• 제목/요약/키워드: a-Si:H

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Development of Wastewater Treatment System by Energy-Saving Photocatalyst Using Combination of Solar Light, UV Lamp and $TiO_2$ (태양광/자외선/이산화티타늄($TiO_2$)을 이용한 에너지 절약형 광촉매 반응 처리시스템 개발)

  • 김현용;양원호
    • Journal of Environmental Health Sciences
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    • v.29 no.1
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    • pp.51-61
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    • 2003
  • Pollution purification using titanium dioxide (TiO$_2$) photocatalyst has attracted a great deal of attention with increasing number of relent environmental problems. Currently, the application of TiO$_2$ photocatalyst has been focused on purification and treatment of waste water. However. the use of conventional TiO$_2$ powder photocatalyst results in disadvantage of stirring during the reaction and of separation after the reaction. And the usage of artificial UV lamp has made the cost of photocatalyst treatment system high. Consequently, we herein studied the pilot-scale design to aid in optimization of the energy-saving process for more through development and reactor design by solar light/UV lamp/ TiO$_2$system. In this study, we manufactured the TiO$_2$sol by sol-gel method. According to analysis by XRD, SEM and TEM, characterization of TiO$_2$ sol were nano-size (5-6 nm) and anatase type. Inorganic binder (SiO$_2$) was added to TiO$_2$ lot to be coated for support strongly, and support of ceramic bead was used to lower separation rate that of glass bead The influences were studied of various experimental parameters such as TiO$_2$ quantity, pH, flow rate. additives, pollutants concentration, climate condition and reflection plate by means of reaction time of the main chararteristics of the obtained materials. In water treatment system, variable realtor as solar light/ or UV lamp according to climate condition such as sunny and cloudy days treated the phenol and E-coli(Escherichia coli) effectively.

The latest movement of PVD coating for industrial application (산업용 PVD코팅 기술 최근 동향)

  • Im, Sang-Won
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.33-55
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    • 2016
  • PVD(Physical Vapour Deposition)코팅은 70년대 미국의 Multi-arc이란 기업에 의해 질화물계나 탄화물계 피막 증착이 가능한 아크이온플레팅(Arc Ion Plating) 기술이 산업에 소개되어, 주로 내마모나 내구성을 요구하는 금형, 절삭공구, 산업용 부품 분야 등에 적용되면서 꾸준한 성장세를 거듭해 왔다. 최근 들어 PVD기술은 그 수요의 급증과 더불어 보다 진화된 형태의 코팅장치 및 코팅피막들이 산업에 소개 되고 있다. 먼저 절삭가공분야에는 new composition, nano composite, multi-element composition, multi-layer, SML(Self Modification Layer)등의 코팅피막들이 단독 또는 조합된 형태로 개발되어 철계 소재를 대상으로 고경도 소재의 고속가공, 저경도~중경도 소재의 중속~고속 광범위영역에서 동시 절삭을 가능케 하였고, 비철.비금속 소재 절삭용으로 종전의 가스방식의 DLC(a-C:H)코팅을 훨씬 능가하는 ta-C Plus(Ultra super DLC) 코팅이 개발되어 고 Si함량의 Al-Si계 합금, Cu-W계, 고 섬유 CFRP, CFRM 및 반소결 상태의 세라믹 소재들을 황삭에서 정삭까지 단일 공정으로 절삭이 가능한 고성능 공구들이 개발보급되고 있다. 금속 성형분야에는 고장력 강판을 냉간에서 성형 가능한 Lubricative multi-layer coating, 열간 또는 고온에서 성형이 가능한 functional multi layer과 이형성이 더한층 개선된 dimpled(or embossed) functional multi layer 코팅들이 개발되어 산업현장에 빠르게 확산되고 있다. PVD 코팅의 또 다른 주요 적용분야로 의료분야를 들 수 있는데, 이는 코팅의 대다수가 고경도의 생체친화적인 특성을 가진데 착안되었으며, 흔히 현대성 질환이라 일컫는 과민성 체질, 과체중 및 허약체질 환자의 증가와 각종 재해 및 사고의 증가 및 인간 수명 증가에 따른 인공적인 시술의 요구증가에 편승하여 이 분야의 시장 또한 가파르게 성장하고 있다. 또한 대량으로 양산 적용단계에 접어든 자동차 핵심부품들을 비롯해서 각종 산업용, 방산용 기계 부품에도 성능 향상, 내구성 향상, 환경친화성 등 다양한 목적으로 확대 적용되고 있는 사례들을 본 발표를 통해 간략하게나마 소개하고자 한다.

