• Journal of Information Display
• /
• v.5 no.3
• /
• pp.25-29
• /
• 2004

Effects of additing various types of ceramic fillers to the BZB-based glass on the thermo-chemical stability, optical reflectance, and mechanical properties were investigated. The glass system demonstrated the feasibility to host various types of ceramic fillers to form micro-composites at the processing temperature suitable for PDP systems. The optical reflectance and mechanical strength of the filler-glass composites were improved as compared to the glass itself. These results demonstrate the feasibility of applying the Pb-free BZB-based glass system as a matrix for employing various types of crystalline ceramic fillers to be used as barrier rib materials in plasma display panels.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.26 no.1
• /
• pp.38-43
• /
• 2013

In this study we aims to examine the effects of $Co_3O_4$ and NiO doping on the defects and electrical properties in ZnO-$Bi_2O_3-Sb_2O_3$ (Sb/Bi=0.5) varistors. It seemed to form ${Zn_i}^{{\cdot}{\cdot}}$(0.20 eV) and ${V_o}^{\cdot}$(0.33 eV) as dominant defects in Co and Ni co-doped ZBS system, however only ${V_o}^{\cdot}$ appeared in Co- or Ni-doped ZBS. Even though the same defects it was different in capacitance (1.5~4.5 nF) and resistance ($0.3{\sim}9.5k{\Omega}$). The varistor characteristics were improved with Co and Co+Ni doping (non-linear coefficient, ${\alpha}$= 36 and 29, relatively) in ZBS. The various parameters ($N_d=1.43{\sim}2.33{\times}10^{17}cm^{-3}$, $N_t=1.40{\sim}2.28{\times}10^{12}cm^{-2}$, ${\Phi}b$=1.76~2.37 V, W= 98~118 nm) calculated from the C-V characteristics in our systems did not depend greatly on the type of dopant, which were in the range of a typical ZnO varistors. It should be derived a improved C-V equation carefully for more reliable parameters because the variation of the varistor capacitance as a function of the applied dc voltage is depend on the defect, frequency, and temperature.

• KIEE International Transactions on Electrophysics and Applications
• /
• v.12C no.4
• /
• pp.220-224
• /
• 2002

The electromagnetic properties and thermal behavior of Mn-Zn ferrite cores for the blocking filter of PLC application were investigated as the function of additives. The highest density and permeability were 4.98 g/㎤ and 8,221, respectively and were obtained to the specimen with composition of MnO 24 mol%, ZnO 25 mol% and Fe$_2$O$_3$51 mol%, added MoO$_3$ of 400 ppm, SiO$_2$ of 100 ppm, and CaO of 200 ppm. The uniform grains were organized, and the microstructures were compacted due to reduction of pores in the specimen. The permeability was increased up to 13,904 as the temperature of specimen increased to 110。C. However, it was decreased precipitously under 100 over 110。C. The exothermic behavior was observed in the frequency range from 1 kHz to 1 MHz, and the maximum temperature of specimen was 102。C at 1 MHz. In the consequence, the Mn-Zn ferrite core developed in this research will maintain the stable electromagnetic properties since the temperature of ferrite core rose to 93 。C in the range of 100 kHz to 450 kHz bandwidth qualified for PLC. The blocking filters were designed for single phase and three phases using the in-line and non-contact core. The best attenuation ratios of -46.46 dB and -73.9 dB were measured in the range of 100 kHz to 450 kHz bandwidth, respectively.

• Proceedings of the KIEE Conference
• /
• 2001.07c
• /
• pp.1460-1462
• /
• 2001

초고속 전력선 통신을 위한 고주파수 대역에서 안정적인 자기적 특성을 갖는 Ni-Zn ferrite를 개발하기 위해서 투자율은 낮지만 주파수 특성이 우수한 $Ni_{0.8}Zn_{0.2}Fe_2O_4$를 기본조성으로 입자를 성장시키는 $Bi_2O_3$를 0.7, 비저항을 증가 시키는 CaO를 0.3, 그리고 입자를 균일하게 하는 $V_2O_5$를 0.1 wt% 첨가하여 미세구조를 제어하고, 다시 고주파 특성을 향상시킬 것으로 기대되는 $Co_3O_4$를 0, 0.3, 0.5, 0.7 wt%로 변화시켜 자기적 특성을 조사하였다. $Co_3O_4$가 밀도 및 미세구조에는 영향을 미치지 않았으나 0.3, 0.5 wt% 첨가시 첨가하지 않은 조성보다 투자율은 감소하였으나 사용 한계 주파수로 여겨지는 공명주파수가 각각 19.905, 19.205 MHz로 크게 증가하였다. 그리고 전체 전력 손실도 $Co_3O_4$를 첨가했을 때 감소하였으나 첨가량에는 큰 변화가 없었다. 와전류 손실이 전체 전력손실에 지배적인 영향을 미치고 있다.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.15 no.2
• /
• pp.1204-1210
• /
• 2014

