• 제목/요약/키워드: absorption ratio

검색결과 1,763건 처리시간 0.031초

INFRARED ABSORPTION MEASUREMENT DURING LOW-TEMPERATURE PECVD OF SILICON-OXIDE FILMS

  • Inoue, Yasushi;Sugimura, Hiroyuki;Takai, Osamu
    • 한국표면공학회지
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    • 제32권3호
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    • pp.297-302
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    • 1999
  • In situ measurement of infrared absorption spectra has been performed during low-temperature plasma-enhanced chemical vapor depositiion of silicon-oxide films using tetramethoxysilane as a silicon source. Several absorption bands due to the reactant molecules are clearly observed before deposition. In the plasma, these bands completely disappear at any oxygen mixing ratio. This result shows that most of the tetramethoxysilane molecules are dissociated in the rf plasma, even C-H bonds. Existence of Si-H bonds in vapor phase and/or on the film surface during deposition has been found by infrared diagnostics. We observed both a decrease in Si-OH absorption and an increase in Si-O-Si after plasma off, which means the dehydration condensation reaction continues after deposition. The rate of this reaction is much slower than the deposition ratio of the films.

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전자빔 증착으로 제조한 $CuInS_2$ 박막의 구조적 및 광학적 특성 (Structural and optical properties of $CuInS_2$ thin films fabricated by electron-beam evaporation)

  • 박계춘;정운조
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
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    • pp.193-196
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    • 2001
  • Single phase $CuInS_2$ thin film with the highest diffraction peak (112) at diffraction angle $(2\theta)$ of $27.7^{\circ}$ and the second highest diffraction peak (220) at diffraction angle $(2\theta)$ of $46.25^{\circ}$ was well made with chalcopyrite structure at substrate temperature of $70^{\circ}C$, annealing temperature of $250^{\circ}C$, annealing time of 60 min. The $CuInS_2$ thin film had the greatest grain size of $1.2{\mu}m$ and Cu/In composition ratio of 1.03. Lattice constant of a and c of that $CuInS_2$ thin film was 5.60 A and 11.12 A respectively. Single phase $CuInS_2$ thin films were accepted from Cu/In composition ratio of 0.84 to 1.3. P-type $CuInS_2$ thin films were appeared at over Cu/In composition ratio of 0.99. Under Cu/In composition ratio of 0.96, conduction types of $CuInS_2$ thin films were n-type. Also, fundamental absorption wavelength, the absorption coefficient and optical energy band gap of p-type $CuInS_2$ thin film with Cu/In composition ratio of 1.3 was 837 nm, $3.0{\times}104cm^{-1}$ and 1.48 eV respectively. When Cu/In composition ratio was 0.84, fundamental absorption wavelength, the absorption coefficient and optical energy band gap of n-type $CuInS_2$ thin film was 821 nm, $6.0{\times}10^4cm^{-1}$ and 1.51 eV respectively.

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전자빔 층착으로 제조한 $CuInS_2$ 박막의 구조적 및 광학적 특성 (Structural and optical properties of $CuInS_2$ thin films fabricated by electron-beam evaporation)

  • 박계춘;정운조
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집
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    • pp.193-196
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    • 2001
  • Single phase CuInS$_2$ thin film with the highest diffraction peak (112) at diffraction angle (2$\theta$) of 27.7$^{\circ}$ and the second highest diffraction peak (220) at diffraction angle (2$\theta$) of 46.25$^{\circ}$ was well made with chalcopyrite structure at substrate temperature of 70 $^{\circ}C$, annealing temperature of 25$0^{\circ}C$, annealing time of 60 min. The CuInS$_2$ thin film had the greatest grain size of 1.2 ${\mu}{\textrm}{m}$ and Cu/In composition ratio of 1.03. Lattice constant of a and c of that CuInS$_2$ thin film was 5.60 $\AA$ and 11.12 $\AA$ respectively. Single phase CuInS$_2$ thin films were accepted from Cu/In composition ratio of 0.84 to 1.3. P-type CuInS$_2$ thin films were appeared at over Cu/In composition ratio of 0.99. Under Cu/In composition ratio of 0.96, conduction types of CuInS$_2$ thin films were n-type. Also, fundamental absorption wavelength, the absorption coefficient and optical energy band gap of p-type CuInS$_2$ thin film with Cu/In composition ratio of 1.3 was 837 nm, 3.0x10 $^4$ $cm^{-1}$ / and 1.48 eV respectively. When CuAn composition ratio was 0.84, fundamental absorption wavelength, the absorption coefficient and optical energy band gap of n-type CuInS$_2$ thin film was 821 nm, 6.0x10$^4$ $cm^{-1}$ / and 1.51 eV respectively.

