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http://dx.doi.org/10.9713/kcer.2015.53.1.103

Effects of Promoter on the Formation of Gas Hydrate from Blast Furnace Gas  

Kwak, Gye-Hoon (Department of Chemical Engineering, Pohang University of Science & Technology)
Sa, Jeong-Hoon (Department of Chemical Engineering, Pohang University of Science & Technology)
Kim, Si-Hwan (CO2 Project Team, Research Institute of Industrial Science & Technology)
Lee, Bo Ram (Chemical and Biological Engineering Department, Colorado School of Mines)
Lee, Kun-Hong (Department of Chemical Engineering, Pohang University of Science & Technology)
Publication Information
Korean Chemical Engineering Research / v.53, no.1, 2015 , pp. 103-110 More about this Journal
Abstract
In this work, the performance of various promoters was investigated used in $CO_2$ separation from the gases emitted from steel-making process using gas hydrate technology. The studied promoters are tetrahydrofuran (THF), propylene oxide and 1,4-dioxane, which are all expected to form a structure II hydrate, and the target gases include $CO_2/N_2$ mixed gases ($CO_2/N_2$ = 20/80 and 40/60) and Blast Furnace Gas (BFG). The phase equilibrium points were measured when each promoter was added with various concentrations. For fast acquisition of abundant data, the "continuous" Quartz crystal microbalance (QCM) method was employed. In addition, the crystal structure of each gas hydrate was analyzed by Powder X-ray diffraction (PXRD).
Keywords
Gas Hydrates; $CO_2$ Separation; Promotion Effect; Blast Furnace Gas (BFG);
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1 https://www.ipcc.ch/report/ar5/wg1.
2 Association, W. S., "World Steel in Figures 2008. Brussels: World steel association," (2008).
3 http://www.gir.go.kr/og/hm/ic/g/OGHMICG010M.do?year=2012&headerValue=04&leftValue=02.
4 http://www.ieagreen.org.uk/sr2p.htm.
5 Kang, S.-P. and Lee, H., "Recovery of $CO_2$ from Flue Gas Using Gas Hydrate: Thermodynamic Verification Through Phase Equi-Librium Measurements," Environ. Sci. Technol., 34, 4397(2000).   DOI
6 Lee, B. R., Ryu, J.-H., Han, K., Park, D.-H., Lee, K.-H. and Lee, I.-B., "Recent Research Trends on Separation of $CO_2$ Emitted From Steelmaking Process using Gas Hydrate Technology," Korean Chem. Eng. Res., 48, 232(2010).
7 Sloan Jr, E. D. and Koh, C., Clathrate Hydrates of Natural Gases, CRC press(2007).
8 Seo, Y.-T., Kang, S.-P. and Lee, H., "Experimental Determination and Thermodynamic Modeling of Methane and Nitrogen Hydrates in the Presence of THF, Propylene oxide, 1, 4-dioxane and Acetone," Fluid Phase Equilib., 189, 99(2001).   DOI
9 Saito, Y., Kawasaki, T., Kondo, T. and Hiraoka, R., "Methane Storage in Hydrate Phase with Water Soluble Guests," Proceeding of the Second International Conference on Gas Hydrate, Toulouse, France, pp. 459-465(1996).
10 Maekawa, T., "Equilibrium Conditions of Clathrate Hydrates Formed from Carbon Dioxide and Aqueous Acetone Solutions," Fluid Phase Equilib., 303, 76(2011).   DOI
11 Seo, Y., Kang, S.-P., Lee, S. and Lee, H., "Experimental Measurements of Hydrate Phase Equilibria for Carbon Dioxide in the Presence of THF, Propylene Oxide, and 1, 4-dioxane," J. Chem. Eng. Data, 53, 2833(2008).   DOI
12 Mohammadi, A. H., Martinez-Lopez, J. F. and Richon, D., "Determining Phase Diagrams of Tetrahydrofuran + Methane, Carbon Dioxide or Nitrogen Clathrate Hydrates Using an Artificial Neural Network Algorithm," Chem. Eng. Sci., 65, 6059(2010).   DOI   ScienceOn
13 Strobel, T. A., Koh, C. A. and Sloan, E. D., "Thermodynamic Predictions of Various Tetrahydrofuran and Hydrogen Clathrate Hydrates," Fluid Phase Equilib., 280, 61(2009).   DOI
14 Yoon, J.-H., "A Theoretical Prediction of Cage Occupancy and Heat of Dissociation of THF-$CH_4$ Hydrate," Korean J. Chem. Eng., 29, 1670(2012).   과학기술학회마을   DOI
15 Fan, S., Liang, D. and Guo, K., "HydrRAate Equilibrium Conditions for Cyclopentane and a Quaternary Cyclopentane-rich Mixture," J. Chem. Eng. Data, 46, 930(2001).   DOI
16 Trueba, A. T., Rovetto, L. J., Florusse, L. J., Kroon, M. C. and Peters, C. J., "Phase Equilibrium Measurements of Structure II Clathrate Hydrates of Hydrogen with Various Promoters," Fluid Phase Equilib., 307, 6(2011).   DOI
17 Zhang, J. and Lee, J. W., "Equilibrium of Hydrogen + Cyclopentane and Carbon Dioxide + Cyclopentane Binary Hydrates," J. Chem. Eng. Data, 54, 659(2008).
