• 제목/요약/키워드: Zinc-Aluminum

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Copper, Zinc, and Aluminium Level in Scalp Hair Samples of Daegu and Kyungbuk Residents

  • Kim, Min-Jeong;Kim, Ki-Sok
    • Biomedical Science Letters
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    • v.16 no.4
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    • pp.323-330
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    • 2010
  • Although copper and zinc are essential metals for human health, excessive level of these metals is toxic. Besides, aluminum is known to induce various adverse health effects including neurological disorders. Therefore, monitoring the human body burden of these metals is important in preventing adverse health effects. In this study, we assessed the exposure to copper, zinc, and aluminum among an adult population residing in Daegu and Kyungbuk areas. Based on data from 171 participants, we found that the geometric mean copper, zinc, and aluminum concentrations in hair were $15.1\;{\mu}g/g$ [95% confidence interval (CI): 13.1~17.5], 76.9 (95% CI: 70.4~84.1), and $1.11\;{\mu}g/g$ (95% CI: 0.81~1.51), respectively. The copper concentrations in hair were significantly related to age, education, and residence area. In addition, zinc concentrations in hair were significantly related to age, whereas higher hair aluminum concentrations were related to alcohol drinking. Correlations between copper and zinc in hair had a significant positive correlation. Our findings suggest that the body burden of copper, zinc, and aluminum varies according to demographic factors, and hair could be used as a valuable biological medium for metal exposure.

A study on the economic analysis of the integrated aluminum truss (일체형 알루미늄 트러스의 경제성분석에 관한 연구)

  • Lee, Young-Lae;Hong, Seong-Wook;Kim, Shin;Mun, Je-Chul;Shin, Chan-Ho
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.05b
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    • pp.127-130
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    • 2011
  • This study is concerned with the integrated aluminum trusses on the economic analysis of the study, and aluminum truss beam zinc red lead of the economy when compared beam total amount of red lead zinc beam 54,000 won 52,000 won 58,000 won Aluminum beam Red lead to over beam 2,000 won, 6,000 won lower than that for zinc are believed to be beam. This material is aluminum and the other beam expensive than the material costs of aluminum and an easy construction method beam attribute part of the low cost of labor and overall cost compared to the red lead beam zinc were identified as having competitive prices.

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Effect of Aluminum on Nitrogen Solubility in Zinc Oxide: Density Functional Theory (산화 아연에서의 질소 용해도에 대한 알루미늄의 효과 : 밀도 범함수 이론)

  • Kim, Dae-Hee;Lee, Ga-Won;Kim, Yeong-Cheol
    • Korean Journal of Materials Research
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    • v.21 no.12
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    • pp.639-643
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    • 2011
  • Zinc oxide as an optoelectronic device material was studied to utilize its wide band gap of 3.37 eV and high exciton biding energy of 60 meV. Using anti-site nitrogen to generate p-type zinc oxide has shown a deep acceptor level and low solubility. To increase the nitrogen solubility in zinc oxide, group 13 elements (aluminum, gallium, and indium) was co-added to nitrogen. The effect of aluminum on nitrogen solubility in a $3{\times}3{\times}2$ zinc oxide super cell containing 72 atoms was investigated using density functional theory with hybrid functionals of Heyd, Scuseria, and Ernzerhof (HSE). Aluminum and nitrogen were substituted for zinc and oxygen sites in the super cell, respectively. The band gap of the undoped super cell was calculated to be 3.36 eV from the density of states, and was in good agreement with the experimentally obtained value. Formation energies of a nitrogen molecule and nitric oxide in the zinc oxide super cell in zinc-rich conditions were lower than those in oxygen-rich conditions. When the number of nitrogen molecules near the aluminum increased from one to four in the super cell, their formation energies decreased to approach the valence band maximum to some degree. However, the acceptor level of nitrogen in zinc oxide with the co-incorporation of aluminum was still deep.

