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http://dx.doi.org/10.5012/bkcs.2002.23.8.1067

A Chelating Resin Containing 2-(2-Thiazolylazo)-5-dimethylaminophenol as the Functional Group: Synthesis and Sorption Behavior for Some Trace Metal Ions  

Lee, Won
Lee, Si-Eun
Kim, Mi-Kyoung
Lee, Chang-Heon
Kim, Young-Sang
Publication Information
Bulletin of the Korean Chemical Society / v.23, no.8, 2002 , pp. 1067-1072 More about this Journal
Abstract
A new polystyrene-divinylbenzene resin containing 2-(2-thiazolylazo)-5-dimethylamino-phenol (TAM) functional groups has been synthesized and its sorption behavior for nineteen metal ions, including Zr(Ⅳ),Hf(Ⅳ) and U(Ⅵ) has been investigated by batch and column methods. The chelating resin showed high sorption affinity for Zr(Ⅳ) at pH 1-5 and U(Ⅵ) at pH 4. Some parameters affecting the sorption of the metal ions have been detailed. The breakthrough and overall capacities were measured under optimized conditions. The overall capacities of Zr(Ⅳ), Th(Ⅳ) and U(Ⅵ), which showed higher than the other metal ions, were 0.90,0.84 and 0.80 mmol/g, respectively. The elution order of metal ions at pH 4 was evaluated as Zr(Ⅳ) > Th(Ⅳ) > U(Ⅵ) > Cu(Ⅱ) > Hf(Ⅳ) > W(Ⅵ) > Mo(Ⅵ) > In(Ⅲ) > Sn(Ⅳ) > Cr(Ⅲ) > V(Ⅴ) > Fe(Ⅲ). Quantitative recovery of most metal ions except Zr(Ⅳ) was achieved using 2M HNO3. Desorption and recovery of Zr(Ⅳ) was successfully performed with 2 M HClO4 and 2 M HCl.
Keywords
Chelating resin; 2-(2-Thiazolylazo)-5-dimethylaminophenol; Sorption behavior; Column method;
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1 Ying, L. L.; De, G. M.; Qiu, Z. Y. Talanta 1995, 42, 1.   DOI   ScienceOn
2 Chang, R. C.; Fritz, J. S. Talanta 1978, 25, 659.   DOI   ScienceOn
3 de Moraes, S.; Abrao, A. Anal. Chem. 1974, 46, 1812.   DOI
4 Lee, W.; Lee, S. E.; Lee, C. H.; Kim, Y. S.; Lee, Y. I. Microchem.J. 2001, 35, 195.
5 Nachod, F. C.; Wood, W. J. Am. Chem. Soc. 1944, 66, 1380.   DOI
6 Saxena, R.; Singh, A. K.; Sambi, S. S. Anal. Chim. Acta 1994,295, 199.   DOI   ScienceOn
7 Anderson, R. G.; Nickless, G. Analyst 1967, 92, 1093.
8 Nachod, F. C.; Wood, W. J. Am. Chem. Soc. 1945, 67, 629.   DOI
9 Degetto, S.; Faguin, M.; Moresco, A.; Baracco, L. Bull. Chem.Soc. Jpn. 1983, 56, 904.   DOI   ScienceOn
10 Eshwar, M. C.; Sharma, C. D. Microchem. J. 1987, 35, 27.   DOI
11 Lee, C. H.; Suh, M. Y.; Joe, K. S.; Eom, T. Y.; Lee, W. Anal. Chim.Acta 1997, 351, 57.   DOI   ScienceOn
12 Reichenberg, D. J. Am. Chem. Soc. 1953, 75, 589.   DOI
13 Irving, H.; Williams, R. Nature 1948, 162, 746.   DOI
14 Schmuckler, D. Talanta 1963, 10, 745.   DOI   ScienceOn
15 Lee, C. H.; Kim, J. S.; Suh, M. Y.; Lee, W. Anal. Chim. Acta 1997,339, 303.   DOI   ScienceOn
16 Yang, X. J.; Pin, C. Anal. Chem. 1999, 71, 1706.   DOI   ScienceOn
17 Turse, R.; Rieman, W. J. Phys. Chem. 1961, 65, 1821.   DOI
18 Boyd, G. E.; Adamson, A. W.; Myers, L. S. J. Am. Chem. Soc.1947, 69, 2836.   DOI
19 Salters, V. J. M. Anal. Chem. 1994, 66, 4186.   DOI   ScienceOn
20 Chwastowska, J.; Mozer, M. Talanta 1985, 32, 7.   DOI   ScienceOn
21 Carlberg, G. E.; Boren, H.; Grimvall, A.; Lundgren, B. V. J. ofChromatography 1987, 391, 169.   DOI   ScienceOn
22 Wada, H.; Nakagawa, G. Anal. Lett. 1968, 1, 687.
23 Svodova, L.; Jandera, P.; Churacek, J. Collet. Czech. Chem.Commun. 1991, 56, 317.   DOI
24 Rawat, J. P.; Thind, P. S. J. Phys. Chem. 1976, 80, 1384.   DOI