• 한국자기학회:학술대회 개요집
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• 한국자기학회 2003년도 하계학술연구발표회 및 한.일 공동심포지엄
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• pp.150-151
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• 2003

In the past years, a giant magnetoresistance (GMR) effect found in perovskite-like structured materials has attracted considerable attention among scientists and manufacturers, since, a practical point of view, the capacity of producing magnetic and sensing sensors. In a stream of this interest, further efforts to understand the underlying mechanism that leads to the GMR effect relative to the correlation between transport and magnetic properties, have been extensively devoted. In these cases, spin-glass-like behaviors are ascribed to the frustration of random competing exchange interactions, namely the ferromagnetic double-exchange interaction between Co$\^$3+/ (or Mn$\^$3+/) and Co$\^$4+/(or Mn$\^$4+/) and the antiferromagnetic one like spins. Noticeably, the distinction of spin-glass region from cluster-glass one, involved in the remarkable changes in transport and magnetic properties at a critical value of doping concentration, was observed. Magnetic anomalies in zero-field-cooled (ZFC) magnetization as well as ac magnetic susceptibility below Curie temperature T$\sub$c/ and the charge/orbital fluctuation were also realized. In this work, we present a study of magnetic properties of a deficient manganese perovskites system of La$\sub$0.6/Sr$\sub$x/MnTi$\sub$y/O$_3$, and particularly provide its new magnetic phase diagram.

• 한국초전도ㆍ저온공학회논문지
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• 제17권1호
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• pp.14-16
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• 2015

Due to the considerable development of the technology of second generation high-temperature superconductors and a significant improvement in their mechanical and transport properties in the last few years it is possible to use HTS tapes in the magnetic levitation systems. The advantages of tapes on a metal substrate as compared with bulk YBCO material primarily in the strength, and the possibility of optimizing the convenience of manufacturing elements of levitation systems. In the present report presents the results of the magnetic levitation force measurements between the stack of HTS tapes containing $n=2{\div}200$ of tapes $12mm{\times}12mm$ and NdFeB permanent magnet in the FC and ZFC regimes. It was found a non- linear dependence of the levitation force from the height of the array of stack in both modes: linear growth at small thickness gives way to flattening and constant at large number of tapes in the stack. Established that the levitation force of stacks comparable to that of bulk samples. The numerical calculations using finite element method showed that without the screening of the applied field the levitation force of the bulk superconductor and the layered superconductor stack with a critical current of tapes increased by the filling factor is exactly the same, and taking into account the screening force slightly different.

• Journal of Magnetics
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• 제11권1호
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• pp.16-19
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• 2006

$2-\mu{m}$ thick GaN epilayer was prepared, and 80 KeV $Co^{-}$ ions with a dose of $3X10^{16}\;cm^{-2}$ were implanted into GaN at $350^{\circ}C$. The implanted samples were post annealed at $700^{\circ}C$. We have investigated the magnetic and structural properties of Co ion-implanted GaN by various measurements. HRXRD results did not show any peaks associated with second phase formation and only the diffraction from the GaN layer and substrate structure were observed. SIMS profiles of Co implanted into GaN before and after annealing at $700^{\circ}C$ have shown a projected range of $\sim390\AA$ with 7.4% concentration and that there is little movement in Co. AFM measurement shows the form of surface craters for $700^{\circ}C$-annealed samples. The magnetization curve and temperature dependence of magnetization taken in zero-field-cooling (ZFC) and field-cooling (FC) conditions showed the features of superparamagnetic system in film. XPS measurement showed the metallic Co 2p core levels spectra for $700^{\circ}C$-annealed samples. From this, it could be explained that magnetic property of our films originated from Co magnetic clusters.