New control methods are proposed for indoor air quality by removing fine airborne dust-particles. As suspended fine dust-particles contain inorganic dust as well as fine organic bacteria, studies for simultaneous control of these contaminants are required. In this study, photocatalytic disinfection of indoor suspended microorganisms such as E. coli and Bacillus subtilis is performed by three types of photocatalysts with UVA irradiation. The UVA irradiation strength was controlled to the minimum $3{\mu}W/cm^2$, and ZnO, $TiO_2$, and ZnO/Laponite ball were used as the catalysts. The results indicate that E. coli was removed over 80 % after about 2 hours of reaction with UVA and all three types of photocatalysts, whereas only with UVA, around 50 % E. coli removal was obtained. Among the catalysts, ZnO/Laponite composite ball was found to have similar sterilizing capacity to $TiO_2$. However, in case of B. subtilis, which has thick cell wall in its spore state, disinfection was not effective under the low UVA irradiation condition, even with the catalysts. Further studies need to figure out the optimal UVA irradiation ranges as well as photocatalysts doses to control airborne dust, to provide healthy clean air environment.

• Corrosion Science and Technology
• /
• v.11 no.1
• /
• pp.1-8
• /
• 2012

The development of martensitic grades which can be processed in continuous galvanizing lines requires the reduction of the oxides formed on the steel during the hot dip process. This reduction mechanism was investigated in detail by means of High Resolution Transmission Electron Microscopy (HR-TEM) of cross-sectional samples. Annealing of a martensitic steel in a 10% $H_2+N_2$ atmosphere with the dew point of $-35^{\circ}C$ resulted in the formation of a thin $_{C-X}MnO.SiO_{2}$ (x>1) oxide film and amorphous $_{a-X}MnO.SiO_{2}$ oxide particles on the surface. During the hot dip galvanizing in Zn-0.13%Al, the thin $_{C-X}MnO.SiO_{2}$ (x>1) oxide film was reduced by the Al. The $_{a-X}MnO.SiO_{2}$ (x<0.9) and $a-SiO_{2}$ oxides however remained embedded in the Zn coating close to the steel/coating interface. No $Fe_{2}Al_{5-X}Zn_{X}$ inhibition layer formation was observed. During hot dip galvanizing in Zn-0.20%Al, the $_{C-X}MnO.SiO_{2}$ (x>1) oxide film was also reduced and the amorphous $_{a-X}MnO.SiO_{2}$ and $a-SiO_{2}$ particles were embedded in the $Fe_{2}Al_{5-X}Zn_{X}$ inhibition layer formed at the steel/coating interface during hot dipping. The results clearly show that Al in the liquid Zn bath can reduce the crystalline $_{C-X}MnO.SiO_{2}$ (x>1) oxides but not the amorphous $_{a-X}MnO.SiO_{2}$ (x<0.9) and $a-SiO_{2}$ oxides. These oxides remain embedded in the Zn layer or in the inhibition layer, making it possible to apply a Zn or Zn-alloy coating on martensitic steel by hot dipping. The hot dipping process was also found to deteriorate the mechanical properties, independently of the Zn bath composition.

