• Title/Summary/Keyword: Zn sheet

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Optimization of GZO/Ag/GZO Multilayer Electrodes Obtained by Pulsed Laser Deposition at Room Temperature

  • Cheon, Eunyoung;Lee, Kyung-Ju;Song, Sang Woo;Kim, Hwan Sun;Cho, Dae Hee;Jang, Ji Hun;Moon, Byung Moo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.336.2-336.2
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    • 2014
  • Indium Tin Oxide (ITO) thin films are used as the Transparent Conducting Oxide (TCO), such as flat panel display, transparent electrodes, solar cell, touch screen, and various optical devices. ZnO has attracted attention as alternative materials to ITO film due to its resource availability, low cost, and good transmittance at the visible region. Recently, very thin film deposition is important. In order to minimize the damage caused by bending. However, ZnO thin film such as Ga-doped ZnO(GZO) has poor sheet resistance characteristics. To solve this problem, By adding the conductive metal on films can decrease the sheet resistance and increase the mobility of the films. In this study, We analyzed the electrical and optical characteristics of GZO/Ag/GZO (GAG) films by change in Ag and GZO thickness.

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Characterization of Al Doped ZnO Thin Films Prepared by RF Magnetron Sputtering Under Various Substrate Temperatures

  • Kim, Deok Kyu;Kim, Hong Bae
    • Applied Science and Convergence Technology
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    • v.23 no.5
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    • pp.279-283
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    • 2014
  • Al doped ZnO thin films have been deposited by a RF magnetron sputtering technique from a ZnO (2 wt.% $Al_2O_3$) target onto glass substrates heated at temperature ranging from RT to $400^{\circ}C$. X-ray diffraction analysis shows that the deposits have a preferential growth along the c-axis of a hexagonal structure. The full with at half maximum decreases from 0.45 to $0.43^{\circ}$ in the studied temperature range. The root main square surface roughness increases with substrate temperature from 1.89 to 2.67 nm. All films are transparent up to 80% in the visible wavelength range and the adsorption edge is red-shifted with substrate temperature from RT to $400^{\circ}C$. The sheet resistance increases from 92 ohm/sq to 419 ohm/sq when the deposition temperature increases from RT to $400^{\circ}C$. The increment of sheet resistance is caused by lowered carrier concentration resulting from an increase in surface roughness.

Effects of Al and Mg on the Microstructure and Hardness of the Coating Layer of Hot-dip Galvanized Steel Sheet (알루미늄과 마그네슘 첨가가 용융아연 도금강판 도금층의 미세조직과 경도에 미치는 영향)

  • Yoonje Sung;Donggyu Kim;Jungi Seo;Kyunghyun Han;Beomki Hong;Kangmin Kim;Seounguk Heo;Seonghyun Park;Jae-Taek Im;Seung Bae Son;Seok-Jae Lee;Jae-Gil Jung
    • Journal of the Korean Society for Heat Treatment
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    • v.36 no.4
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    • pp.198-205
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    • 2023
  • We investigated the effects of Al and Mg on the microstructure and hardness of the coating layer of galvanized steel sheets, by thermodynamic calculations, X-ray diffraction, scanning electron microscopy, and Vickers hardness tests of Zn-0.2Al, Zn-6Al-2Mg, and Zn-10Al-5Mg coating layers. Regardless of the alloy composition of the galvanizing bath, a Fe-Al layer was observed between the coating layer and steel sheet. The Zn-0.2Al coating layer consists of major h.c.p. Zn phase and minor f.c.c. Al phase. The fraction of f.c.c. Al phase (containing a significant amount of Zn) of the coating layer increases with increasing the chemical composition of Al of the galvanizing bath. The h.c.p. MgZn2 phase was formed in the Al/Mg-containing Zn-6Al-2Mg and Zn-10Al-5Mg coating layers, forming Zn-Al-MgZn2 eutectic microstructure. The primary MgZn2 phase was additionally formed in the Zn-10Al-5Mg coating layers containing high concentrations of Al and Mg. The Vickers hardness values of Zn-0.2Al, Zn-6Al-2Mg, and Zn-10Al-5Mg coating layers were 59.1 ± 1.2 HV, 161.2 ± 5.7 HV, and 215.5 ± 40.3 HV, respectively. The addition of Al and Mg increased the hardness of the coating layer by increasing the fraction of the Al phase (containing Zn) and MgZn2 intermetallic compound, which were harder than the Zn phase.

