• 한국산학기술학회논문지
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• 제14권2호
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• pp.535-541
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• 2013

본 연구에서는 아연도금강관 용접에 용접 전류, 전압과 보호가스가 용접 비드 형상과 미세조직과 경도에 미치는 영향을 조사하였다. 전압, 전류과 보호가스 종류 및 조성의 변화가 용접 비드의 높이와 너비, 용입깊이에 영향을 미침을 확인하였다. 비드높이에는 보호가스 Ar 가스, 용입에는 $CO_2$ 가스, 그리고 비드너비에는 Ar+$O_2$ 가스가 가장 큰 영향을 미쳤다. 용접부의 경도에서는 Ar+10% $O_2$ 와 Ar+20% $CO_2$ 가스 사용 시 결정립계 페라이트와 다각형 페라이트가 생성되어 낮았으며, Ar+2% $O_2$ 가스를 사용했을 때는 아시큘러 페라이트와 베이나이트적 페라이트와 사이드플레이트 페라이트가 생성되어 경도가 높았다.

• 한국자기학회지
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• 제9권5호
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• pp.234-238
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• 1999

각종 microwave용 통신기기 소자 및 고주파용 memory 소자로 사용하기 위해서 각형비가 크고 보자력이 작은 lithium ferrite를 개발하고 물리적인 특성을 조사하기 위하여 Li0.48-0.5xBi0.02Ni0.04ZnxFe2.46-0.5xO4의 조성식을 갖는 시편을 제조하였다. ZnO을 첨가하여 변화시킴에 따라 잔류자기(Bm)가 증가하고 보자력(Hc)이 낮아졌으나 각형비 R은 감소하였다. 105$0^{\circ}C$에서 소결한 시편의 경우 R=0.82, Hc=1.8Oe로 나타났고 110$0^{\circ}C$에서 소결한 시편의 경우 R=0.75 및 Hc=1.70Oe인 값을 얻었다. Tc는 463$^{\circ}C$로 측정되었고 주변온도 변화에 대한 Br값의 변화가 매우 안정된 0.09~0.11 값으로 나타났다.

• Journal of Magnetics
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• 제21권3호
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• pp.308-314
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• 2016

Cobalt-, zinc-, and nickel-zinc-substituted nano-size manganese ferrite powders, $MnFe_2O_4$, $Mn_{0.8}Co_{0.2}Fe_2O_4$, $Mn_{0.8}Zn_{0.2}Fe_2O_4$ and $Mn_{0.8}Ni_{0.1}Zn_{0.1}Fe_2O_4$, were fabricated using a sol-gel method, and their crystallographic and magnetic properties were subsequently studied. The $MnFe_2O_4$ ferrite powder annealed at temperatures above 523 K exhibited a spinel structure, and the particle size increased as the annealing temperature increased. All ferrites annealed at 773 K showed a single spinel structure, and the lattice constants and particle size decreased with the substitution of Co, Zn, and Ni-Zn. The $M{\ddot{o}}ssbauer$ spectrum of the $MnFe_2O_4$ ferrite powder annealed at 523 K only showed a doublet due to its superparamagnetic phase, and the $M{\ddot{o}}ssbauer$ spectra of the $MnFe_2O_4$, $Mn_{0.8}Co_{0.2}Fe_2O_4$, and $Mn_{0.8}Zn_{0.2}Fe_2O_4$ ferrite powders annealed at 773 K could be fitted as the superposition of two Zeeman sextets due to the tetrahedral and octahedral sites of the $Fe^{3+}$ ions. However, the $M{\ddot{o}}ssbauer$ spectrum of the $Mn_{0.8}Ni_{0.1}Zn_{0.1}Fe_2O_4$ ferrite powder annealed at 773 K consisted of two Zeeman sextets and one quadrupole doublet due to its ferrimagnetic and paramagnetic behavior. The area ratio of the $M{\ddot{o}}ssbauer$ spectra could be used to determine the cation distribution equation, and we also explained the variation in the $M{\ddot{o}}ssbauer$ parameters by using this cation distribution equation, the superexchange interaction and the particle size. Relative to pure $MnFe_2O_4$, the saturation magnetizations and coercivities were larger in $Mn_{0.8}Co_{0.2}Fe_2O_4$ and smaller in $Mn_{0.8}Zn_{0.2}Fe_2O_4$, and $Mn_{0.8}Ni_{0.1}Zn_{0.1}Fe_2O_4$. These variations could be explained using the site distribution equations, particle sizes and magnetic moments of the substituted ions.

