• Title/Summary/Keyword: acid neutralization

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Antimicrobial Effects of Lactic Acid Bacteria Isolated from Tibetan Yogurt against Foodborne Pathogenic Bacteria (티베트 요거트에서 분리한 유산균의 병원성 세균 항균 효과 연구)

  • Gho, Ju Young;Lee, Jiyeon;Choi, Hanhee;Park, Sun Woo;Kang, Seok-Seong
    • Journal of Dairy Science and Biotechnology
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    • v.39 no.3
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    • pp.121-127
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    • 2021
  • Yogurt is produced by bacterial fermentation of milk and contains lactic acid bacteria (LAB), which produce various metabolites such as organic acid, hydrogen peroxide, and bacteriocin. This study aimed to investigate cell-free supernatants (CFS) of LAB isolated from Tibetan yogurt. CFS (TY1, TY2, TY3, TY4, TY5, TY6, and TY7) from selected strains of LAB were co-incubated with four different foodborne pathogenic bacteria, namely E. coli O157:H7, Listeria monocytogenes, Salmonella typhimurium, and Staphylococcus aureus. Inhibition of foodborne pathogenic bacterial growth was not affected in the presence of CFS (pH 6.5). In contrast, CFS without neutralization completely inhibited the growth of the bacteria. Furthermore, when the concentration of CFS (without neutralization) was changed to 1:4 and 1:8, a difference in inhibition was observed between Gram-positive and Gram-negative bacteria. CFS more effectively inhibited the growth of Gram-negative E. coli O157:H7 and S. Typhimurium than Gram-positive L. monocytogenes and S. aureus. These results suggest that organic acids in LAB may inhibit the growth of foodborne pathogenic bacteria, particularly Gram-negative bacteria.

Kinetics Study of $2^{nd}$ Hydrolysis in Concentrated Sulfuric Acid Hydrolysis Process by $^1H-NMR$ Spectroscopy (진한 황산 가수분해에서 2단계 산 가수분해 반응에서 일어나는 반응 동역학(Kinetics)을 $^1H-NMR$을 사용한 연구)

  • Shin, Soo-Jeong;Kim, Yong-Hwan;Cho, Dae-Haeng;Sung, Yong-Joo;Kim, Byung-Ro;Cho, Nam-Seok
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2011.04a
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    • pp.93-99
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    • 2011
  • Proton-NMR spectroscopic method was applied to kinetics study of concentrated sulfuric acid hydrolysis reaction. Xylan was used as model compounds. Without neutralization steps in proton-NMR methods, this analysis method is valid for analysis of xylose, furfural and formic acid in acid hydrolyzates.

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Nonlinear pH Control Using a Three Parameter Model

  • Lee, Jie-Tae;Park, Ho-Cheol
    • Transactions on Control, Automation and Systems Engineering
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    • v.2 no.2
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    • pp.130-135
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    • 2000
  • A two parameter model of a single fictitious weak acid with unknown dissociation constant has been successfully applied to design a neutralization system for many multi-component acid streams. But there are some processes for which above two parameter model is not satisfactory due to poor approxmation of the nonlinearity of pH process. Here, for etter control of wide class of multi-component acid streams, a three parameter model of a strong acid and a weak acid with unknown dissociation constant is proposed. The model approximates effectively three types of largest gain variation nonlinearities. Based on this model a nonlinear pH control system is designed. Parameters can eeasily estimated since their combinations appear linearly in the model equations and nonlinear adaptive control system may also be constructed just as with the two parameter model.