Effects of Zinc and Aluminum Hot-dip Galvanized Sheet Steel on the Gill and Hepatopancreas of the Abalone Haliotis discus hannai (아연 및 알루미늄 용융도금 처리된 강판이 북방전복(Haliotis discus hannai)의 아가미와 간췌장에 미치는 영향)

  • Lee, Chi Hoon;Park, Jun Young;Lee, Young Don
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.50 no.4
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    • pp.388-395
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    • 2017
  • We investigated the toxicity of zinc and aluminum hot-dip galvanized sheet steel to abalone Haliotis discus hannai via changes in the gill and hepatopancreas using histological and transmission electron microscopy analysis. Experimental groups were composed of one control and four exposure conditions (direct or indirect exposure to zinc and aluminum hot-dip galvanized sheet steel). In the control group, aluminum exposure groups (direct and indirect), and indirect zinc exposure group, abalone mortality was not observed until the end of the experiment, and no histopathological changes were observed in the gill and hepatopancreas. However, the direct zinc exposure group exhibited 100% mortality. Ultrastructural analysis of the cytoplasm of ciliated and microvilli-bearing epithelial cells from gill filaments revealed electron-dense vesicles near the cell membrane and disruption of the nuclear membrane. We also observed swollen mitochondria and a loss of mitochondrial cristae. The hepatopancreas showed similar changes, and we detected highly electron-dense particles within the vesicles. These results suggest that abalone exposed directly to zinc hot-dip galvanized sheet steel experience acute toxicity, causing damage to cell organelles in the gill and hepatopancreas and, finally, inducing mortality.

Effects of Zn Coating and Heat Treatment on the Corrosion of Aluminum Heat Exchanger Tubes (아연 코팅과 열처리에 따른 알루미늄 열교환기 소재의 부식)

  • Cho, Soo Yeon;Kim, Jae Jung;Jang, Hee Jin
    • Corrosion Science and Technology
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    • v.18 no.1
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    • pp.24-32
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    • 2019
  • The effects of zinc coating and heat treatment on the corrosion resistance of aluminum alloys including A1100 and the modified A3003, used as heat exchanger tube were investigated in this study. The grain size of the heat-treated specimen is larger than that of the specimen without heat treatment, but the grain size did not significantly affect the corrosion behavior. The concentration of zinc was noted at 11.3 ~ 31.4 at.% for the as-received Zn-coated samples and reduced to 1.2 ~ 2.4 at.% after the heat treatment, as measured by the scanning electron microscopy (SEM) with an energy dispersive spectrometer (EDS) on the surface. The concentration of oxygen is 22 ~ 46 at.% for the zinc coated specimens while noted at 7.4 ~ 12.8 at.% for the specimens after the removal of the coating. The corrosion behavior depended largely on the concentrations of zinc, aluminum, and oxygen on the specimen surface, but not on the Mo content. The corrosion potential was high and the corrosion rate was low for a specimen with a low zinc content, a high aluminum content, and a high oxygen content.

Joining of Zinc Coated Steel and Aluminum Alloy for Car Body (자동차용 아연 도금 강판과 알루미늄 합금의 접합)

  • Lee, Woo-Ram;Lee, Jung-Hyun
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.20 no.2
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    • pp.145-150
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    • 2011
  • There is problem to reduce the car body weight for improving fuel consumption and $CO_2$ generation. As one of the solution, the multi material car body concept using aluminum alloys and high strength steels is proposed recently. Therefore, new welding processes by which these dissimilar material can be joined in high reliability and productivity are demanded. Laser spot welding was developed for joining of dissimilar metals. In the present work, Laser spot welding of zinc coated steel and aluminum alloy was investigated, and the process parameters were studied. Otherwise, the influences of process parameters on the weldability, the formation of intermetallic compound layer and the mechanical properties have been investigated. When intermetallic compound layer thickness was more than 1mm, specimen was failure in the interface.