• 한국표면공학회지
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• 제50권3호
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• pp.212-218
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• 2017

$Mg_xNi_yZn_{1-x-y}Fe_2O_4$ ferrite powders were prepared by self-propagating high temperature synthesis followed by classifying with an ultrasonic wet-magnetic separation unit to get high pure nano-sized particles. The $Mg_xNi_yZn_{1-x-y}Fe_2O_4$ ferrites were well formed by using several powders like iron, nickel oxide, zinc oxide and magnesium oxide at 0.1 MPa of oxygen pressure. The ultrasonic wet-magnetic separation of pre-mechanical milled ferrite powders resulted in producing the powders with average size of 800 nm. The addition of a surfactant during the wet-magnetic separation process improved productivity more than twice. The coercive force, maximum magnetization and residual magnetization of the $Mg_xNi_yZn_{1-x-y}Fe_2O_4$ nano-powders with 800 nm size were 3651 A/m, $53.92Am^2/kg$ and $4.0Am^2/kg$, respectively.

• Journal of Magnetics
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• 제20권3호
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• pp.246-251
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• 2015

This study was aimed to study the effect of Zn content on the hyperfine parameters and the structural variation of $Ni_{1-x}Zn_xFe_2O_4$ for x = 0, 0.2, 0.4, 0.6, and 0.8. To achieve this, a sol-gel route was used for the preparation of samples and the obtained ferrites were investigated by X-ray diffraction, scanning electron microscopy, and $M{\ddot{o}}ssbauer$ spectroscopy. The formation of spinel phase without any impurity peak was identified by X-ray diffraction of all the samples. Moreover, the estimated crystallite size by X-ray line broadening indicates a decrease with increasing Zn content. This result was in agreement with the scanning electron microscopy result, indicating the reduction in grain growth with further zinc substitution. The room-temperature $M{\ddot{o}}ssbauer$ spectra show that the hyperfine fields at both the A and B sites decreased with increasing Zn content; however, the rate of reduction is not the same for different sites. Moreover, the best fit parameter showed that the quadrupole splitting values of B site increased from the pure nickel ferrite to the sample with x = 0.8.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2016년도 추계학술대회 논문집
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• pp.201.2-201.2
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• 2016

$Mg_xNi_yZn_{1-x-y}Fe_2O_4$ ferrite powders were prepared by self-propagating high temperature synthesis followed by classified by ultrasonic wet-magnetic separation method to get nano-sized particles with high purity. The $Mg_xNi_yZn_{1-x-y}Fe_2O_4$ ferrites were well formed by using several powders like iron, nickel oxide, zinc oxide and magnesium oxide at 0.1 MPa of oxygen pressure. The ultrasonic wet-magnetic separation of pre-mechanical milled ferrite powders produced the powders with average size of $3.7-0.8{\mu}m$. The addition of a surfactant during the separation process improved productivity more than twice. The coercive force, maximum magnetization and residual magnetization of the $Mg_xNi_yZn_{1-x-y}Fe_2O_4$ nano-powders with 810 nm size were 45.89 Oe, 53.92 emu/gOe, 0.4 emu/Oe, respectively.

• 한국세라믹학회지
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• 제56권5호
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• pp.474-482
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• 2019

Chromium-doped zinc ferrite nanoparticles with the general formula Cr_yZnFe_2-yO₄ (y = 0, 0.025, 0.05, 0.075, and 0.1) were synthesized by a surfactant-assisted chemical co-precipitation route using metal nitrate salt precursors. The phase purity and structural parameters were determined by powder X-ray diffraction. The concentration of Cr³⁺ doped into ZnFe₂O₄ (ZF) noticeably affected the crystallite size, which was in the range of 22 nm to 36 nm, and all samples showed a single cubic spinel structure without any secondary phase or impurities. The lattice parameter, X-ray density, and skeletal density increased with an increase in the Cr-doping concentration; on the other hand, a decreasing trend was observed for the particle size and porosity. The influence of Cr³⁺ substitution on ZF magnetic properties were studied under an applied field of 15 kOe. The overall results revealed that the incorporation of a small amount of Cr dopant changed the structural, electrical, and magnetic properties of ZF.