18 Lim, Y.-A., Babu, P., Kumar, R. and Linga, P., "Morphology of Carbon Dioxide-hydrogen-cyclopentane Hydrates with or Without Sodium Dodecyl Sulfate," Crystal Growth & Design 13, 2047(2013).   DOI
19 Zhang, J. and Lee, J. W., "Enhanced Kinetics of $CO_2$ Hydrate Formation Under Static Conditions," Ind. Eng. Chem. Res., 48, 5934(2008).
20 Mohammadi, A. H. and Richon, D., "Phase Equilibria of Clathrate Hydrates of Methyl Cyclopentane, Methyl Cyclohexane, Cyclopentane or Cyclohexane + Carbon Dioxide," Chem. Eng. Sci., 64, 5319(2009).   DOI
21 Shimada, W., Ebinuma, T., Oyama, H., Kamata, Y., Takeya, S., Uchida, T., Nagao, J. and Narita, H., "Separation of Gas Molecule Using Tetra-n-butyl Ammonium Bromide Semi-clathrate Hydrate Crystals," Jpn. J. Appl. Phys., 42, L129(2003).   DOI
22 Kamata, Y., Oyama, H., Shimada, W., Ebinuma, T., Takeya, S., Uchida, T., Nagao, J. and Narita, H., "Gas Separation Method Using Tetra-n-butyl Ammonium Bromide Semi-clathrate Hydrate," Jpn. J. Appl. Phys., 43, 362(2004).   DOI
23 Shin, K., Kim, Y., Strobel, T. A., Prasad, P., Sugahara, T., Lee, H., Sloan, E. D., Sum, A. K. and Koh, C. A., "Tetra-n-butylammonium Borohydride Semiclathrate: A Hybrid Material for Hydrogen Storage," J. Phys. Chem. A, 113, 6415(2009).
24 Acosta, H. Y., Bishnoi, P. R. and Clarke, M. A., "Experimental Measurements of the Thermodynamic Equilibrium Conditions of Tetra-n-butylammonium Bromide Semiclathrates Formed from Synthetic Landfill Gases," J. Chem. Eng. Data, 56, 69(2010).
25 Lee, S., Lee, Y., Park, S. and Seo, Y., "Phase Equilibria of Semiclathrate Hydrate for Nitrogen in the Presence of Tetra-n-Butylammonium Bromide and Fluoride," J. Chem. Eng. Data, 55, 5883 (2010).   DOI
26 Rodionova, T., Komarov, V., Villevald, G., Aladko, L., Karpova, T. and Manakov, A., "Calorimetric and Structural Studies of Tetrabutylammonium Chloride Ionic Clathrate Hydrates," J. Phys. Chem. B, 114, 11838(2010).   DOI
27 Chapoy, A., Gholinezhad, J. and Tohidi, B., "Experimental Clathrate Dissociations for the Hydrogen + Water and Hydrogen + Tetrabutylammonium Bromide + Water Systems," J. Chem. Eng. Data, 55, 5323(2010).   DOI
28 Li, G., Liu, D. and Xie, Y., "Study on Thermal Properties of TBAB-THF Hydrate Mixture for Cold Storage by Dsc," J. Therm. Anal. Calorim., 102, 819(2010).   DOI
29 Oshima, M., Shimada, W., Hashimoto, S., Tani, A. and Ohgaki, K., "Memory Effect on Semi-clathrate Hydrate Formation: A Case Study of Tetragonal Tetra-n-butyl Ammonium Bromide Hydrate," Chem. Eng. Sci., 65, 5442(2010).   DOI
30 Deschamps, J. and Dalmazzone, D., "Hydrogen Storage in Semiclathrate Hydrates of Tetrabutyl Ammonium Chloride and Tetrabutyl Phosphonium Bromide," J. Chem. Eng. Data, 55, 3395(2010).   DOI
31 Li, S., Fan, S., Wang, J., Lang, X. and Wang, Y., "Semiclathrate Hydrate Phase Equilibria for $CO_2$ in the Presence of Tetra-n-Butyl Ammonium Halide (bromide, chloride, or fluoride)," J. Chem. Eng. Data, 55, 3212(2010).   DOI