Effect of Bismuth Addition on the Zinc Consumption in Hot-Dip Galvanizing (용융아연도금에서 비스머스 첨가에 의한 아연 수율향상에 관한 연구)

  • Kim, S.K.;Yoo, J.S.
    • Journal of the Korean institute of surface engineering
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    • v.36 no.1
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    • pp.42-47
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    • 2003
  • Hot-dip galvanizing process is used widely in industry to achieve corrosion resistant coatings. Poor drainage during this process often leads to problems such as icicle formation and bridging In this work, mild steel specimens were hot-dip galvanized. Influence of the addition of bismuth, aluminum and both (bismuth and aluminum) to the zinc bath on the zinc drainage were determined. Bismuth additions improved the drainage significantly. Zinc bath containing 0.1 wt.% Bi and 0.025∼0.05 wt.% Al showed uniformity of coatings. Industrial trials with this bath composition showed reduction in zinc consumption, reduction of ash and dross, and good luster of workpiece.

Effects of Iron, Silicon and Zinc Contained in Molten Aluminum on Aluminizing of Cast Iron (주철 소지상에 용융알루미늄 도금시 철 규소 및 아연의 영향)

  • Choi, Chong-Sool;Moon, Sung-Wuck
    • Journal of the Korean institute of surface engineering
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    • v.20 no.4
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    • pp.144-153
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    • 1987
  • In the case of dipping the Ni-Resist cast iron into molten aluminum with iron content, the thickness of intermetallic compound was remarkably increased with increasing iron content. The thickness was shown by following equation in the range of 1-3% iron content; $x=22.5t^{1/2}+4.47{\cdot}t{\cdot}(Fe%)$. where, x is thickness(${\mu}m$), t the time (minute), Fe% the iron w/o. When the Ni-Resist cast iron was dipped into the molten aluminum containing zinc content, the intermetallic compound thickness was also increased with increasing zinc contents. And thickness was represented by the following equation in the range of 2-10% zinc content; $x=3.46t^{1/2}+0.27{\cdot}t{\cdot}(Zn%)$. However, in the case of dipping the Ni-resist cast iron into molten aluminum with silicon content, the thickness of intermetallic compound was decreased with increasing silicon content, as shown in the following equation; $x=7.17t^{1/2}-0.15{\cdot}t{\cdot}(Si%)$. The intermetallic compound formed onto Ni-Resist cast iron was identified to be $FeAl_3\;and\;Fe_3Al$. As the result of hardness measurement, the peak hardness appeared in the intermetallic compound at near interface of the cast iron and the compound.

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Influence of Surface Texturing on the Electrical and Optical Properties of Aluminum Doped Zinc Oxide Thin Films

  • Lee, Jaeh-Yeong;Shim, Joong-Pyo;Jung, Hak-Kee
    • Journal of information and communication convergence engineering
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    • v.9 no.4
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    • pp.461-465
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    • 2011
  • An aluminum doped zinc oxide (AZO) film for front contacts of thin film solar cells, in this work, were deposited by r.f. magnetron sputtering, and then etched in diluted hydrochloric acid solution for different times. Effects of surface texturing on the electro-optical properties of AZO films were investigated. Also, to clarify the light trapping of textured AZO film, amorphous silicon thin film solar cells were fabricated on the textured AZO/glass substrate and the performance of solar cells were studied. After texturing, the spectral haze at the visible range of 400 ~750 nm increased substantially with the etching time, without a change in the resistivity. The conversion efficiency of amorphous Si solar cells with textured AZO film as a front electrode was improved by the increase of short-circuit current density ($J_{sc}$), compared to cell with flat AZO films.

Synthesis and Characterization of Zinc Phosphate Cement Powder and Cement-forming Liquid

  • Park, Choon-Keun
    • The Korean Journal of Ceramics
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    • v.3 no.4
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    • pp.269-273
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    • 1997
  • Chemical composition of cement powder influences the setting time and early compressive strength development. The setting time increases as the amounts of zinc oxide and magnesium oxide are increased. For one day compressive strength development, a cement powder with a composition 90% ZnO, 8% MgO and 2% silica resulted in the highest strength (greater than 1, 090 kg/$\textrm{cm}^2$). Cement-forming liquids also need to be buffered, with both aluminum and zinc ions, for a good consistency and a higher strength of the zinc phosphate cement. These liquids control the setting reactions.

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