• Title/Summary/Keyword: acrylonitrile-butadiene-styrene

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Retentive Force of Adjustable Dental Impression Trays with Different Synthetic Resin Materials (합성수지 재료에 따른 가변형 치과 인상용 트레이의 유지력에 관한 연구)

  • Lee, In-Seob;Lee, jin-Han;Kim, Yu-Lee;Dong, Jin-Keun
    • Journal of Dental Rehabilitation and Applied Science
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    • v.22 no.1
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    • pp.11-21
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    • 2006
  • The adjustable dental impression trays were made for being adjusted their width automatically along the width of patient's dental arch. The purpose of this study was to investigate the retentive force of adjustable dental impression trays made of different synthetic resin materials. Three pairs of adjustable trays were made of ABS(acrylonitrile butadiene styrene) synthetic resin, polyurethane synthetic resin and polycarbonate synthetic resin with a hole and without a rim on the border area of them. The experiment was done with the horse-shoe shaped metal plate to pull out the set impression body from the tray jig which was made for holding the tray on the lower part of Universal Testing Machine(UTM, Zwick Z020, Zwick Co., Germany). After the alginate impression in the tray was allowed to set four minutes, a tensile force was applied at right angles to the tray which had been previously seated on the jig. The force was applied to measure a maximum force by use of UTM at a constant strain rate 100mm per minute. The results obtained in this study were as follows : 1. The upper trays were showed higher retentive force than lower trays in three tray materials. 2. There was no significant difference in the retentive force of the tray materials(p>0.05).

Development of Triboelectrostatic Separation Technique for Material Separation of ABS and PS Mixed Plastic Waste (ABS와 PS 혼합(混合) 폐플라스틱 재질분리(材質分利)를 위한 마찰하전형정전선별(摩擦荷電型靜電選別) 기술개발(技術開發))

  • Lee, Eun-Seon;Baek, Sang-Ho;Kim, Su-Kang;Choi, Woo-Zin;Chin, Ho-Ill;Jeon, Ho-Seok
    • Resources Recycling
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    • v.22 no.6
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    • pp.33-40
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    • 2013
  • Due to the environmental problem caused by plastics largely used in various fields, the importance of recycling is being emphasized. A research on material separation of ABS and PS mixed plastic waste, using a triboelectrostatic separator, was carried out for recovery the ABS. As a results of research on charging characteristic for choosing charging material, it was confirmed that ABS was optimum charging material for a tribo-charger in the material separation of ABS and PS. In the material separation using ABS charger, ABS grade of 99.5% and recovery of 92.5% were achieved at 20 kV, splitter position +2 cm from the center and 30% relative humidity. Therefore, material separation technique for recycling ABS and PS mixed plastic waste was established.

Understanding Three-dimensional Printing Technology, Evaluation, and Control of Hazardous Exposure Agents (3D 프린팅 기술의 이해, 유해 인자 노출 평가와 제어)

  • Park, Jihoon;Jeon, Haejoon;Oh, Youngseok;Park, Kyungho;Yoon, Chungsik
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.28 no.3
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    • pp.241-256
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    • 2018
  • Objectives: This study aimed to review the characteristics of three-dimensional printing technology focusing on printing types, materials, and health hazards. We discussed the methodologies for exposure assessment on hazardous substances emitted from 3D printing through article reviews. Methods: Previous researches on 3D printing technology and exposure assessment were collected through a literature review of public reports and research articles reported up to July 2018. We mainly focused on introducing the technologies, printing materials, hazardous emissions during 3D printing, and the methodologies for evaluation. Results: 3D printing technologies can be categorized by laminating type. Fused deposition modeling(FDM) is the most widely used, and most studies have conducted exposure assessment using this type. The printing materials involved were diverse, including plastic polymer, metal, resin, and more. In the FDM types, the most commonly used material was polymers, such as acrylonitrile-butadiene-styrene(ABS) and polylactic acids(PLA). These materials are operated under high-temperature conditions, so high levels of ultrafine particles(mainly nanoparticle size) and chemical compounds such as organic compounds, aldehydes, and toxic gases were identified as being emitted during 3D printing. Conclusions: Personal desktop 3D printers are widely used and expected to be constantly distributed in the future. In particular, hazardous emissions, including nano sized particles and various thermal byproducts, can be released under operation at high temperatures, so it is important to identify the health effects by emissions from 3D printing. Furthermore, appropriate control strategies should be also considered for 3D printing technology.

