, Ag and Cu are considered to be SERS active. Silver and gold are extensively used as SERS active substrates due to chemical inertness and stability in air compare to copper. However, use of Cu as a suitable alternative has been taken into account as it is cheap. Herein, we have synthesized air-stable copper microstructures/nanostructures by chemical, electrochemical and microwave-assisted methods. In this paper, we have also discussed the use of as synthesized copper micro/nanostructures as inexpensive yet effective SERS active substrates for the fast identification of micro-organisms like Staphylococcus aureus and Escherichia coli.

Evaluation of Humidity Control Ceramic Board Using Gypsum Binder (석고계 바인더를 활용한 습도도절 세라믹 보드의 특성 평가)

  • Lee, Jong-Kyu;Kim, Tae-Yeon
    • Korean Journal of Materials Research
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    • v.28 no.1
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    • pp.62-67
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    • 2018
  • Active clay, bentonite and zeolite were used as porous materials for humidity controlling ceramic boards. The specific area and the pore volume of active clay were higher than bentonite and zeolite. The flexible strength of the gypsum board decreased with an increasing amount of porous material, and the flexible strength was lowest when active clay with a higher specific surface area than others porous materials was added. The specific surface area and total pore volume of ceramic boards containing porous material were highest at $102.25m^2/g$, $0.142cm^3/g$, respectively, when the active clay was added. In addition, as the amount of added porous materials increased, the specific surface area and total pore volume of the ceramic board increased, but the average pore diameter decreased. The addition of s porous materials with a high specific area and a large pore volume improved the moisture absorptive and desorptive performance of the ceramic board. Therefore, in this experiment, the moisture absorptive and desorptive properties were the best when active clay was added. Furthermore, as the amount of added porous materials increased, the moisture absorptive and desorptive properties improved. When 70 mass% of active clay was added to ${\alpha}$-type gypsum, the hygroscopicity was the highest, about $300g/m^2$, in this experiment.

MERGING AND FRAGMENTATION IN THE SOLAR ACTIVE REGION 10930 CAUSED BY AN EMERGING MAGNETIC FLUX TUBE WITH ASYMMETRIC FIELD-LINE TWIST DISTRIBUTION ALONG ITS AXIS

  • Magara, Tetsuya
    • Journal of The Korean Astronomical Society
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    • v.52 no.4
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    • pp.89-97
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    • 2019
  • We demonstrate the subsurface origin of the observed evolution of the solar active region 10930 (AR10930) associated with merging and breakup of magnetic polarity regions at the solar surface. We performed a magnetohydrodynamic simulation of an emerging magnetic flux tube whose field-line twist is asymmetrically distributed along its axis, which is a key to merging and fragmentation in this active region. While emerging into the surface, the flux tube is subjected to partial splitting of its weakly twisted portion, forming separate polarity regions at the solar surface. As emergence proceeds, these separate polarity regions start to merge and then break up, while in the corona sigmoidal structures form and a solar eruption occurs. We discuss what physical processes could be involved in the characteristic evolution of an active region magnetic field that leads to the formation of a sunspot surrounded by satellite polarity regions.

Subsurface origin of merging and fragmentation in AR10930

  • Magara, Tetsuya
    • The Bulletin of The Korean Astronomical Society
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    • v.44 no.2
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    • pp.41.2-41.2
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    • 2019
  • The aim of this study is to demonstrate the subsurface origin of the complex observed evolution of the solar active region 10930 (AR10930) associated with merging and breakup of magnetic polarity regions at the solar surface. This is important for a comprehensive understanding of observed properties of the active region, because subsurface magnetic flux and subsurface dynamical processes are seamlessly connected to surface magnetic flux and surface dynamical processes, respectively. In other words, the solar surface does not behave as an impermeable boundary towards magnetic flux and dynamical processes. In this talk, we show a magnetohydrodynamic (MHD) model of merging and fragmentation in AR10930. We then discuss what physical processes could be involved in the characteristic evolution of an active region magnetic field that leads to the formation of a sunspot surrounded by satellite polarity regions.