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폐석분 및 바텀애시를 사용한 인공경량골재의 융제(Flux) 종류에 따른 밀도 및 흡수율 특성 (Density and Water Absorption Characteristics of Artificial Lightweight Aggregates containing Stone-Dust and Bottom Ash Using Different Flux)

  • 한민철;신재경
    • 한국건설순환자원학회논문집
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    • 제7권3호
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    • pp.49-55
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    • 2012
  • 본 연구에서는 인공경량골재의 주요 물성인 밀도 및 흡수율의 성능 향상을 위하여 융제 종류 및 첨가율에 따른 밀도 및 흡수율 특성을 검토하였다. 실험결과, 화학제품의 융제 사용에 관한 특성으로, $Na_2CO_3$$CaSO_4$는 경우 낮은 소성온도에서 소성이 가능하나, 흡수율이 증가하였고, $CaCO_3$, NaOH, $Fe_2O_3$는 첨가율이 증가할수록 흡수율은 낮아졌으나, 절건밀도가 높아지는 것으로 나타나 융제로서 부적합하였다. $Na_2SO_4$의 사용한 경우에는 절건밀도 $1.35{\sim}1.50g/cm^3$와 상대적으로 낮은 흡수율로 융제로서 가장 적합하였다. 산업부산물의 융제 사용에 관한 특성으로 유리연마 슬러지는 절건밀도 $1.45{\sim}1.55g/cm^3$ 및 흡수율 9~12 %로 흡수율이 높게 나타났다. 고로슬래그 미분말은 첨가율이 증가할수록 밀도는 높아지고 흡수율은 낮아지는 것으로 나타났다. 산화슬래그는 첨가율 10 %에서 절건밀도 $1.46g/cm^3$, 흡수율 8,5 %로 낮은 절건밀도와 흡수율을 갖는 양질의 인공경량골재를 제조할 수 있었다.

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랜덤입사방법에 의한 포러스 콘크리트의 흡음특성에 관한 실험적 연구 (The Study on Sound Absorbing Characteristics of Porous Concrete according to Reverberation Room Methods)

  • 서대석;박승범;조광연;장영일;김형석;이윤선
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2004년도 춘계 학술발표회 제16권1호
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    • pp.568-571
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    • 2004
  • This research estimated the physical. mechanical characteristic and the character of sound absorption according to target void ratio of porous concrete and the mixing ratio of recycled aggregate for the valid utilization of recycled aggregate using waste concrete and sound reduction out of a road, a railway, a residential street, and a downtown area. As a result of the test, compressive strength tended to be a radical strength fall when target void ratio was $25\%$ and contents of recycled aggregate exceeded over $50\%$. Also, the character of sound absorption of porous concrete which used recycled aggregate using waste concrete was the most excellent when target void ratio was $25\%$, and the influence by contents of recycled aggregate was trivial. Therefore, when the strength and the character of sound absorption of porous concrete are considered, it is proved valid that proper target void ratio was $25\%$ and contents of recycled aggregate using waste concrete was $50\%$ or so.

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Specific Gravity and Dimensional Stability of Boron-Densified Wood on Three Lesser-Used Species from Indonesia

  • AUGUSTINA, Sarah;WAHYUDI, Imam;DARMAWAN, I Wayan;MALIK, Jamaludin;BASRI, Efrida;KOJIMA, Yoichi
    • Journal of the Korean Wood Science and Technology
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    • 제48권4호
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    • pp.458-471
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    • 2020
  • Effect of pre-treatment and compression ratio on specific gravity (SG) and dimensional stability improvement of three lesser-used wood species from natural forest area of North Kalimantan Province, Indonesia had been investigated. Hot soaking at 80℃ for 3 hours within 2 and 5% of boron solution was applied as pre-treatment, while compression ratio applied was 20 and 40% from the initial thickness. Densification was conducted using hot pressing machine at 30 kg/㎠ of pressure and 160℃ of temperature for 15 minutes. Specific gravity was measured gravimetrically, while dimensional stability was evaluated through thickness swelling and water absorption as the indicator. Results show that SG of densified wood was influenced by wood species and compression ratio, but not by pre-treatment applied; while dimensional stability was influenced by wood species, compression ratio, and pre-treatment. Specific gravity and water absorption of densified wood was improved significantly. Specific gravity increased 28.86-63.03%, while water absorption decreased 12.80-15.89%. Thickness swelling of 20% densified wood was lower than that of 40% densified wood.