Size Distributions of Particulate Matter Emitted during 3D Printing and Estimates of Inhalation Exposure (3D 프린팅 가동 조건 별 발생 입자크기 분포와 흡입 노출량 추정)

  • Park, Jihoon;Jeon, Haejoon;Park, Kyungho;Yoon, Chungsik
    • Journal of Environmental Health Sciences
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    • v.44 no.6
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    • pp.524-538
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    • 2018
  • Objective: This study aimed to identify the size distributions of particulate matter emitted during 3D printing according to operational conditions and estimate particle inhalation exposure doses at each respiratory region. Methods: Four types of printing filaments were selected: acrylonitrile-butadiene-styrene (ABS), polylactic acid (PLA), Laywood, and nylon. A fused deposition modeling (FDM) 3D printer was used for printing. Airborne particles between 10 nm and $10{\mu}m$ were measured before, during, and after printing using real-time monitors under extruder temperatures from 215 to $290^{\circ}C$. Inhalation exposures, including inhaled and deposited doses at the respiratory regions, were estimated using a mathematical model. Results: Nanoparticles dominated among the particles emitted during printing, and more particles were emitted with higher temperatures for all materials. Under all temperature conditions, the Laywood emitted the highest particle concentration, followed by ABS, PLA, and nylon. The particle concentration peaked for the initial 10 to 20 minutes after starting operations and gradually decreased with elapsed time. Nanoparticles accounted for a large proportion of the total inhaled particles in terms of number, and about a half of the inhaled nanoparticles were estimated to be deposited in the alveolar region. In the case of the mass of inhaled and deposited dose, particles between 0.1 and $1.0{\mu}m$ made up a large proportion. Conclusion: The number of consumers using 3D printers is expected to expand, but hazardous emissions such as thermal byproducts from 3D printing are still unclear. Further studies should be conducted and appropriate control strategies considered in order to minimize human exposure.

Investigation of Labeling Status and Toxicity Data of Environmentally Hazardous Substances in Children's Products (어린이용품의 환경유해인자 표시 현황과 독성자료에 대한 연구)

  • Lee, Jiyun;Kim, Jihyo;Moon, Myunghee;Lee, Kiyoung;Ji, Kyunghee
    • Journal of Environmental Health Sciences
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    • v.45 no.5
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    • pp.443-456
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    • 2019
  • Objectives: Children are exposed to various environmental pollutants through contact with children's products. We investigated the KC mark, certification number, and contained substances labeled on children's products through market research and collected the toxicological data on these substances. Methods: The environmentally hazardous substances labeled on children's products (n=6576), including toys (n=2812), personal care products (n=2212), stationary/books (n=1333), and playground equipment (n=219) were examined. For the components that could be identified by CAS number, toxicological data on oral, inhalation, and dermal routes, cancer slope factor, and reference dose were collected. Results: Among the investigated products, KC marks or certification numbers were found for 4557 products (69.3%). Except for cosmetics and cleansers, the material information was labeled on most of the products. The frequency of labeling substance information in toys and stationary/books was low since this information could be omitted if KC certification was obtained. In the target products, 617 substances were identified by CAS number, and polypropylene, acrylonitrile butadiene styrene, and polyester were the most frequently displayed. Chronic toxicity data was found for only 32.4% of individual components, and information on toxicity through the dermal route was also highly limited. Conclusion: Our study suggested that labeling guidelines should be required to identify the environmentally hazardous substances contained in children's products. In addition, the toxicological data on many ingredients in children's products were insufficient. The data gap for toxicity data should be filled for future risk assessment.