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Synthesis of DL-Aminoalkyl Phosphonic Acids and Their Derivatives (III) (DL-Aminoalkyl Phosphonic Acid와 그 유도체들의 합성 (제3보))

  • Man Khyun Rho;Yong Joon Kim
    • Journal of the Korean Chemical Society
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    • v.17 no.2
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    • pp.136-141
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    • 1973
  • DL-1-aminobutylphosphonic acid was synthesized from the pentanoic acid which was prepared from the butyl alcohol, by the modified Curtius reaction. DL-2-amino-2-carboxyethylphosphonic acid was also synthesized from the pyruvic acid was also synthesized from the pyruvic acid. Four previously unreported N-acylated derivatives were prepared according to the modified Schotten-Baumann method. They are as follows; N-acetyl-DL-1-aminobutylphosphonic acid, N-benzoyl-DL-1-aminobutylphosphonic acid, N-benzoyl-DL-2-amino-2-carboxyethylphosphonic acid, N-p-chlorobenzoyl-DL-2-amino-2-carboxyethylphosphonic acid. The products were identified by the methods of elemental analysis, infrared spectra, ninhydrin test and neutralization equivalent.

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Effect of SCODMn and pH Adjustment on Physicochemical Characteristics in Liquid Fertilizer Production Process Using Swine Manure (SCODMn 농도 및 pH 조정이 양돈분뇨의 후숙발효과정에 미치는 이화학적 영향)

  • Hong, In-Gi;Kim, Soo-Ryang;Lee, Myung-Gyu
    • Journal of Animal Environmental Science
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    • v.18 no.sup
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    • pp.13-20
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    • 2012
  • This research investigated the effect of $SCOD_{Mn}$ concentrations and pH adjustment at the stage before land application, namely 2nd-aeration treatment stage of liquid fertilizer in the liquid fertilizer treatment process of swine manure on the physicochemical compositions of 2nd-aeration treated liquid fertilizer. The liquid fertilizer used in this research is the alkaline fermented liquid fertilizer of swine manure more than pH 9.0 through aeration treatment (Alkaline fermentation treatment group). About the alkaline liquid fertilizer, phosphate neutralization treatment was conducted with phosphoric acid and it was a phosphate neutralization treatment group. In 2nd-aeration treatment of liquid fertilizer for 30 days, each group was divided into alkaline treatment groups (T-1, T-2, and T-3) and phosphate neutralization treatment groups (T-4, T-5, and T-6) according to early $SCOD_{Mn}$ concentrations. The research results are as follows. 1. As for $SCOD_{Mn}$ reduction rate, the average 29.9% in alkaline treatment groups and the average 36.9% in phosphate neutralization treatment groups were shown and so the relatively high reduction rate was shown in phosphate neutralization treatment groups. 2. After finishing the experiment, the group of the lowest $SCOD_{Mn}$ concentrations was the phosphate neutralization treatment group, T-6 with the lowest inflow concentrations. In case the final goal level of 2nd-aeration treated liquid fertilizer is assumed as concentrations less than $SCOD_{Mn}$ 3,000 ppm, it would be desired that inflow concentrations of 2nd-aeration treatment groups are adjusted less than $SCOD_{Mn}$ 5,500 ppm. 3. As for the persistence rate of nitrogen, the average 29.3% in alkaline treatment groups and the average 38.9% in phosphate neutralization treatment groups were shown and so phosphate neutralization treatment groups showed the relatively low loss rate of nitrogen, meanwhile, in the case of T-P, phosphate neutralization treatment groups maintained high concentrations (average 1,473 ppm). 4. In the event of 2nd-aeration treatment of liquid fertilizer, "alkaline fermentation treatment" condition in 'low phosphate-low nitrogen' type and "phosphate neutralization treatment" condition in 'high phosphate-high nitrogen' type are expected to be favorable.

The study on the formation of titanic acid by dehydration of TiCl₄ (TiCl₄가수분해에 의한 titanic acid의 생성에 관한 연구)

  • Kim, Heon;Kim, Dae Ung;Lee, Gyeong Hui;Baek, Un Pil
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.2
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    • pp.342-342
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    • 1998
  • The effect of pH on the dehydration reaction of TiCl₄solution. KOH and HCl were used as a accelerater and retarder in dehydration. Results are follow. Neutralization point is pH 7.4 in the system of $TiCl_4-KOH$ and the production which is produced at acidic side is Ti-gel of poly metatitanic acid. The production which is produced at alkalic side is aligomer and crystalline potasium titanate is not detected.

