• 제목/요약/키워드: a-C/B:H film

검색결과 279건 처리시간 0.026초

초전도 $MgB_2$ 박막의 온도와 장기장의 변화에 따른 광학적 성질 (Temperature and magnetic field dependent optical properties of superconducting $MgB_2$ thin film)

  • 정종훈;이해자;김경완;김명훈;노태원;;강원남;정창욱;이성익
    • Progress in Superconductivity
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    • 제3권1호
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    • pp.31-35
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    • 2001
  • We investigated the temperature and magnetic field dependent optical properties of a$ MgB_2$ thin film in the far-infrared region. In the superconducting state, i.e. 5 K, we obtained the values of superconducting gap $2\Delta$ ~ 5.2 meV and $2\Delta$ $_{k}$ $B/T_{c}$ ~1.8. Although the value of$ 2\Delta$$B/T_{c}$ was nearly half of the BCS value, the $2\Delta$ seemed to follow the temperature dependence of the BCS formula. Under the magnetic field (H), the superconducting state became suppressed. Interestingly, we found that the normal state area fraction abruptly increased at low field but slowly increased at high field. It did not follow the H-dependences predicted for a s-wave superconductor (i.e. a linear dependence) nor for a s-wave one (i.e. $H^{1}$2/ dependence). We discussed the complex gap nature of $MgB_2$ in comparison with two gap and anisotropic s-wave scenarios.ios.

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복합동시증착 방법을 이용한 In-situ $MgB_2$ 박막제조 (The growth of in-situ $MgB_2$ thin film by ESSD method)

  • 송규정;김호섭;김태형;이영석;고락길;하홍수;하동우;오상수;문승현;박찬;유상임
    • 한국초전도ㆍ저온공학회논문지
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    • 제8권3호
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    • pp.18-22
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    • 2006
  • We obtained in-situ $MgB_2$ thin films in an one-step process using ESSD (Evaporation Sputtering Simultaneous Deposition) method. In our approach. the Ma evaporator is designed specially Mg and B are simultaneously evaporated and sputtered, respectively, in the specially designed ESSD chamber. The background pressure was less than $1{\times}10^{-6}$ Torr. The substrate temperature was kept at 623 K. The film properties were investigated by both electrical resistivity and PPMS. As a result, typical $T_c$ of films was 11 K.

$MgB_2$ Thin Films on SiC Buffer Layers with Enhanced Critical Current Density at High Magnetic Fields

  • Putri, W.B.K.;Tran, D.H.;Kang, B.;Lee, N.H.;Kang, W.N.
    • Progress in Superconductivity
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    • 제14권1호
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    • pp.30-33
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    • 2012
  • We have grown $MgB_2$ superconducting thin films on the SiC buffer layers by means of hybrid physical-chemical vapor deposition (HPCVD) technique. Prior to that, SiC was first deposited on $Al_2O_3$ substrates at various temperatures from room temperature to $600^{\circ}C$ by using the pulsed laser deposition (PLD) method in a vacuum atmosphere of ${\sim}10^{-6}$ Torr pressure. All samples showed a high transition temperature of ~40 K. The grain boundaries of $MgB_2$ samples with SiC layer are greater in amount, compare to that of the pure $MgB_2$ samples. $MgB_2$ with SiC buffer layer samples show interesting change in the critical current density ($J_c$) values. Generally, at both 5 K and 20 K measurements, at lower magnetic field, all $MgB_2$ films deposited on SiC buffer layers have low $J_c$ values, but when they reach higher magnetic fields of nearly 3.5 Tesla, $J_c$ values are enhanced. $MgB_2$ film with SiC grown at $600^{\circ}C$ has the highest $J_c$ enhancement at higher magnetic fields, while all SiC buffer layer samples exhibit higher $J_c$ values than that of the pure $MgB_2$ films. A change in the grain boundary morphologies of $MgB_2$ films due to SiC buffer layer seems to be responsible for $J_c$ enhancements at high magnetic fields.

Sol-Gel 법을 이용한 칼슘-알루미네이트계 전자화물 박막의 제조와 특성 (Fabrication and properties of Calcium-aluminate electride thin films using by sol-gel process)

  • 김경훈;박주석;채재홍;서원선;소성민;김태관;김형순;이병하
    • 한국결정성장학회지
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    • 제20권6호
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    • pp.262-266
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    • 2010
  • Sol-gel법을 적용하여 $12CaO{\cdot}7Al_2O_3$(C12A7) 전자화물 박막을 제조하기 위해 CaO-$Al_2O_3$ sol을 제조하여 dip 코팅법을 적용하여 quartz 기판에 박막을 형성하였으며 열처리를 통해 C12A7의 박막을 제조하였다. C12A7 상의 형성 $800^{\circ}C$에서 시작되었고 $1,200^{\circ}C$ 온도에서 1시간 열처리를 통해 치밀화된 박막을 제조할 수 있었다. 제조된 C12A7 박막은 부도체였지만 수소 환원 분위기 열처리를 통해 전기전도도를 나타내기 시작했으며 $1,200^{\circ}C$ 48시간 열처리 시 120 S/cm의 전기전도도를 나타내었다.