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A Study on the Geological Occurrence, the Mineralogical and Physico-Chemical Properties of the Yucheon Sericite Ore in Chungha Area, Kyungsangbuk-do (청하지역 유천 견운모의 산상 및 물성)

  • 이동진
    • Journal of the Mineralogical Society of Korea
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    • v.10 no.2
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    • pp.114-125
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    • 1997
  • The purpose of this study is to clarify the geological occurrence, mineralogical, physico-chemical and thermal properties of the sericite ore which located in Chungha area, Kyungsangbuk-do. The geology of this area are composed mainly of hornfels and some felsite porphyry. The sericitic ore is classified into sericite, sericite-quartz and quartz-sericite ore according to mineral assemblages. Mineral components in sericite ore are mainly sericite with minor quartz, apatite, sphene, zircon, ilmenite, bismuthinite, iron oxide and etc. Sericite-quartz ore are mainly composed of sericite and quartz. Accessary minerals are muscovite, epidote, zircon, sphene, iron oxide and etc. The chemical compositions of K2O, Al2O3, & Ignition loss in sericite and sericite-quartz ore increase than that of the host rock, while the composition of SiO2, Na2O & Fe2O3 decrease. Sericite and sericite-quartz ore are characterized by the specific gravity of 2.35 and 2.44, the pH of 4.36 cP and 2.36 cP respectively. The result of size analyses of sericite ore is 11.3% in grain volume concentration between 12.9 $\mu\textrm{m}$ and 11.1$\mu\textrm{m}$, and 32.3% between 9.6$\mu\textrm{m}$ and 12.9$\mu\textrm{m}$. The thermal expansivity of sericite and sericite-quartz ore show the similar pattern. The sericite ore shows the thermal expansivity of 0.31% at 50$0^{\circ}C$, 0.39~0.75% at 600~1,00$0^{\circ}C$ and 0.74% at 1,10$0^{\circ}C$. The sericite-quartz ore show the thermal expansivity of 0.29% at 50$0^{\circ}C$, 0.36~0.72% at 600~1,000% and 0.71% at 1,10$0^{\circ}C$.

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Effects of Ginkgo(Ginkgo biloba L.) Leaf Wastes during Drug Manufacturing Process as Potential Organic Resources on Paddy Rice Growth (제약폐기(製藥廢棄) 은행잎이 벼생육에 미치는 영향)

  • Seong, Ki-Seog;Kim, Bok-Jin;Kwon, Oh-Kyung;Choi, Du-Hoi
    • Korean Journal of Soil Science and Fertilizer
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    • v.30 no.4
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    • pp.341-344
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    • 1997
  • To check the possibility to use the pharmaceutical by product of ginkgo leaf for the improvement soil fertility, a pot experiment was conducted with paddy rice. There were three treatment; NPK alone, NPK+7000kg(air dry)/ha of ginkgo leaf waste and NPK+700 kg of water-washed ginkgo leaf waste (air dry)/ha. The result indicated that the application of ginkgo leaf waste severely retarded the growth of rice. Water washing did reduce the severity of retardation, but the water washed ginkgo leaf waste also retarded the growth of rice significantly. The result of this study suggested that ginkgo leaf waste may contain some growth inhibiting substance.