32 Sun, Z.-G. and Sun, L., "Equilibrium Conditions of Semi-clathrate Hydrate Dissociation for Methane + Tetra-n-butyl Ammonium Bromide," J. Chem. Eng. Data, 55, 3538(2010).   DOI
33 Li, X.-S., Xu, C.-G., Chen, Z.-Y. and Wu, H.-J., "Tetra-n-butyl Ammonium Bromide Semi-clathrate Hydrate Process for Post-combustion Capture of Carbon Dioxide in the Presence of Dodecyl Trimethyl Ammonium Chloride," Energy, 35, 3902(2010).   DOI   ScienceOn
34 Deschamps, J. and Dalmazzone, D., "Dissociation Enthalpies and Phase Equilibrium for TBAB Semi-clathrate Hydrates of $N_2$, $CO_2$, $N_2$ + $CO_2$ and $CH_4$ + $CO_2$," J. Therm. Anal. Calorim., 98, 113(2009).   DOI
35 Li, X.-S., Xia, Z.-M., Chen, Z.-Y., Yan, K.-F., Li, G. and Wu, H.- J., "Equilibrium Hydrate Formation Conditions for the Mixtures of $CO_2$ + $H_2$ + Tetrabutyl Ammonium Bromide," J. Chem. Eng. Data, 55, 2180(2009).
36 Mayoufi, N., Dalmazzone, D., Furst, W., Delahaye, A. and Fournaison, L., "$CO_2$ Enclathration in Hydrates of Peralkyl-(ammonium/ phosphonium) Salts: Stability Conditions and Dissociation Enthalpies," J. Chem. Eng. Data, 55, 1271(2009).
37 Makino, T., Yamamoto, T., Nagata, K., Sakamoto, H., Hashimoto, S., Sugahara, T. and Ohgaki, K., "Thermodynamic Stabilities of Tetra-n-butyl Ammonium Chloride + $H_2$, $N_2$, $CH_4$, $CO_2$, or $C_2H_6$ Semiclathrate Hydrate Systems," J. Chem. Eng. Data, 55, 839 (2009).
38 Fan, S., Li, S., Wang, J., Lang, X. and Wang, Y., "Efficient Capture of $CO_2$ from Simulated Flue Gas by Formation of TBAB or TBAF Semiclathrate Hydrates," Energy Fuels, 23, 4202(2009).   DOI
39 Lee, B. R., Sa, J.-H., Park, D.-H., Cho, S., Lee, J., Kim, H.-J., Oh, E., Jeon, S., Lee, J. D. and Lee, K.-H., "Continuous" Method for the Fast Screening of Thermodynamic Promoters of Gas Hydrates Using a Quartz Crystal Microbalance," Energy Fuels, 26, 767(2011).
40 Sa, J.-H., Kwak, G.-H., Lee, B. R., Park, D.-H., Han, K. and Lee, K.-H., "Hydrophobic Amino Acids as a New Class of Kinetic Inhibitors for Gas Hydrate Formation," Scientific Reports, 3 (2013).
41 Van Cleeff, A. and Diepen, G., "Gas Hydrates of Nitrogen and Oxygen Ii," Recueil des Travaux Chimiques des Pays-Bas 84, 1085(1965).
42 Seo, Y.-T. and Lee, H., "Structure and Guest Distribution of the Mixed Carbon Dioxide and Nitrogen Hydrates as Revealed by X-ray Diffraction and 13c Nmr Spectroscopy," J. Phys. Chem. B, 108, 530(2004).   DOI
43 Florusse, L. J., Peters, C. J., Schoonman, J., Hester, K. C., Koh, C. A., Dec, S. F., Marsh, K. N. and Sloan, E. D., "Stable Low-pressure Hydrogen Clusters Stored in a Binary Clathrate Hydrate," Science, 306, 469 (2004).   DOI
44 Alavi, S., Susilo, R. and Ripmeester, J. A., "Linking Microscopic Guest Properties to Macroscopic Observables in Clathrate Hydrates: Guest-host Hydrogen Bonding," J. Chem. Phys., 130, 174501(2009).   DOI
45 Adisasmito, S., Frank III, R. J. and Sloan Jr, E. D., "Hydrates of Carbon Dioxide and Methane Mixtures," J. Chem. Eng. Data, 36, 68(1991).   DOI