• Bulletin of the Korean Chemical Society
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• 제23권8호
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• pp.1067-1072
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• 2002

A new polystyrene-divinylbenzene resin containing 2-(2-thiazolylazo)-5-dimethylamino-phenol (TAM) functional groups has been synthesized and its sorption behavior for nineteen metal ions, including Zr(Ⅳ),Hf(Ⅳ) and U(Ⅵ) has been investigated by batch and column methods. The chelating resin showed high sorption affinity for Zr(Ⅳ) at pH 1-5 and U(Ⅵ) at pH 4. Some parameters affecting the sorption of the metal ions have been detailed. The breakthrough and overall capacities were measured under optimized conditions. The overall capacities of Zr(Ⅳ), Th(Ⅳ) and U(Ⅵ), which showed higher than the other metal ions, were 0.90,0.84 and 0.80 mmol/g, respectively. The elution order of metal ions at pH 4 was evaluated as Zr(Ⅳ) > Th(Ⅳ) > U(Ⅵ) > Cu(Ⅱ) > Hf(Ⅳ) > W(Ⅵ) > Mo(Ⅵ) > In(Ⅲ) > Sn(Ⅳ) > Cr(Ⅲ) > V(Ⅴ) > Fe(Ⅲ). Quantitative recovery of most metal ions except Zr(Ⅳ) was achieved using 2M HNO3. Desorption and recovery of Zr(Ⅳ) was successfully performed with 2 M HClO4 and 2 M HCl.

• Bulletin of the Korean Chemical Society
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• 제7권5호
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• pp.334-337
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• 1986

The preparation of the metal-metal bonded complex $Cp_2ZrClFeCp(CO)_2$ has been achieved by the reaction of $Cp_2ZrCl_2$ and strong nucleophile $NaFeCp(CO)_2$. The more soluble metal-metal bonded complexes $Cp_2ZrRFeCp(CO)_2(R=CH_3,\;n-C_8H_{17}$) have also been prepared through the reaction of Cp$_{2}$ZrRCl and NaCpFe(CO)$_{2}$. The complexes were characterized by IR, Raman, $^{1}$H NMR and Mass spectra. The complete absorption (100-3800 cm$^{-1}$) spectra for the three metal-metal bonded molecules are reported and the bands of each vibration were assigned.

• 한국분말재료학회지
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• 제6권1호
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• pp.49-55
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• 1999

Al-Cr-Zr nanocomposite metal powders were prepared by mechnical alloying (MA) in order to develop aircraft structure materials with lighter weight and lower cost than the conventional Ti and Ni alloys. The morphological changes and microstrutural evolution of Al-6wt.%Cr-3wt.%Zr nanocomposite metal powders during MA were investigated by SEM, XRD and TEM. The approximately 50$\mu$m sized Al-Cr-Zr nanocomposite metal powders has been formed after 20 h of MA. The individual X-ray diffraction peaks of Al, Cr and Zr were broadened and peak intensitied were decreased as a function of MA time. The observed Al crystallite size by TEM was in the range of 20 nm, which is a simliar value calculated by Scherrer equation. The microhardness of Al-Cr-Zr nanocomposite metal powders increases alomost linearly with increase of the processing time, reaching a saturation hardness value of 127 kg/$mm^2$ after 20 h of processing. The intermetallic compound phase of $Al_3Zr_4$ in the matrix was identifed by XRD and TEM.

• 한국전기전자재료학회논문지
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• 제19권9호
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• pp.808-812
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• 2006

In this dissertation, Ru-Zr metal gate electrode deposited on two kinds of dielectric were formed for MOS capacitor. Sample co-sputtering method was used as a alloy deposition method. Various atomic composition was achieved when metal film was deposited by controlling sputtering power. To study the characteristics of metal gate electrode, C-V(capacitance-voltage) and I-V(current-voltage) measurements were performed. Work function and equivalent oxide thickness were extracted from C-V curves by using NCSU(North Carolina State University) quantum model. After the annealing at various temperature, thermal/chemical stability was verified by measuring the variation of effective oxide thickness and work function. This dissertation verified that Ru-Zr gate electrodes deposited on $SiO_{2}\;and\;ZrO_{2}$ have compatible work functions for NMOS at the specified atomic composition and this metal alloys are thermally stable. Ru-Zr metal gate electrode deposited on $SiO_{2}\;and\;ZrO_{2}$ exhibit low sheet resistance and this values were varied with temperature. Metal alloy deposited on two kinds of dielectric proposed in this dissertation will be used in company with high-k dielectric replacing polysilicon and will lead improvement of CMOS properties.

• 한국군사과학기술학회지
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• 제15권4호
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• pp.519-526
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• 2012

Recently fuel cell is considered to be a new technology that can substitute the ICE(Internal Combustion Engine) as well as overcome environmental issues. In military applications, fuel cell has an unique advantages, which are quietness, namely, stealth. The environmental requirement such as shock and vibration in military application, however, is very severe comparing to civilian demand. Especially, the safety concerning hydrogen storage is the most important problem. Among the candidate methods to store hydrogen, the metal hydride storage is promising method owing to the storage mechanism of chemical absorption of hydrogen to metal hydrides. In this study, the new composition of Ti-Zr type metal hydride(A composition) was suggested and investigated to increase the hydrogen storage capacity. For comparison, the hydrogen charge-discharge properties were investigated with the commercialized Ti-Zr type metal hydride(B composition) using PCT(Pressure-Composition-Temperature) measurement. Also two hydrogen storage cylinders were loaded with each metal hydride and their hydrogen charging and discharging characteristics were investigated. As a result, it was found that the new Ti-Zr type metal hydride has a slightly higher hydrogen storage capacity compared to commercial Ti-Zr type metal hydride.