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Novel Synthesis and Nanocharacterization of Graphene and Related 2D Nanomaterials Formed by Surface Segregation

  • Fujita, Daisuke
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.60-60
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    • 2015
  • Nanosheets of graphene and related 2D materials have attracted much attention due to excellent physical, chemical and mechanical properties. Single-layer graphene (SLG) was first synthesized by Blakely et al in 1974 [1]. Following his achievements, we initiated the growth and characterization of graphene and h-BN on metal substrates using surface segregation and precipitation in 1980s [2,3]. There are three important steps for nanosheet growth; surface segregation of dopants, surface reaction for monolayer phase, and subsequent 3-D growth (surface precipitation). Surface phase transition was clearly demonstrated on C-doped Ni(111) by in situ XPS at elevated temperatures [4]. The growth mode was clarified by inelastic background analysis [5]. The surface segregation approach has been applied to C-doped Pt(111) and Pd(111), and controllable growth of SLG has been demonstrated successfully [6]. Recently we proposed a promising method for producing SLG fully covering an entire substrate using Ni films deposited on graphite substrates [7]. A universal method for layer counting has been proposed [8]. In this paper, we will focus on the effect of competitive surface-site occupation between carbon and other surface-active impurities on the graphene growth. It is known that S is a typical impurity of metals and the most surface-active element. The surface sites shall be occupied by S through surface segregation. In the case of Ni(110), it is confirmed by AES and STM that the available surface sites is nearly occupied by S with a centered $2{\times}2$ arrangement. When Ni(110) is doped with C, surface segregation of C may be interfered by surface active elements like S. In this case, nanoscopic characterization has discovered a preferred directional growth of SLG, exhibiting a square-like shape (Fig. 1). Also the detailed characterization methodologies for graphene and h-BN nanosheets, including AFM, STM, KPFM, AES, HIM and XPS shall be discussed.

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Antifungal Activities of Streptomyces blastmyceticus Strain 12-6 Against Plant Pathogenic Fungi

  • Kim, Yeon Ju;Kim, Jae-heon;Rho, Jae-Young
    • Mycobiology
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    • v.47 no.3
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    • pp.329-334
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    • 2019
  • Streptomyces blastmyceticus strain 12-6 was isolated from a forest soil sample of Cheonan area on the basis of strong antifungal activities against plant pathogenic fungi. Butanol extracts of the cultural filtrates were active against C. acutatum, C. coccodes, C. gloeosporioides, F. oxysporum, and T. roseum. Active fractions were prepared by thin layer chromatography using silica gel plate; 12-6-2 ($R_f$ 0.36), 12-6-3 ($R_f$ 0.44). Scanning electron microscopy showed that the active fractions caused a change in surface texture of fungal spores from smooth surface to wrinkled surface. The lethal effect on the spores of the active fractions varied from 56% to 100%. It was shown that the spores of C. acutatum were more sensitive to the antifungal fractions than the spores of F. oxysporum. Fluorescence staining using TOTO-1 indicated that the antifungal fractions could make the spores more sensitive to the fluorescence dye. Thus, it was suggested that antifungal agents prepared in this study exhibited the antifungal activity by damaging the plasma membrane of both fungal spores and hyphae. Identification of antifungal agents in the active fraction using GC-MS analysis revealed the presence of cyclo-(Leu-Pro) and 9-octadecenamide as major components that have already been known as antifungal substances.

Tracking Performance Test of Polymer Insulator with Salt Solution which is added Surface Active Agent (계면활성제가 첨가된 염수용액에 따른 폴리머 애자의 트래킹 성능 평가)