Tribological Characteristics of ABS-like Resin According to Silicon Oil Viscosity (실리콘 오일 점도에 따른 ABS-like 레진의 트라이볼로지 특성)

  • Park, Seonghyun;Son, Jungyu;Woo, Seongwoong;Ryu, Euijin;Lee, Hyunseop
    • Tribology and Lubricants
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    • v.36 no.6
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    • pp.365-370
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    • 2020
  • Recently, additive manufacturing (AM) technology has been applied to various industries such as automotive, aviation, medical, and electronics. Most prior studies are limited to the mechanical properties of printed materials, and few studies are being conducted on their tribological characteristics. However, the friction and wear characteristics of the material should be studied in order to utilize the components manufactured using AM technology as mechanical parts. In this study, the friction and wear characteristics of acrylonitrile-butadiene-styrene (ABS)-like resin printed with stereo lithography apparatus (SLA) 3D printing are evaluated according to the viscosity of silicon oil lubricant using a ball-on-disk experiment. Lubricants with a viscosity of 500, 1000, and 2000 cSt are prepared for the experiment. If silicon oil lubricants are used during the ball-on-disk test, the coefficient of friction (COF) and wear rates are significantly reduced, and the higher the viscosity of the lubricant, the lower will be the COF and wear rates. It is also verified that the temperature of the specimen owing to friction also decreases according to the viscosity of the lubricant. This is because of the silicon oil film thickness, and the higher the viscosity of the lubricant, the thicker will be the oil film. More studies on the tribological characteristics of 3D printing materials and suitable lubricants will be required to use 3D printed parts as mechanical elements.

Characterization of ABS/PC/POE Thermoplastic Composites and Prediction of Mechanical Properties by Geometry Simulation (ABS/PC/POE 열가소성 복합재료의 특성평가 및 시뮬레이션을 통한 물리적 성능 예측 연구)

  • Yu, Seong-Hun;Lee, Jong-Hyuk;Yeo, Dong-Hyun;Shin, Yong-Ho;Park, Jong-Su;Sim, Jee-Hyun
    • Textile Coloration and Finishing
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    • v.34 no.2
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    • pp.117-126
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    • 2022
  • In this study, thermoplastic composites were manufactured using ABS(acrylonitrile butadiene styrene), PC(polycarbonate), and POE(polyolefin elastomer), which are thermoplastic plastics. Twin screw extruder and injection molding were used to manufacture thermoplastic composites. When the ABS/PC/POE thermoplastic composite material was manufactured, the POE mass fraction was set to 1 to 5 wt.%, and the thermal and mechanical properties according to the POE mass fraction were analyzed. Based on the physical properties of ABS/PC/POE, a 3D model in the form of an e-bike frame was created. After setting the boundary conditions, when an external load is applied, geometry simulation was performed to predict product performance. The ABS/PC/POE thermoplastic composite material exhibited the best physical properties when the mass fraction of POE was 3 wt.%. In the simulation results for the physical properties of the 3D model in the form of an e-bike frame, the best physical properties were shown when the mass fraction of POE was 2 ~ 3 wt.%. As a result, the manufacturing conditions for ABS/PC/POE thermoplastic composite materials were set, and research was conducted to reduce product development costs and development time.

Structural Model Test for Strength Performance Evaluation of Fairlead Chain Stopper Installed on MW Class Floating Type Offshore Wind Turbine (메가와트급 부유식 해상풍력발전기용 페어리드 체인 스토퍼의 강도 성능평가를 위한 구조 모형 시험)

  • Chang-Yong Song
    • Journal of the Korean Society of Industry Convergence
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    • v.26 no.3
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    • pp.421-431
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    • 2023
  • Recently, the destructive power of typhoons is continuously increasing due to the influence of global warming. In a situation where the installation of floating wind turbines is increasing around the world, concerns about the huge loss and collapse of floating offshore wind turbines due to strong typhoons are deepening. Regarding to the safe operation of the floating offshore wind turbine, the development of a new type of disconnectable mooring system is required. A new fairlead chain stopper considered in this study is devised to more easily attach or detach the floating offshore wind turbine with mooring lines comparing to other disconnectable mooring apparatuses. In order to investigate the structural safety of the initial design of fairlead chain stopper that can be applied to MW-class floating type offshore wind turbine, scale-down structural models were produced using a 3-D printer and structural tests were performed on the models. For the structural tests of the scale-down models, tensile specimens of acrylonitrile butadiene styrene material that was used in the 3-D printing were prepared, and the material properties were evaluated by performing the tensile tests. The finite element analysis of fairlead chain stopper was performed by applying the material properties obtained from the tensile tests and the same load and boundary conditions as in the scale-down model structural tests. Through the finite element analysis, the structural weak parts on the fairlead chain stopper were reviewed. The structural model tests were performed considering the main load conditions of fairlead chain stopper, and the test results were compared to the finite element analysis. Through the results of this study, it was possible to experimentally verify the structural safety of the initial design of fairlead chain stopper. It is also judged that the study results can be usefully used to improve the structural strength of fairlead chain stopper in a detailed design stage.