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Field Measurements for the Lattice Girder and the Shotcrete Lining (격자지보와 숏크리트 계측에 대한 현장실험 연구)

  • Kim, Hak-Joon;Jin, Soo-Hwan;Park, Si-Hyun
    • The Journal of Engineering Geology
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    • v.18 no.1
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    • pp.93-102
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    • 2008
  • The use of lattice girder is increased at the tunnel site in Korea because of the several advantages over the traditional H-steel rib. The lattice girder supports the ground with shotcretes, forming a combined support system. Therefore, stress measurements at the lattice girder are necessary to calculated the ground loads. However, field measurements at the lattice girder are rarely performed at the tunnel site. The proper way of stress measurements for the lattice girder is not fully established in Korea. The correction of stress measurements at the shotcretes is often disregarded even though the measured stresses include non-stress related strains. Results of the stress measurements obtained from the lattice girder and non-stress shotcretes are used to improve the credibility of the stress measurements at the primary lining.

Effect of Diallyl Trisulfide on Human Ovarian Cancer SKOV-3/DDP Cell Apoptosis

  • Wan, Hui-Fang;Yu, Le-Han;Wu, Jin-Lan;Tu, Shuo;Zhu, Wie-Feng;Zhang, Xia-Li;Wan, Fu-Sheng
    • Asian Pacific Journal of Cancer Prevention
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    • v.14 no.12
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    • pp.7197-7201
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    • 2013
  • Aim: To investigate the effects of diallyl trisulfide (DT) on apoptosis of cisplatin (DDP)-resistant human epithelial ovarian cancer SKOV-3 cells (SKOV-3/DDP), and the role of p53 upregulated modulator of apoptosis (PUMA). Methods: SKOV-3/DDP cells were randomly divided into control, DT, DPP and DPP+DT groups, which were treated with DT or combined DT and DDP. All cells were incubated for 48 h. and apoptosis rates were assessed by flow cytometry. mRNA and protein expression of PUMA, Bax and Bcl-2 was determined by RT-PCR and Western blot assays, respectively. Results: Compared with control group, the apoptosis rates of SKOV-3/DDP cells in DT groups were obviously increased, with dose-dependence (P < 0.05), the mRNA and protein expressions of PUMA, Bax also being up-regulated (P < 0.05), while those of Bcl-2 were down-regulated (P < 0.05). Compared with DT groups, the apoptosis rate in the DDP+DT group was significantly increased (P < 0.05). After knockdown of PUMA with specific siRNA, the apoptosis rate of SKOV-3/DDP cells was obviously decreased (P < 0.05). Conclusion: DT can promote the apoptosis of SKOV-3/DDP cells with PUMA playing a critical role.

Experimental Study on Particle and Soluble Gas Removal Efficiency of Water-cyclone (Water-cyclone을 이용한 미세입자 및 수용성가스 제거효율에 대한 실험적 연구)

  • Kim, Chun-Lee;Kwon, Sung-An;Lee, Sang-Jun;Ko, Chang-Bog
    • Journal of Korean Society for Atmospheric Environment
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    • v.29 no.2
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    • pp.163-170
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    • 2013
  • The fine-particles, moisture and variety of hazardous gases are produced during electronic manufacture process. Most of the fine-particles are 0.1~10 ${\mu}m$ in size and the hazardous gases such as HF, $SiH_4$, CO, $NH_3$, etc. seriously affect environment, human's body and manufacturing process. To remove these characterized gases and fine-particles, Water-Cyclone designed and tested for removal efficiency on fine-particles and $NH_3$ under -980Pa negative pressure condition. As a result, under 0.1~1.0 $m^3/min$ flow condition, the efficiency on 5 ${\mu}m$ particles was 80~96%, 10 ${\mu}m$ particles was 86~96%, and 20 ${\mu}m$ particles was 91~99%. Besides, the removal efficiency on soluble gas $NH_3$ was 56.5% at 0.5m3/min and 79.1% at 1.0m3/min under 500 ppm flow concentration and 70.0% at 1.0 $m^3/min$ under 1,000 ppm flow concentration. Therefore, on particles, as the flow rate and particle size increased, the collection efficiency rate was increased. On soluble gas, as the flow rate increased, the removal efficiency was increased under the same concentration.

