• Title/Summary/Keyword: YBa$_2$Cu$_3$O$_{7-{\delta}}$

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Microstructure Analysis of Y-Ba-Cu-O thin Films Grown on STO Substrates with Controlled ZnO Nanorods (ZnO 나노막대가 형성된 STO기판에 증착한 Y-Ba-Cu-O 박막의 미세구조 분석)

  • Oh, S.K.;Jang, G.E.;Tran, H.D.;Kang, B.W.;Kim, K.W.;Lee, C.Y.;Hyun, O.B.
    • Progress in Superconductivity
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    • v.11 no.1
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    • pp.47-51
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    • 2009
  • For many large-scale applications of high-temperature superconducting materials, large critical current density ($J_c$) in high applied magnetic fields are required. A number of methods have been reported to introduce artificial pinning centers in $YBa_2Cu_3O_{7-{\delta}}$ films for enhancement of their $J_c$. We studied the microstructures and characteristic of $YBa_2Cu_3O_{7-{\delta}}$ films fabricated on $SrTiO_3$ (100) substrates with ZnO nanorods as pinning centers. Au catalyst nanoparticles were synthesized on STO substrates with self assembled monolayer to control the number of ZnO nanorods. The density of Au nanoparticles is approximately $240{\sim}260{\mu}m^{-2}$ with diameters of $41{\sim}49nm$. ZnO nanorods were grown on STO by hot-walled PLD with Au nanoparticles. Typical size of ZnO nanorod was around 179 nm in diameter and $2{\sim}6{\mu}m$ in length respectively. YBCO films deposited directly on STO substrates show the c-axis orientation, while YBCO films with ZnO nanorods exhibit any mixed phases without any typical crystal orientation.

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A study on the single buffer layers for the application of $YBa_{2}$$Cu_{3}$$O_{7-\delta}$ coated conductors (Y$Ba_{2}$$Cu_{3}$$O_{7-\delta}$ coated conductors의 응용을 위한 단일완충층에 대한 연구)

  • ;;;Donggi Shi
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2003.10a
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    • pp.120-122
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    • 2003
  • BaZrO$_3$and SrTiO$_3$(STO) thin films were Pulsed laser deposited on biaxially textured Ni and Ni-W alloy substrates to be used as single buffer layer for coated conductor. The texture of the films were analysed using the GADDS (general area detector diffraction system). Both films deposited on the metal tape were strongly (001) oriented, and in-plane textured (Δø (BZO) =9$^{\circ}$, Δø (STO) = 10$^{\circ}$).

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The Superconductivity of $Y(Ba_{1-x}, K_x)_2Cu_3O_y$ (Y$(Ba_{1-x}, K_x)_2Cu_3O_y$의 초전도성)

  • 이형철;김성래;성낙억;강광용;노지현;장민수
    • Electrical & Electronic Materials
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    • v.3 no.1
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    • pp.52-58
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    • 1990
  • YBa$_{2}$ Cu$_{3}$O$_{7-{\delta}}$의 Ba대신 K를 일부 치환시킨 Y(Ba$_{1-x}$ , $K_{x}$ )$_{2}$Cu$_{3}$O$_{y}$ 에서 x의 값에 따른 초전도 특성의 변화를 연구하였다. XRD 무늬와 Infrared의 투과율로써 상의 변화를 관측하고 온도에 따른 전기저항의 변화를 측정함으로써 초전도성을 조사하였다. Ba 대신 K의 양이 증가할수록 Y(Ba$_{1-x}$ ,K$_{x}$)$_{2}$Cu$_{3}$O$_{y}$ 는 다중상이 되어 갔고 전기저항이 0이 되는 T$_{c}$는 점점 더 낮은 온도로 이동하다가 x.geq.0.6이 되면 초전도 특성을 잃었다.을 잃었다..

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Application of Dielectric-loaded Cavity Resonators with HTS Endplates for Tunable High-Q Resonators and Characterization Tools for Large HTS Films (고온초전도 박막이 설치된 유전체부하 공진기의 주파수 조절 가능한 High-Q 공진기 제작 및 대면적 고온초전도 박막의 특성평가에의 응용)

  • Kwon, Hyeong-Jun;Park, Jong-Un;Kang, Hun;Hur, Jung;Lee, Sang-Young
    • 한국초전도학회:학술대회논문집
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    • v.9
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    • pp.75-82
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    • 1999
  • TE$_{01\;{\delta}}$ mode Cavity Resonators with a low loss dielectric rod and YBa$_2Cu_3O_{7-{\delta}}$ (YBCO) endplates were prepared and their microwave properties were studied at temperatures above 30 K. Both sapphire and rutile were used as the dielectrics. The TE$_{01\;{\delta}}$ mode Q$_0$ of the resonator, designed to work as a tunable resonator with variations in the gap distance (s) between the dielectric rod and the top YBCO, was more than 1000000 at s = 0 mm and at 30 K and .the resonant frequency of 19.56GHz when a sapphire rod was used for the dielectric. The TE$_2Cu_3O_{7-{\delta}}$ mode resonant frequency (f$_0$) appeared to decrease as the temperature is raised. Meanwhile, the temperature dependence of the TE$_2Cu_3O_{7-{\delta}}$ mode f$_0$ of the rutile-loaded resonator appeared different with f$_0$ increasing according to the temperature and Q$_0$ more than 300000 at 30 K and f$_0$ = 8.56 CHz. Comparisons were made between the microwave properties of the sapphire-loaded and the rutile-loaded resonators. Also, applications of the TE$_2Cu_3O_{7-{\delta}}$ mode cavity resonator for a tunable resonator with a very high Q$_0$ as · well as a characterization tool for surface resistance measurements of HTS films are described.