• 한국분말재료학회지
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• 제7권1호
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• pp.19-26
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• 2000

Al-Cr-Zr metal powders were prepared by cryo-milling(-75$^{\circ}C$),ambi-milling(25$^{\circ}C$) and warm-milling(200$^{\circ}C$) to investige the effect of milling temperature. The morphogical changes and microstructural evolution of Al-6wt.%Cr-3wt.%Zr metal powder ball milling were investigated by SEM, OM and XRD. The cryo-milling at -75$^{\circ}C$ caused the more refinement of powder particle size than ambi-milling and warm-milling. The partic morpholgy of Al-Cr-Zr metal powders changed changes into spheroidal particles at 25$^{\circ}C$and spherical particles at 200$^{\circ}C$The spherical particles were formed by agglomertion and contiuous wrapping of the spheroidal particles. The calculated Al crystallite size in Al-Cr-Zr metal powders by the Scherer equation were refined rapidly for short milling time -75$^{\circ}C$compared with milling at 25$^{\circ}C$ and 200$^{\circ}C$.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제53권4호
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• pp.208-212
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• 2004

In this paper, the characteristics of co-sputtered Ru-Zr metal alloy as gate electrode of MOS capacitors have been investigated. The atomic compositions of alloy were varied by using the combinations of relative sputtering power of Ru and .Zr. C-V and I-Vcharacteristics of MOS capacitors were measured to find the effective oxide thickness and work function. The alloy made of about 50% of Ru and 50% of Zr exhibited an adequate work function for nMOS. C-V and I-V measurements after 600 and $700^{\circ}C$ rapid thermal annealing were performed to prove the thermal and chemical stability of the Ru-Zr alloy film. Negligible changes in the accumulated capacitance and work function before and after annealing were observed. Sheet resistance of Ru-Zr alloy was lower than that of poly-silicon. It can be concluded that the Ru-Zr alloy can be a possible substitute for the poly-silicon used as a gate of nMOS.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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• pp.197-197
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• 2008

There are fast growing demands for new dielectric materials for passive capacitors of RF-ICs and other wireless applications. One of the bulk microwave dielectric materials which have superior properties is $ZrTiO_4$ due to its large dielectric constant and high quality factor. Therefore, $ZrTiO_4$ is worth studying as a form of thin film to be applied for passive capacitors of integrated circuits. In this study, we fabricated metal-insulator-metal type capacitors with $ZrTiO_4$ dielectric thin film, and evaluated their capacitor properties.

• 한국재료학회지
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• 제12권8호
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• pp.617-623
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• 2002

In order to improve the hydrogen storage capacity and the activation properties of the hydrogen storage alloys, the rare-earth metal alloy series, $MmNi_{ 4.5}$$Mn_{0.5}$ $Zr_{x}$ (x=0, 0.025, 0.05, 0.1), are prepared by adding the excess Zr in $MmNi_{4.5}$ $Mn_{0.5}$ / alloy for the strong resistance to intrinsic degradation. The hydrogen storage alloys of rare-earth metal such as $LaNi_{5}$ , and $MmNi_{5}$X and $MmNi_{4.5}$ /$_Mn{0.5}$ alloys which substituted La by misch metal properties were characterized as well. The hydrogen storage alloys were produced by melting each metal mixture in arc melting furnace, and the as-cast alloys were heat-treated at $1100^{\circ}C$ for 10 hr. The major elements of misch metal(Mm) were La, Ce, Pr and Nd with some impurities less than 1wt.% determined by ICP-AES. X-ray diffraction indicated that the structure for these samples was a single phase of hexagonal with $CaCu^{5}$ type. As the Zr contents increases, the activation time and the plateau pressure decrease and sloping of the plateau pressure increase. Amount of the 2nd phases increases with increase in Zr contents in $MmNi_{ 4.5}$$Mn_{0.5}$ $Zr_{0.1}$ alloy, This phenomenon indicated that $ZrNi_3$ in this phase, which shows the maximum storage capacity and the strong resistance to intrinsic degradation, is considered as a proper alloy for hydrogen storage..

• Bulletin of the Korean Chemical Society
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• 제34권7호
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• pp.2073-2080
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• 2013

In this study the effects of adding alkaline-earth (IIA) metal oxides to NiZr-loaded Zeolite Y catalysts were investigated on hydrogen rich production by ethanol steam reforming (ESR). Four kinds of alkaline-earth metal (Mg, Ca, Sr, or Ba) oxides of 3.0% by weight were loaded between the $Ni_6Zr_4O_{14}$ main catalytic species and the microporous Zeolite Y support. The characterizations of these catalysts were examined by XRD, TEM, $H_2$-TPR, $NH_3$-TPD, and XPS. Catalytic performances during ESR were found to depend on the basicity of the added alkaline-earth metal oxides and $H_2$ production and ethanol conversion were maximized to 82% and 98% respectively in 27($Ni_6Zr_4O_{14}$)3MgO/70Zeolite Y catalyst at $600^{\circ}C$. Many carbon deposits and carbon nano fibers were seen on the surface of $30Ni_6Zr_4O_{14}$/70Zeolite Y catalyst but lesser amounts were observed on alkaline-earth metal oxide-loaded 27($Ni_6Zr_4O_{14}$)3MO/70Zeolite Y catalysts in TEM photos after ESR. This study demonstrates that hydrogen yields from ESR are closely related to the acidities of catalysts and that alkaline-earth metal oxides reduce the acidities of 27($Ni_6Zr_4O_{14}$)3MO/70Zeolite Y catalysts and promote hydrogen evolution by preventing progression to hydrocarbons.