• Korean Journal of Materials Research
• /
• v.13 no.6
• /
• pp.365-368
• /
• 2003

Small amounts of additives such as mol % 0.13 NiO and mol % 0.01 $CaCO_3$were added to Cu-Zn-Mg ferrites. Basic composition of the Cu-Zn-Mg ferrites was $Cu_{Cu}$X/$Fe_{0.054}$ /$Zn_{0.486}$$Mg_{0.407}$ $Fe_{1.946}$ $O_4$(group A) and $Cu_{0.263}$$Fe_{0.027}$ $Zn_{0.503}$ $Mg_{0.262}$ $Fe_{1.973}$ $O_4$(group B). Specimens were sintered at different temperatures (1010, 1030, $1050^{\circ}C$) for 2 hours in air followed by an air cooling. Then, effects of various composition and sintering temperatures on the microstructure and the magnetic properties such as inductions, coercive forces, and initial permeabilities of the Cu-Zn-Mg ferrites were investigated. The average grain size increased with the increase of sintering temperature. The magnetic properties obtained from the aforementioned Cu-Zn-Mg ferrite specimens were 1,724 gauss for the maximum induction, 1.0 oersted for the coercive force, and 802 for the initial permeability. These magnetic properties indicated that the specimens could be utilized as the core of IFT (intermediate frequency transformer) and antenna in the amplitude modulation.

• Korean Journal of Soil Science and Fertilizer
• /
• v.46 no.2
• /
• pp.87-91
• /
• 2013

The crystal structure of partially dehydrated fully $Zn^{2+}$-exchanged zeolite Y was determined by X-ray diffraction techniques in the cubic space group $Fd\bar{3}m$ at 294(1) K and refined to the final error indices $R_1/wR_2$ = 0.035/0.119 for $|Zn_{35.5}(H_2O)_{13}|[Si_{121}Al_{71}O_{384}]$-FAU. About 35.5 $Zn^{2+}$ ions per unit cell are found at six distinct positions; sites I, I', a second I', II', II, and a second II. In sodalite cavities, the 11 water molecules coordinate to Zn(I'b) and/or Zn(II') ions; each of two $H_2O$ bonds to a Zn(IIb) in supercages. Two different $Zn^{2+}$ positions near 6-oxygen ring are due to their Si-Al ordering in tetrahedral site by Si/Al ratio leading to the different kinds of 6-rings.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2002.11a
• /
• pp.95-98
• /
• 2002

전력선 통신 blocking filter용 자심 재료를 개발하기 위해서 MnO 24 mol%, ZnO 25 mol% and $Fe_{2}O_{3}$ 51 mol% 의 기본조성에 $MoO_{3}$, $SiO_{2}$, CaO를 첨가하여 $1350^{\circ}C$에서 대기압 상수 A를 7.8롤 고정하고 소결하여 미세구조를 제어하였으며 기본 조성에 $MoO_{3}$ 400 ppm, $SiO_{2}$ 100 ppm and CaO 200 ppm을 첨가한 경우 평균 입경 $25{\mu}m$ 의 균일한 결정립으로 구성된 미세구조를 얻었고 기공의 감소에 의한 치밀화로 $4.98g/cm^{2}$의 고밀도화가 이루어 졌다. 또한 소결체의 균일한 미세구조와 고밀도화로 인해서 8221(${25^{\circ}C}$, 1 KHz) 의 가장 높은 투자율 특성을 나타냈다. 시편의 온도가 증가함에 따라 투자율이 증가되어 ${110^{\circ}C}$에서 13904의 거대 투자융이 측정되었고, 코일의 인가주파수가 1 KHz에서 1 MHz까지 증가됨에 따라 최고 ${102^{\circ}C}$까지 시편 온도가 상승하였다. 가장 높은 투자율 특성을 나타낸 ferrite 코어를 사용하여 단상 및 3상용 블로킹 필터의 감쇄율을 측정한 결과 현재 국내의 전력선 통신용 주파수 대역으로 규정되어 있는 10 KHz ~ 450 KHz 대역에서 각각 -46.46 dB와 -73.9 dB의 최고 값을 얻었다.

• Journal of the Korean Vacuum Society
• /
• v.16 no.6
• /
• pp.453-457
• /
• 2007

Zinc oxide (ZnO) and Ga doped zinc oxide (GZO) with different thickness in range of 10nm to 100nm are prepared on glass substrate by RF magnetron sputtering at room temperature. The structural and optical properties of the thin films is evaluated. The structural properties of ZnO and GZO are investigated by Tunneling Electron Microscopy (TEM) and scanning electron microscopy (SEM). Optical properties are also investigated by UV-VIS-NIR spectrophotometer (200$\sim$1400nm). The much larger grain size of ZnO compared to GZO decreased the light scattering at the grain boundary and improved the transmittance. The transmittance of ZnO is higher than that of GZO through all of the ranges of wavelengths. In case of over 50nm, we found that the transmittance of ZnO is 20% higher than that of GZO.