Transparent Conducting ZnO:$Ga_2O_3$ Thin Films Grown by r.f. Magnetron Sputtering

  • Lee, Yong-Eui;Yun, Sun-Jin
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.822-824
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    • 2002
  • Transparent conducting ZnO:$Ga_2O_3$ thin films were deposited on glass substrates using rf magnetron sputtering method. The ZnO:$Ga_2O_3$ thin films were highly c-axis oriented normal to the substrates and had smooth surface features. The sheet resistance of the films was 2.8-6.4 ${\Omega}/{\square}$ at the growth temperature ranging from 25 to 30$^{\circ}C$.

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Post Deposition Annealing Effect on the Structural, Electrical and Optical Properties of ZnO/Ag/ZnO Thin Films

  • Kim, Daeil
    • Journal of the Korean Society for Heat Treatment
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    • v.25 no.2
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    • pp.85-89
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    • 2012
  • Transparent conductive ZnO/Ag/ZnO (ZAZ) multilayer films were deposited by Radio frequency (RF) magnetron sputtering and direct current (DC) magnetron sputtering. The effects of post deposition vacuum annealing temperature on the structural, electrical and optical properties of the ZAZ multilayer films were investigated. The thickness of ZAZ films is kept constant at ZnO 50 nm/Ag 5nm/ZnO 45 nm, while the vacuum annealing temperatures were varied from 200 and $400^{\circ}C$, respectively. As-deposited ZAZ films exhibit a sheet resistance of $6.1{\Omega}/{\Box}$ and optical transmittance of 72.7%. By increasing annealing temperature to $200^{\circ}C$, the resistivity decreased to as low as $5.3{\Omega}/{\Box}$ and optical transmittance also increased to as high as 82.1%. Post-deposition annealing of ZAZ multilayer films lead to considerably lower electrical resistivity and higher optical transparency, simultaneously by increased crystallization of the films.

Effects of phosphate coating on some performance of painted Al alloy sheet (도장 알루미늄 합금판의 성능에 미치는 인산염피막의 영향)

  • 이규환;노병호
    • Journal of the Korean institute of surface engineering
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    • v.28 no.5
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    • pp.289-299
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    • 1995
  • The effects of phosphate coating have been studied on physical properties and corrosion resistance of painted aluminum alloy sheet for automobile body. The physical properties (surface roughness, paint adhesion, impact resistance and pencil hardness) and corrosion resistance(cyclic corrosion and filiform corrosion) were investigated. Phosphate coatings enhanced the physical properties of painted Al alloy sheet, especially paint adhesion after the 240hours water immersion test. Phosphate coating also markedly improved the resistance for cyclic corrosion and filiform corrosion of painted cold rolled steel and Zn-Ni plated steel sheet as well as painted Al alloy sheet. The corrosion resistance of painted Al sheets was varied with the concentration of free fluoride ion and metal additives like Ni and Mn in the phosphating bath. A maximum corrosion resistance was obtained at about 300ppm of fluoride ion and additives of Ni and Mn obviously increased the corrosion resistance of painted specimens.

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Quantitative Analysis of Zn-Fe Electroplated Steel Sheet by Glow Discharge Spectrometry (Glow Discharge 방출분광법에 의한 Zn-Fe 전기도금강판의 정량분석)

  • So, Jai-Chun;Chung, Sung-Wook;Lee, Do-Hyung
    • Analytical Science and Technology
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    • v.5 no.1
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    • pp.73-77
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    • 1992
  • The quantitative analysis experiment of Zn-Fe electroplated steel was carried out by means of glow discharge spectrometry. The experimental results of chemical composition and coating weight of the Zn-Fe layer were compared with those obtained by the wet chemical analysis method. It has been found that those results obtained by two different methods agreed well with each other.

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Electrical and optical properties of Ag/ZnO multilayer thin film by the FTS (FTS법으로 제작한 Ag/ZnO 박막의 전기적, 광학적 특성)

  • Rim, Y.S.;Kim, S.M.;Son, I.H.;Lee, W.J.;Choi, M.K.;Kim, K.H.
    • Journal of the Korean Vacuum Society
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    • v.17 no.2
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    • pp.102-108
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    • 2008
  • We have studied the properties of Ag/undoped ZnO (ZnO) multilayer thin films deposited on glass substrate by the facing targets sputtering method. In an attempt to find out the optimum conditions of the Ag thin film, which would be coated on the ZnO thin film, we investigated the changes of sheet resistance, transmittance and surface morphology as a function of deposition times and the substrate temperature. The electrical and optical characteristics of Ag/ZnO multilayers were evaluated by a four-point probe, a UV/VIS spectrometer with a spectral range of 390-770 nm, a X-ray Diffractometer (XRD), an atomic force microscope (AFM) and a Field Emission Scanning Electron Microscope (SEM), respectively. We were able to prepare the Ag/ZnO multilayer thin film with sheet resistance of 9.25 $\Omega/sq.$ and transmittance of over 80% at 550nm.