Simulation of $H_2O/LiBr$ Triple Effect Absorption Systems with a Modified Reverse Flow

  • Jo, Young-Kyong;Kim, Jin-Kyeong;Kang, Yang-Tae
    • International Journal of Air-Conditioning and Refrigeration
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    • 제15권3호
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    • pp.114-121
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    • 2007
  • In this study, a modified reverse flow type, one of the triple effect absorption cycles, is studied for performance improvement. The cycle simulation is carried out by using EES(Engineering Equation Solver) program for the working fluid of $H_2O/LiBr$ solution. The split-ratios of solution flow rate, UA of each component, pumping mass flow rate of solution are considered as key parameters. The results show that the optimal SRH (split ratio of high side) and SRL (split ratio of low side) values are 0.596 and 0.521, respectively. Under these conditions, the COP is maximized to 2.1. The optimal pumping mass flow rate is selected as 3 kg/s and the corresponding UAEV A is 121 kW/K in the present system. The present simulation results are compared to the other literature results from Kaita's (2002) and Cho's (1998) triple effect absorption systems. The present system has a lower solution temperature and a higher COP than the Kaita's modified reverse flow, and it also gives a higher COP than the Cho's parallel flow by adjusting split ratios.

진단방사선 영역에서 증감지의 유효이용에 관한 연구 (A Study on the Effective Utilization of Intensifying Screens in the Region of Diagnostic Radiology)

  • 김영근;이경섭
    • 대한방사선기술학회지:방사선기술과학
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    • 제22권1호
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    • pp.43-47
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    • 1999
  • In order to obtain effective utilization of intensifying screens[$CaWO_4(W),\;Gd_2O_2S:Tb(Gd)$, BaFCl : Eu(Ba)] over the diagnostic radiology range, we calculated absorption coefficient (${\mu}$), absorption efficiency (${\eta}_{\alpha}$) and absorbed energy ratio(R) and analyzed effects of these properties on X-ray image, finally concluded as below. Regardless of presence of contrast media, absorption coefficient of Gd the highest and decreased with increase of thickness and kVp. Absorption efficiency related with absorbance of fluorescent materials showed the highest value for the Gd, and discontinuous points exhibited at around $80{\sim}90\;kVp$ and $90{\sim}100kVp$ for the Ba and the Gd, respectively. Furthermore, the absorbed energy ratio(R) correspond to contrast of reflection showed the largest value for the W in the absence of contrast media, and for the Gd in the case of the existence of it, and the ratio was decreased with increasing of incident energy. Owing to these properties, we assumed that it was more preferable to use rare earth type intensifying screen for the radiography using in the C.M.(I, Ba), while in the general radiography, $CaWO_4$ intensifying screen was applicable.

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차세대 반도체용 유-무기 나노 복합재료의 에폭시 수지변화에 따른 흡습특성 (Moisture Absorption Properties of Organic-Inorganic Nano Composites According to the Change of Epoxy Resins for Next Generation Semiconductor Packaging Materials)

  • 김환건;김동민
    • 반도체디스플레이기술학회지
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    • 제12권1호
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    • pp.23-28
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    • 2013
  • Epoxy resins are widely used in microelectronics packaging such as printed circuit board and encapsulating for semiconductor manufacturing. Water can diffuse into and through the epoxy matrix systems and moisture absorption at boarding interfaces of matrix resin systems can lead to a hydrolysis at the interfaces resulting in delamination of encapsulating materials. In the study, the changes of diffusion coefficient and moisture content ratio of epoxy resin systems with nano-sized fillers according to the change of liquid type epoxy resins were investigated. RE-304S, RE-310S, RE-810NM and HP-4032D as a epoxy resin, Kayahard AA as a hardener, and 1B2MI as a catalyst were used in these epoxy resin systems. After curing, moisture content ratios were measured with time under the 85 and 85% relative humidity condition using a thermo-hydrostat. The maximum moisture absorption ratio and diffusion coefficient of EMC decrease with the filler content. It can be seen that these decreases are due to the increase of filler surface area and the decrease of moisture through channel with the content of nano-sized filler.

초미세 발포 플라스틱의 유리전이온도를 변화시키는 가스 용해량의 영향 (The Effect of Gas Absorption Induced a Change of Glass Transition Temperature in Microcellular Foamed Plastics)

  • 황윤동;차성운
    • 대한기계학회논문집A
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    • 제25권5호
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    • pp.816-822
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    • 2001
  • The thermoforming process is widely used in the plastics industry to produce articles for the packaging, automotive, domestic construction and leisure industries. The microcellular foaming process appeared at M.I.T. in 1980s to save a quantity of polymer materials and increase their mechanical properties. The glass transition temperature of polymer materials is one of many important process variables in appling the microcellular foaming process to the conventional thermoforming process. The goal of this research is to evaluate the relation between gas absorption and glass transition temperature in batch process using microcellular foaming process. The weight gain ratio of polymer materials has a conception of gas absorption. Polymers such as acrylonitrile-butadiene-styrene(ABS), polystyrene(PS) have been used in this experiment. According to conventional Chows model and Cha-Yoon model, it was estimated with real experimental result to predict a change of glass transition temperature as a function of the weight gain ratio of polymer materials in batch process to gain microcellular foamed plastic products.