Study on the Strength Characteristics of PP and ABS According to the Ratio of Recycled Resin (재사용 수지 비율에 따른 PP, ABS의 강도 특성에 관한 연구)

  • Jun-Han Lee;Jong-Sun Kim
    • Design & Manufacturing
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    • v.18 no.2
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    • pp.57-63
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    • 2024
  • In this study, the recyclability of commonly used PP (polypropylene) and ABS (acrylonitrile butadiene styrene) was evaluated by molding test specimens from mixture of virgin and shredded material, followed by measuring their strength properties, Experiments were conducted o two type of PP (transparent and non-transparent) and two types of ABS (white and yellow). Test specimens for each resin were prepared with shredded material ratios ranging from 10% to 50% in 10% increments. Changes in tensile strength, elastic modulus, and elastic limit were analyzed based on the mixing ratio of the shredded material. The experimental results demonstrated that the strength properties of all the resins remained consistent within a certain range, even with increasing proportions of shredded material. For transparent PP, the tensile strength ranged from 30.87± MPa, the elastic modulus from 1.23±0.04 GPa, and the elastic limit from 19.17±0.44%. Non-transparent PP exhibited a tensile strength ranging from 27.71±0.58 MPa, an elastic modulus from 1.03±0.06 GPa, and an elastic limit from 17.35±0.41%. For ABS, white ABS had a tensile strength of 39.42±0.28 MPa, an elastic modulus of 1.94±0.01 GPa, and an elastic limit of 36.76±0.25%. Yellow ABS showed a tensile strength of 39.25±0.78 MPa, an elastic modulus of 1.94±0.01 GPa, and an elastic limit of 37.14±0.23%, with values remaining consistent within this range. Based on these results, it was confirmed that the mechanical properties of the resins used in this study do not change significantly when mixed with recycled shredded material, indicating excellent mechanical recyclability.

Effects of Phenolic and Phosphite Antioxidants on the properties for PC/ABS Blends during High-Shear-Rate Processing (고속 전단 가공에서 페놀계와 인산계 산화방지제에 의한 PC/ABS 블렌드의 물성 변화 연구)

  • Lee, Han Ki;Kim, Seon Hong;Lee, Hyung Il;Yoo, Jae Jung;Yong, Da Kyoung;Choi, Seok Jin;Lee, Seung Goo;Lee, Kee Yoon
    • Korean Chemical Engineering Research
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    • v.52 no.2
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    • pp.266-271
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    • 2014
  • The effects of antioxidants on the properties of Polycarbonate/Acrylonitrile-Butadiene-Styrene(PC/ABS) blends were studied for the functions of the screw speed and loaded duration of high shear rate processing in order to investigate the degradation for PC/ABS blends. Tris-(2,4-di-tert-butyl-phenyl phosphate) (A1) and Bis(2,4-dicumylphenyl) pentaerythritol diphosphite (A3) as phosphite antioxidants and Octadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate (A2) as a phenolic antioxidant are used. The thermal properties were detected by TGA and severely decreased, after the processing. The stress-induced and thermal degradation for PC/ABS blends with the antioxidant A3 was retarded better than the others. By using UTM, the mechanical properties also showed individually decreased according to the antioxidants, after the processing, especially, the elongations showed considerable decline behaviors, while the tensile strengths of PC/ABS blends changed very little. For example, in the operating conditions of 1000rpm of screw speed and 20 seconds of loaded period, the elongations decreased from 148% before the processing, to 91.6% with the A1, to 63% with the A2 and to 131% with the A3 after the processing, respectively. In order to get the morphological properties, the size distributions of the dispersed phases for PC/ABS were investigated by SEM analysis and tended to decrease, as the screw speed and loaded period of the processing increased. Therefore, we confirmed that the antioxidant A3 was the best of all of three to inhibit the stress-induced degradation of PC/ABS blends during the high shear rate processing.