  • Cho, Han-Goo;Han, Dong-Hee;Lee, Un-Yong;Lim, Kee-Joe;Choi, In-Hyuk
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.1121-1124
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    • 2004
  • Aging test to estimate life property of polymer insulator is executed through several international standard such as IEC 61109 and CEA tracking wheel test, but is not getting clear conclusion yet. There are two methods in the diagnosis method of polymer insulator such as off-line and on-line. The diagnosis methods in off-line are external condition analysis by the eye, contaminant analysis on surface, surface analysis, pollution withstand voltage test, power frequency flashover voltage test, lightning impulse flashover test, tensile fracture load test and flexural load test. The diagnosis methods in off-line most are the method for virgin and last aged sample. However, the diagnosis method in on-line is method that can be evaluate sample state as progressing continuously aging test in beginning, The diagnosis method in on-line is arranged as following: leakage current measurement, electric field, surface state investigation, thermal image, emitting light measurement and then so. In this paper, the tracking performance of polymer insulator with salt solution which is added surface active agent. The diagnosis of insulator sample has been analyzed by leakage current and visual examination.

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Evaluation of Copper-Chromium-Arsenic Preservatives Fixation on Wood by Measuring the Density of Surface Electric Charge (표면전하밀도(表面電荷密度)를 이용(利用)한 동(銅)·크롬·비소계(砒素系) 방부방충제의 정착(定着)에 관(關)한 연구(硏究))

  • Kim, Yeong-Suk
    • Journal of the Korean Wood Science and Technology
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    • v.18 no.1
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    • pp.24-30
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    • 1990
  • This study was attempted to propose a method evaluating fixation of active ingredients in Copper-Chromium-Arsenic preservatives treatment. Fixated amount of active ingredients on wood was obtained by measuring the density of surface electric charge based on $\varsigma$ potential. Data accumulated from density of surface electric charge showed that the fixated amount of preservatives on wood increased linearly as concentration of treating solution increaced, which indicatied quantitative reactions in fixation of preservatives.

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Preliminary Studies on the Quality Changes of Eggplant as Influenced by Active Packaging

  • Zuo, Li;Seog, Eun-Ju;Lee, Jun-Ho;Rhim, Jong-Whan
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.38 no.5 s.118
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    • pp.66-73
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    • 2006
  • The effects of active packaging on the surface stiffness, mass, volume, density and weight changes of fresh as well as stored eggplant were studied at 11 and $25^{\circ}C$ for 10 days with active packaging material Type 1 and 2 and control. Mass, volume, and surface stiffness of eggplant decreased linearly throughout the storage period regardless of storage conditions; while the mass density showed a reverse trend in the ease of $11^{\circ}C$ storage. Reduction rate of mass, mass density and weight was observed minimum at $25^{\circ}C$ storage temperature with active packaging Type 1. The weight of eggplant decreased at a higher rate in the initial 4 days compared to that in the later period of storage regardless of storage temperature and type of packaging.

Synthesis and Surface Active Properties of Amphoteric Surfactant Derivatives(II);Surface Active Properties of N-Alkyl or Acyl Hydroxy sulfobetaines (양쪽성 이온 계면활성제의 유도체합성 및 계면성에 관한 연구(제2보);N-알킬 혹은 아실히드록시 술포베타인류의 계면성)

  • Lee, J.H.;Ha, J.W.;Park, H.J.;No, Y.C.;Nam, K.D.
    • Journal of the Korean Applied Science and Technology
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    • v.11 no.1
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    • pp.79-85
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    • 1994
  • All the activities and physical properties including surface tension' foaming power, foam stability, emulsifying power, dispersion effect of 3-(N, N-dimethyl N-alkylammonio)-2-hydroxyY-1-propane sulfonate (HSB)류와 3-CN-alkylamidopropyl-N,N-dimethylamm-onjo)-2-hydroxy-1-propane sulfonate (APSB) aquous solution were measured and critical micelle concentration was evaluated. Their cmc of hydroxy sulfobetaine derivatives evaluated by the surface tension method was $1.0{\times}10^{-3}{\sim}1.0{\times}10^{-4}$ mol/l, and surface tension of the aquous solution was decreased to $27{\sim}38dyne/cm$. The experimental results for foaming power, foam stability, emulsifying power in liquid paraffin showed a good surface active properties, especially, dispersion effect in ferric oxide exhibited some efficient surface active properties, and then it would be expected to application as detergent and dispersion agent.