• 한국초전도ㆍ저온공학회논문지
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• 제5권3호
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• pp.6-10
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• 2003

Silver nano-powder was added to Ma $B_2$ to make (Ag)$_{(x)wt.%}$(Mg $B_2$)$_{(l00-x)wt.%}$ (A $g_{x}$-Mg $B_2$) (10 $\leq$ x $\leq$ 50) composite superconductors to investigate the effect of the Ag nano-powder on the vortex pinning. Pellets made out of the mixed powder were put inside stainless steel tubes, which were sintered at 85$0^{\circ}C$ in Ar atmosphere. No impurity phase was identified for as-rolled samples. However, both the Mg $B_2$ and the A $g_{x}$-Mg $B_2$ composite pellets, when sintered, contain small amount of Mg $B_4$ and MgAg impurity phases. From the magnetization study, it was found that the flux pinning was improved in the high magnetic field region (> 3 T) only when 10w/o Ag was added to Mg $B_2$. The "two step" structures in ZFC M(T) curve gradually increased as the amount of Ag added increased. Pinning centers can be created by adding a suitable amount of Ag nano-powder which is not too large to increase the decoupling between the Mg $B_2$ grains.crease the decoupling between the Mg $B_2$ grains.

• Journal of Magnetics
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• 제13권4호
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• pp.149-152
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• 2008

In this report, we present the results of a study on the effects of the particle size on the properties of the Prussian blue (PB) analog $Na_xMn_y[Fe(CN){_6}]$. A novel synthesis method of the $Na_xMn_y[Fe(CN){_6}]$ nano-particles using an organic solvent, formamide, is employed. The size of the PB particles is found to be 100-150 nm for the samples prepared in the formamide solvent, which is much smaller than that of the samples prepared using water only. The broadening of the X-ray diffraction peaks of the nano-sized PB samples is attributed to the lattice disorder and a dramatic reduction in the particle size. The compositions of the samples are confirmed by an energy-dispersive X-ray analysis (EDAX), and the result proves that the samples are actually $Na_xMn_y[Fe(CN){_6}]$ Prussian blue. The UV-vis spectra show a broad intervalence charge-transfer (CT) band in the visible region between 400 and 700 nm, and the absorption decreases abruptly in the green region for the nano-sized PB sample. A divergence between the field cooled (FC) and zero field cooled (ZFC) magnetization curves is observed for the nano-sized PB sample at 11 K, indicating that nanoparticles in the sample are single domain superparamagnets with a blocking temperature of 11 K. Our results reveal that the nano-sized PB samples show significantly different optical and magnetic properties than those of the bulk PB samples.

• 한국초전도ㆍ저온공학회논문지
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• 제17권1호
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• pp.21-24
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• 2015

New results of dependence of magnetic field, trapped by a stack of HTS tapes, on amount of tapes in a stack are reported. Commercial GdBCO tape 12 mm width and without Cu layer was used for the research. Tape was divided in square pieces $12{\times}12mm^2$ from which stacks were formed. Filling factor of the tape was about 1.4%. Measurements were carried out for stacks with height from 5 to 250 pieces and at wide temperature range from liquid helium to liquid nitrogen. Both FC (field cooling) and ZFC (zero field cooling) cooling methods were used in the research. These two methods show matching results with good accuracy. As a result dependences of trapped magnetic flux on amount of tapes for different temperatures were received. Research shows, that with increasing height of the stack trapped magnetic field value reach saturation at about 60 tapes in a stack for low temperatures. From 60 to 100 tapes increase of magnet flux is only 5%. Thus increase amount of tapes in a stack is not profitable. Also investigation of trapped magnet field relaxation was carried out. Relaxation speed decreases with increasing amount of elements. It means that the higher the stack is, the longer trapped flux will be held in cause of the same temperature.

• Journal of Magnetics
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• 제10권1호
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• pp.5-9
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• 2005

Nanoparticles $Ni_{0.9}Zn_{0.1}Fe_2O_4$ is fabricated by a sol-gel method. The magnetic and structural properties of powders were investigated with XRD, SEM, Mossbauer spectroscopy, and VSM. $Ni_{0.9}Zn_{0.1}Fe_2O_4$ powders annealed at $300{^{\circ}C}$ have a spinel structure and behaved superparamagnetically. The estimated size of $Ni_{0.9}Zn_{0.1}Fe_2O_4$ nanoparticle is about 10 nm. The hyperfine fields at 13 K for the A and B patterns are found to be 533 and 507 kOe, respectively. The ZFC curves are rounded at the blocking temperature ($T_B$)and show a paramagnetic-like behavior above $T_B$. $T_B$ of $Ni_{0.9}Zn_{0.1}Fe_2O_4$ nanoparticle is about 250 K. Nanoparticles $Ni_{0.9}Zn_{0.1}Fe_2O_4$ annealed at 400 and $500{^{\circ}C}$ have a typical spinel structure and is ferrimagnetic in nature. The isomer shifts indicate that the iron ions were ferric at the tetrahedral (A) and the octahedral (B). The saturation magnetization of nanoparticles $Ni_{0.9}Zn_{0.1}Fe_2O_4$ annealed at 400 and $500{^{\circ}C}$ are 40 and 43 emu/g, respectively. The magnetic anisotropy constant of $Ni_{0.9}Zn_{0.1}Fe_2O_4$ annealed at $300{^{\circ}C}$ were calculated to be 1.6 ${\times}$ $10^6$ ergs/$cm^3$.