Development of a Concentration Measurement System for Pickling Line Control (산세라인 자동화를 위한 농도 측정 시스템 개발)

  • Park, Hyoung-Kuk;Lee, Jong-Hyun;Noh, Ill-Hwan
    • Journal of Institute of Control, Robotics and Systems
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    • v.19 no.10
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    • pp.891-895
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    • 2013
  • This paper proposes the development of a new method for online analysis which measured acid concentration in a pickling line. Pickling is the most important step to remove surface scale layers and is strongly depending on the exactly controlled pickling liquor composition. Today, there is no feasible system available for the online control of pickling lines. Within this paper, new methods for online analysis of pickling liquors have been tested and implemented into an overall pickling process control tool. This method measured simultaneously the hydrochloric acid and iron ion concentration in a solution of hydrochloric acid by measuring the ultrasonic speed, the solution temperature, and the electrical conductivity. Experimental results showed excellent precision and the measurement error was ${\pm}2g/l$ compared with the neutralization titration measurement.

Effects of Polymerization Parameters on Absorption Properties of an Itaconic Acid-based Superabsorbent Hydrogel

  • Kim, Dong Hyun
    • Elastomers and Composites
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    • v.54 no.3
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    • pp.232-240
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    • 2019
  • A superabsorbent hydrogel (SAH) can absorb and retain water weighing more than a hundred times of their dry weight because of their three-dimensional hydrophilic structure. To fabricate an SAH, itaconic acid (IA) and vinyl sulfonic acid (VSA) were subjected to radical polymerization in an aqueous solution, wherein IA and VSA were neutralized, and then, a crosslinker and a thermal initiator were added in sequence. The structure of poly(IA-co-VSA) was characterized using attenuated total reflectance Fourier-transform infrared spectroscopy. We also studied the changes in the absorption properties of the SAH composites according to the polymerization temperature, degree of neutralization, type and content of the initiator used, and type and content of the crosslinker used. Thus, we could determine the effects of some synthetic factors on the absorption properties of the SAH.

The Effects of K-Addition and the Catalytic Dehydrogenation of Ethylbenzene on Ferrite Catalysts (페라이트 촉매의 K 첨가효과와 에틸벤젠의 탈수소반응)

  • Kim, Ki-Chul;Lee, Gun Dae;Lee, Ho-In
    • Applied Chemistry for Engineering
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    • v.3 no.4
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    • pp.722-729
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    • 1992
  • Mg-and Zn-ferrites having spinel structure, a kind of complex oxides showing the advantageous properties of constituently single metal oxides, were selected to find a relationship between their catalytic activities in the dehydrogenation of ethylbenzene to styrene and the catalytic properties. For the structural and physical analyses of ferrites, XRD, BET, DTA, XPS, TEM and TPD methods were employed. Potassium added to the catalyst played a role of bifunctional promoter which brought the electronic effect as well as the structural one for the increment of particle dispersion. K-addition decreased acid strength of the catalyst by neutralization and increased its acidity. In the dehydrogenation of ethylbenzene, K-addition let the selectivity to styrene be constant throughout the reaction by the proper acid strength of the ferrite for the reaction, which could be obtained from the neutralization of strong acid sites by potassium.

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Industrial Synthesis for α-Sulfonation of Fatty Acid Methyl Ester (알파술폰화 고급지방산 메틸 에스테르의 공업적 합성)

  • Kim, Jin-Hyun;Choi, Seung-Ok;Yun, Young-Kyun;Nam, Ki-Dae
    • Applied Chemistry for Engineering
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    • v.9 no.4
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    • pp.595-602
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    • 1998
  • ${\alpha}$-sulfonated fatty acid methyl esters[$C_mH_{2m+1}CH(SO_3Na)COOC_nH_{2n+1}$], where hydrophobic group has carbon number of 12~18, were prepard by sulfonation of fatty acid methylester. The mole ratio of $SO_3$ to ester used was 1.3 and the reaction temperature was $70{\sim}90^{\circ}C$. The yield was found to be 97% by mixed gas reaction of inactive gas/gaseous $SO_3$. Studies on bleaching and neutralization processes in the pilot scale provided conditions applicable to industrial synthesis process.

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