Enhancement of Lysine Production in Recombinant Corynebacterium glutamicum through Expression of Deinococcus radiodurans pprM and dr1558 Genes (Deinococcus radiodurans 유래 DR1558과 PprM에 의한 Corynebacterium glutamicum의 라이신 생산 향상 연구)

  • Kim, Su-mi;Lim, Sangyong;Park, Si Jae;Joo, Jeong Chan;Choi, Jong-il
    • Microbiology and Biotechnology Letters
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    • v.45 no.3
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    • pp.271-275
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    • 2017
  • The expression of Deinococcus radiodurans dr1558 and pprM genes was examined for enhanced lysine production in recombinant Corynebacterium glutamicum. These genes are known to confer high tolerance to pH and osmotic shock in Escherichia coli. D. radiodurans dr1558 and pprM genes were expressed in C. glutamicum by using 6 synthetic promoters of different strengths, to evaluate the effect of expression efficiency on lysine production. Recombinant C. glutamicum expressing DR1558 under the L26 and I64 promoters showed higher lysine production than that expressing DR1558 under other promoters. Similarly, recombinant C. glutamicum expressing PprM under same promoters (L26 and I64) showed a higher increase in lysine production compared to that expressing PprM under other promoters. In the absence of $CaCO_3$ in the medium, the expression of DR1558 or PprM also increased lysine concentration in C. glutamicum depending on the promoter used. Together, these results suggest that genes involved in radiation tolerance in D. radiodurans can be used to enhance production of amino acids and their derivatives.

Effects of Promoter on the Formation of Gas Hydrate from Blast Furnace Gas (철강공정 배기가스로부터 가스 하이드레이트 형성에 미치는 촉진제의 영향)

  • Kwak, Gye-Hoon;Sa, Jeong-Hoon;Kim, Si-Hwan;Lee, Bo Ram;Lee, Kun-Hong
    • Korean Chemical Engineering Research
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    • v.53 no.1
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    • pp.103-110
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    • 2015
  • In this work, the performance of various promoters was investigated used in $CO_2$ separation from the gases emitted from steel-making process using gas hydrate technology. The studied promoters are tetrahydrofuran (THF), propylene oxide and 1,4-dioxane, which are all expected to form a structure II hydrate, and the target gases include $CO_2/N_2$ mixed gases ($CO_2/N_2$ = 20/80 and 40/60) and Blast Furnace Gas (BFG). The phase equilibrium points were measured when each promoter was added with various concentrations. For fast acquisition of abundant data, the "continuous" Quartz crystal microbalance (QCM) method was employed. In addition, the crystal structure of each gas hydrate was analyzed by Powder X-ray diffraction (PXRD).

A Study on the Design and Fabrication of the Planar Light Waveguide type $2\times32$ Optical Coupler (평면도파로형 $2\times32$ 광커플러의 설계와 제작에 관한 연구)

  • 신기수;최영복;류근호;문동찬
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.24 no.12B
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    • pp.2335-2341
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    • 1999
  • The $2\times32$ coupler consists of Mach-Zehnder interferometer and Y branch coupler. For the designs of this coupler, three dimensional rectangular core waveguide decomposed to two-dimensional structure by the effective index method. To optimize the waveguide structure, the confinement factor was investigated with two-dimensional finite difference Beam Propagation Method. The $2\times32$ coupler fabricated by simulation with height between Mach-Zehnder arms, H=$43.6\mu\textrm{m}$(path difference $0.668\mu\textrm{m}$) was showed best characteristics. In the results of dry etching of core layer, the etching rate of core layer was above 2600${\AA}$/min, the etching ratio of SiO2 to Al mask was 30:1 and the uniformity of etching was $\pm$5%. The maximum insertion loss and the uniformity of $2\times32$ coupler were below 19.2dB, 2dB respectively.

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