• Journal of the Korean Physical Society
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• 제73권12호
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• pp.1863-1866
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• 2018

The sodium-iron phosphate maricite-$NaFe_{0.9}Mn_{0.1}PO_4$ was synthesized using the ball mill method. The crystal structure and magnetic properties of the prepared materials were studied using X-ray diffraction (XRD), vibrating sample magnetometer (VSM), and $M{\ddot{o}}ssbauer$ spectroscopy. Structural refinement of maricite-$NaFe_{0.9}Mn_{0.1}PO_4$ was analyzed using the FullProf program. From the XRD patterns, the crystal structure of maricite-$NaFe_{0.9}Mn_{0.1}PO_4$ was found to be orthorhombic with the space group Pmnb. The lattice parameters of maricite-$NaFe_{0.9}Mn_{0.1}PO_4$ are as follows: $a_0=6.866{\AA}$, $b_0=8.988{\AA}$, $c_0=5.047{\AA}$, and $V=311.544{\AA}^3$. Maricite-$NaFePO_4$ has an edge-sharing structure that consists of $FeO_6$ octahedral. Under an applied field of 100 Oe, the temperature dependences of zero-field-cooled (ZFC) and field-cooled (FC) curves were measured from 4.2 to 295 K. $M{\ddot{o}}ssbauer$ spectra were also recorded at various temperatures ranging from 4.2 to 295 K. We thus confirmed that the $N{\acute{e}}el$ temperature of $NaFe_{0.9}Mn_{0.1}PO_4$ ($T_N=14K$) was lower than that of maricite-$NaFePO_4$ ($T_N=15K$).

• 새물리
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• 제68권12호
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• pp.1293-1301
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• 2018

시판 중인 고온초전도 GdBCO 박막선재의 기본적인 자기적 특성들을 PPMS-VSM 장비를 이용하여 조사하였다. ZFC m(T) 곡선으로부터 $T_c$ 는 ~93 K였다. m(H) 배경데이터를 제거한 후, GdBCO 초전도층의 알짜 m(H) 데이터를 얻고, ${\Delta}m_{irr}$ 을 구하였다. $H_{irr}(T)$ 곡선은 $H_{irr}=H_{irr}(0)(1-T/T_c)^n$ 관계식과 잘 일치하고, n 값은 1.19이다. GdBCO 박막선재의 $J_c$ 와 H의 $J_c{\propto}{\Delta}M_{irr}{\propto}{\Delta}m_{irr}{\propto}H^{-{\delta}}$ 관계식의 ${\delta}$ 값으로부터 자속 특성을 조사하였다. 독립적인 자속고정효과를 나타내는 ${\delta}{\approx}0$ 인 영역, 상호작용의 집단적인 자속고정효과를 나타내는 ${\delta}{\approx}0.6{\sim}1.2$인 영역, 그리고 로렌츠 힘을 받아 자속들이 자유롭게 움직이는 ${\delta}{\gg}2$ 영역 등으로 구분할 수 있다. ${\delta}{\approx}0$ 특성에서 ${\delta}{\approx}0.6{\sim}1.2$ 특성으로 변화하는 자기장을 $H_1$ 으로, ${\delta}{\approx}0.6{\sim}1.2$ 특성에서 ${\delta}{\gg}2$ 특성으로 전이하는 자기장을 $H_2$ 라 하였다. $H_1$ < H < $H_2$ 영역에서 ${\delta}(T)$ 관계를 구하였고, 온도가 감소함에 따라 ${\delta}$ 값은 점차적으로 줄어들었다.