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Characteristics of $YBa_2Cu_3O_{7-x}$ Thin Films on $SrTiO_3$ substrate with surface modification by Au nanoparticles (STO기판에 금 나노입자가 분산된 YBCO 박막의 특성)

  • Oh, Se-Kweon;Jang, Gun-Eik;Tran, Hai Duc;Kang, Byoung-Won;Lee, Cho-Yeon;Hyun, Ok-Bae
    • Progress in Superconductivity and Cryogenics
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    • v.12 no.3
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    • pp.7-11
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    • 2010
  • For many large-scale applications of high-temperature superconducting materials, large critical current density($J_c$) in high applied magnetic fields are required. A number of methods have been reported to introduce artificial pinning centers(APCs) in $YBa_2Cu_3O_{7-\delta}$(YBCO) films for enhancement of their $J_c$. In this work, we investigated electric characteristic of YBCO films on $SrTiO_3$ (100) substrates whose surfaces were modified by the introduction of Au nanoparticles (AuNPs). Au nanoparticles were uniformly dispersed on STO substrates with one of typical solution techniques, self assembled monolayer. After heating the STO substrates with Au nanoparticles, the size of Au nanoparticles was around 29~32 nm in height and 41~49 nm in diameter. XRD diffraction patterns taken on the YBCO film with Au nanoparticles show the c-axis orientation. The measured $T_c$ of YBCO /AuNPs films was around 89K and the $J_c$ was 0.75 MA/$cm^2$ at 65 K and 1 T.

An Automated Measurement System for the Microwave Surface Resistance of High-$T_c$ Superconductor Films

  • Lee, J.H.;Lim, J.;Lee, Jung-Hun;Lee, Sang-Young
    • Progress in Superconductivity
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    • v.2 no.1
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    • pp.27-32
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    • 2000
  • A prototype for a highly sensitive, automated measurement system for the microwave surface resistance of high-$T_c$ superconductor films was set up, and tested by measuring the microwave surface resistances of high-$T_c$ $YBa_2Cu_3O_{7-\delta}$ (YBCO) films at the frequency of about 19.6 GHz and the temperature of 30 K $\sim$ 90 K. An open-ended $TE_{011}$ mode sapphire-loaded cylindrical cavity resonator was used as the measurement probe, where YBCO films were used as the endplates of the cylindrical cavity. The characteristics of the measurement system include functions to display the unloaded Q and the resonant frequency of the $TE_{011}$ mode resonator as well as the microwave surface resistance of the YBCO films, all simultaneously as a function of temperature. Applicability of the measurement system for investigating the homogeneity in the microwave properties of large high-$T_c$ superconductor films is discussed.

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Determination of the Copper Valency and the Oxygen Deficiency in the High Tc Superconductor, $YBa_2Cu_3O_{7-\delta}$

  • Choy, Jin-Ho;Choi, Suk-Yong;Byeon, Song-Ho;Chun, Sung-Ho;Hong, Seung-Tae;Jung, Duk-Young;Choe, Won-Young;Park, Yung-Woo
    • Bulletin of the Korean Chemical Society
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    • v.9 no.5
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    • pp.289-291
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    • 1988
  • The ratio of trivalent to divalent copper has been determined by the redox titration for two superconducting phases of $YBa_2Cu^{3+}_{2x}Cu^{2+}_{3-2x}O_{6.5+x}$ with the onset temp. of 60K (x = 0.23 ${\pm}$ 0.01) and 90K (x = 0.35 ${\pm}$ 0.02), and for the insulating one (x ${\cong}$ 0) which was kept in an ambient atmosphere for 72 hrs. It is found that $T_c$, and the ratio of $Cu^{3+}/Cu^{2+}$ depend strongly on the annealing temperature and time. A typical orthorhombic phase can easily be obtained by a slow cooling or stepwise cooling at $PO_2$ = 1 atm, and shows a high Tc (ca. 90K) superconductivity.

An automated measurement system for the microwave surface resistance of high-T$_c$ superconductor films

  • Lee, J.H.;Lim, J.;Lee, Jung-Hun;Lee, Sang-Young
    • 한국초전도학회:학술대회논문집
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    • v.10
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    • pp.173-178
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    • 2000
  • A prototype for a highly sensitive, automated measurement system for the microwave surface resistance of high-T$_c$ superconductor films was set up, and tested by measuring the microwave surface resistances of high-T$_c$ YBa$_2$Cu$_3$O$_{7-{\delta}}$(YBCO) films at the frequency of about 19.6 GHz and the temperature of 30 K ${\sim}$ 90 K. An open-ended TE$_{011}$ mode sapphire-loaded cylindrical cavity resonator was used as the measurement probe, where YBCO films were used as the endplates of the cylindrical cavity. The characteristics of the measurement system include functions to display the unloaded ${\varrho}$ and the resonant frequency of the TE$_{011}$ mode resonator as well as the microwave surface resistance of the YBCO films, all simultaneously as a function of temperature. Applicability of the measurement system for investigating the homogeneity in the microwave properties of large high-T$_c$ superconductor films is discussed.

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