• 한국세라믹학회지
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• 제46권1호
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• pp.74-80
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• 2009

Electrospinning process is the useful and unique method to produce nanofibers from metal precursor and polymer solution by controlled viscosity. In this study, the NiZn ferrite nanofibers were prepared by electrospinning with a aqueous metal salts/polymer solution that contained polyvinyl pyrrolidone and Fe (III) chloride, Ni (II) acetate tetrahydrate and zinc acetate dihydrate in N,N-dimethylformamide. The applied electric field and spurting rate for spinning conditions were 10 kV, 2 ml/h, respectively. The obtained fibers were treated at $250^{\circ}C$ for 1 h to remove the polymer. Finally, the NiZn ferrite fibers were calcined at $600^{\circ}C$ for 3 h and annealed at $900{\sim}1200^{\circ}C$ in air. By tuning the viscosity of batch solution before electrospinning, we were able to control the microstructure of NiZn ferrite fiber in the range of $150{\sim}500\;nm$ at 770 cP. The primary particle size in $600^{\circ}C$ calcined ferrite fiber was about 10 nm. The properties of those NiZn ferrite fibers were determined from X-ray diffraction analysis, electron microscopy, energy dispersive spectroscopy, Fourier transform infrared spectroscopy, thermal analysis, and magnetic measurement.

• 한국결정성장학회지
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• 제1권2호
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• pp.23-33
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• 1991

Mn-Zn Ferrite는 단결정을 성장하기 위하여 용융하는 동안 불균질 용융과 ZnO휘발의 고유특성을 갖는 재료이다. 그 결과로, 결정성장축을 따라 양이온의 분포가 불균일 하게 된고 또한 기존의 Bridgman법에서는 도가니내에서 용융대가 장시간 유지됨으로써 백금입자가 결정안으로 침입하게된다. 이들은 훼라이트의 자기적 성질을 저하시키는 성질을 갖고 있다. 그러나 새로운 성장법에서는 이러한 단점들을 극복하고 양질의 단결정을 얻기 위하여 결정성장 인자들의 관계를 고찰하였으며 그 인자들은 다음과 같다 : 도가니내의 melt 높이, melt의 표면장력과 밀도, 계면에서의 melt거동, 도가니와 고액계면의 형상, 원료공급속도, 결정성장속도. 아울러, 성장된 결정의 조성을 분석하였을 때 초기조성과 비교하여 $\textrm{Fe}_2\textrm{O}_3$ 1.5 mol%, MnO, Zn 2.0 mol% 이내로 조성 변동은 각각 억제되었고 성장결정면 (110)에서 화확적인 etching 법을 이용하여 광학현미경을 통해 결정내부등을 관찰하였으며, 자기적 특성등을 측정하였다.

• 한국결정학회지
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• 제14권1호
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• pp.1-6
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• 2003

석유화학 공정 중 styrene monomer제조공정에서 발생되는 산화철 폐촉매는 산업 폐기물로서 전량 매립되고 있는데, 이를 출발원료로 사용하여 NiZn-페라이트를 합성하였고, 그 자기적 특성을 조사하였다. 출발 원료인 산화철 폐촉매는 산 처리와 CeO₂ 분리과정을 거쳤으며, 이렇게 정제된 산화철 폐촉매에 NiO및 ZnO를 혼합하여 900℃에서 하소하여 스핀넬형 페라이트를 합성하고 1325℃에서 5시간 소결하였다. Ni/sub x/Zn/sub 1-x/Fe₂O₄(x=0.36, 0.50, 0.66)과 (Ni/sub 0.5/Zn/sub 0.5/)/sub 1-y/Fe/sub 2+y/O₄(y =-0.02, 0, 0.02)의 조성에 대하여 초투자율을 측정하였고, S-parameter를 측정하여 반사 감쇄량을 계산하였다.