플라즈마 화학증착법으로 제조된 B-doped a-SiC:H 박막의 물성 (Characterization of B-doped a-SiC:H Thin Films Grown by Plasma-Enhanced Chemical Vapor Deposition)

  • 김현철;신혁재;이재신
    • 한국재료학회지
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    • 제9권10호
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    • pp.1006-1011
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    • 1999
  • $SiH_4$, $CH_4$, $B_2H_6$ 혼합기체를 이용하여 플라즈마 화학증착법으로 탄화실리콘 (a-SiC:H) 박막을 증착하였다. 증착중에 혼합기체중의$CH_4$농도 ($CH_4/CH_4+SiH_4$)를 변화시켜 얻은 박막의 물성을 SEM, XRD, Raman 분광법, FTIR, XPS, 광흡수도와 광전도도 분석을 통하여 살펴보았다. $SiH_4$기체만 이용하여 증착한 Si:H 박막은 비정질상태를 나타내었으나, $CH_4$가 첨가됨에 따라 실리콘 박막의 Si-$\textrm{H}_{n}$(n은 정수) 결합기가 Si-$\textrm{C}_{n}\textrm{H}_{m}$ (n,m은 정수) 형태의 결합기로 변화되었으며, 박막내 수소함량은 $CH_4$농도가 0~0.8의 범위에서 증가함에 따라 30~45% 범위에서 증가하였다. 반응기체중의 $CH_4$농도의 증가에 따라 박막 내의 탄소 농도가 증가함을 확인하였으며, 이에 따라 막의 전기비저항과 광학적밴드갭 역시 증가하였다.

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플라즈마 CVD 법을 이용한 대면적 균일한 비정질 탄소 막 증착 (Large-area Uniform Deposition of Amorphous Hydrogenated Carbon Films using a Plasma CVD Method)

  • 윤상민;양성채
    • 한국전기전자재료학회논문지
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    • 제22권5호
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    • pp.411-414
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    • 2009
  • It has been investigated for the film uniformity and deposition rate of a-C:H films on glass substrate and polymeric materials in the presence of the modulated crossed magnetic field. We used Plasma CVD, i.e, using a crossed electromagnetic field, for uniform depositing thin film. The optimum discharge condition has been discussed for the gas pressure, the magnetic flux density and the distance between substrate and electrodes, As a result, it is found that the optimum discharge conditions are $CH_4$ concentration $CH_4$=10 %, modulated magnetic flux density B=48 Gauss, pressure P=100 mTorr, discharge power supply voltage V=l kV under these experimental conditions. By using these experimental condition, it is possible to prepare the most uniform film extends over about 160 mm of the film width. In this study, we deposited a-C:H thin film on glass substrate, and have a plan that using this condition, study depositing a-C:H thin film on polymeric substrate in next studies.

Development of Antimicrobial Edible Film from Defatted Soybean Meal Fermented by Bacillus subtilis

  • KIM , HYUNG-WOOK;KIM, KYUNG-MI;KO, EUN-JUNG;LEE, SI-KYUNG;HA, SANG-DO;SONG, KYUNG-BIN;PARK, SANG-KYU;KWON, KI-SUNG;BAE, DONG-HO
    • Journal of Microbiology and Biotechnology
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    • 제14권6호
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    • pp.1303-1309
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    • 2004
  • In order to extend shelf-life of the packaged or coated foods, an antibacterial edible film was developed. Antimicrobial activities of 9 bacteriocin-like substance (BLS)­producing strains were evaluated after growing them on defatted soybean meal medium (DSMM). Bacillus subtilis was selected among those, because it showed the biggest inhibition zone against 6 problem bacteria in food. The antimicrobial edible film, containing $0.32\%$ of BLS, was produced from the fermented soybean meal with B. subtilis at the optimum condition of pH 7.0-7.5 and $33^{\circ}C$ for 33 h. The antimicrobial activity of the film was over $50\%$ of the maximum activity after film production with heat treatment at $90^{\circ}C$ and pH adjustment to 9. When the soy protein film with BLS was applied on the agar media containing E. coli, the growth inhibition was much higher than the ordinary soy protein film. These results indicate that the soy protein film with BLS from B. subtilis can be used as a new packaging material to extend the shelf-life of foods.

방전처리에 따른 Poly(ethylene terephthalate) 필름의 표면특성에 관한 연구 (A Study on the Surface Properties of Poly(ethylene terephthalate) films by Discharge Treatment)

  • 임경범;이백수;이상희;황명환;박구범;박종관;김영일;임헌찬;이덕출
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2000년도 하계학술대회 논문집 C
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    • pp.1587-1589
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    • 2000
  • In this paper the weight loss, surface potential decay, surface resistivity and dielectric constant are measured to investigate the surface properties, insulation characteristic changes of PET film according to the discharge treatment. As a result of the test, up to the 10[min] the surface potential decay and surface resistivity have increased. Also, from the result of dielectric constant has decreased. On the other hand, the insulation characteristic of PET film have decreased after 10[min] in the discharge treatment.

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고밀도 플라즈마 화학 증착 장치를 이용한 $TiB_2$ 박막 제조 (Deposition Of $TiB_2$ Films by High Density Plasma Assisted Chemical Vapor Deposition)

  • 이승훈;남경희;홍승찬;이정중
    • 한국표면공학회지
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    • 제38권2호
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    • pp.60-64
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    • 2005
  • The ICP-CVD (inductively coupled plasma chemical vapor deposition) process was applied to the deposition of $TiB_2$ films. For plasma generation, 13.56 MHz r.f. power was supplied to 2-turn Cu coil placed inside chamber. And the gas mixture of $TiCl_4,\;BCl_3,\;H_2$ and Ar was used for $TiB_2$ deposition. $TiB_2$ films with high hardness (<40 GPa) were obtained at extremely low deposition temperature $(250^{\circ}C)$, and the films hardness increased with ICP power and gas flow ratio of $TiCl_4/BCl_3$. The film structure was changed from (100) preferred orientation to random orientation with increasing RF power. It is supposed that the enhanced hardness of films was caused by a strong Ti-B chemical bonding of stoichiometric $TiB_2$ films and film densification induced by high density plasma.