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Chemistry and Crystallographic Studies of Metal Ion Exchanged Zeolite X. Ⅰ. The Crystal Structure of Fully Dehydrated and Fully $K^+$-Exchanged Zeolite X, $K_{92}$-X

  • 장세복;김양
    • Bulletin of the Korean Chemical Society
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    • v.16 no.6
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    • pp.539-542
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    • 1995
  • The crystal structure of K92-X (K92Al92Si100O384), a=25.128(1) Å, dehydrated at 360 ℃ and 2X 10-6 Torr, has been determined by single-crystal X-ray diffraction techniques in the cubic space group Fd&bar{3} at 21(1) ℃. The structure was refined to the final error indices R1=0.044 and Rw=0.039 with 242 reflections for which I<3σ(I). In this structure, ninety-two K+ ions are located at the five different crystallographic sites. Sixteen K+ ions are located at the centers of the double six rings (site I; K(1)-O(3)=2.65(2) Å and O(3)-K(1)-O(3)=92.0(6)°). About twelve K+ ions lie at site I' in the sodalite cavity opposite double six rings (D6R's) and these K+ ions are recessed ca. 1.62 Å into the sodalite cavity from their O(3) plane (K(2)-O(3)=2.74(2) Å, O(3)-K(2)-O(3)=88.5(8)°). About thirty-two K+ ions are located at the site II in the supercage and these K+ ions are recessed ca. 1.20 Å into the supercage from their O(2) plane (K(3)-O(2)=2.64(2) Å, and O(2)-K(3)-O(2)=101(1)°). About twenty-two K+ ions lie at the site III in the supercage opposite 4-ring ladder and the remaining ten K+ ions lie at the site III' near the 4-ring ladder in the supercage (K(4)-O(4)=2.88(3) Å, O(4)-K(4)-O(4)=79.8(9)°, K(5)-O(4)=2.8(2) Å, and O(4)-K(5)-O(4)=68(5)°).

Bright band detection using X-band polarimetric radar (X-밴드 이중편파 레이더에 의한 밝은 띠 탐지)

  • Lee, Dong-ryul;Jang, Bong-joo;Hwang, Seok Hwan;Noh, Hui-seong
    • Journal of Korea Water Resources Association
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    • v.53 no.12
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    • pp.1211-1220
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    • 2020
  • This research detects the features of the bright band (BB) through analysis of the vertical profile of range height indicator (RHI) and the slant range beam profile of plane position indicator (PPI) of the polarimetric radar measurements-horizontal reflectivity (ZH), differential reflectivity (ZDR), and cross-correlation coefficient (ρHV). As a result of the analysis, it is possible to clearly detect the bright band using the polarimetric radar measurements, and it is confirmed that the result is consistent by double searching for the BB using the RHI and PPI scan data at the same time. Based on these results, the accuracy of QPE (quantification of precipitation estimation) can be improved by applying the BB search method by the PPI slant range in this research to large rainfall radars that only scan PPI volumes in the field without RHI observations.

Characterizations of GaN polarity controlled by substrate using the hydride vapor phase epitaxy (HVPE) technique (HVPE법으로 성장시킨 GaN 박막의 기판에 따른 극성 특성)

  • Oh, Dong-Keun;Lai, Van Thi Ha;Choi, Bong-Geun;Yi, Seong;Chung, Jin-Hyun;Lee, Seong-Kuk;Shim, Kwang-Bo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.18 no.3
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    • pp.97-100
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    • 2008
  • Polar and non-polar GaN was grown by the HVPE on various substrates and influence of polarity has been investigated. The $10\;{\mu}m$ thickness GaN were grown by HVPE is along A-plane ($11{\bar{2}}0$), C-plane (0001) and M-Plane ($10{\bar{1}}0$) sapphire substrate respectively. Surface properties were observed by optical microscope and atomic force microscopy. High resolution X-ray diffraction (HR-XRD) confirms the wurtzite structure. The donor band exciton peak located at ${\sim}3.4\;eV$ and also located yellow luminescence peak at 2.2 eV. The polarity of the GaN film has a strong influence on the morphology and the optical properties.

The study of Controlling chaos for Bonhoeffer-van der Pol oscillation model by small parameter perturbation (Bonhoeffer - van der Pol 오실레이터 모델에서의 미소 파라미터 섭동에 의한 카오스 제어)

  • Bae, Yeong-Chul;Ko, Jae-Ho;Yim, Wha-Yeong
    • Proceedings of the KIEE Conference
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    • 1995.07b
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    • pp.817-819
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    • 1995
  • Applied by periodic Stimulating Currents in Bonhoeffer-Van der Pol(BVP) model, chaotic and periodic phenomena occured at specific conditions. The conditions of the chaotic motion in BVP comprised 0.7182< $A_{1}$ <0.792 and 1.09< $A_{1}$ <1.302 proved by the analysis of phase plane, bifurcation diagram, and lyapunov exponent. To control the chaotic motion, two methods were suggested by the first used the amplitude parameter $A_{1}$,$A_{1}={\varepsilon}((x-x_{s})-(y-y_{s}))$ and the second used the temperature parameter c, c=c$(1+ {\eta}cos{\Omega}t)$ which the values of $\eta$, ${\Omega}$ varied respectlvly, and $x_{s}$, $y_{s}$ are the periodic signal. As a result of simulating these methods, the chaotic phenomena was controlled with the periodic motion of periodisity. The feasibilities of the chaotic and the periodic phenomena were analysed by phase plane and lyapunov exponent.

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Effects of Slits and Swirl Vanes on the Main Flow Fields of a Gun-Type Gas Swirl Burner (슬릿과 스월베인이 Gun식 가스버너의 주 유동장에 미치는 영향)

  • Kim, J.K.;Jeong, K.J.
    • Journal of Power System Engineering
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    • v.6 no.4
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    • pp.23-29
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    • 2002
  • This paper is studied to investigate the effect of slits and swirl vanes on the main flow fields of a gun-type gas burner through X-Y plane and Y-Z plane respectively by using X-probe from hot-wire anemometer system. This experiment was carried out with flow rate $450{\ell}/min$ in respective burner models installed in the test section of a subsonic wind tunnel. The burner models with only slits and only swirl vanes respectively were made by modifying original gun-type gas burner. The fast jet flow spurted from slits played a role such as an air-curtain because it encircled rotational flow by swirl vanes and drives mixed main flow to axial direction. As a result, the gun-type gas burner had a wider flow range up to about Y/R=1.5 deviated from slits and maintains a comparatively large velocity in the central part of burner within the range of about X/R=2.5. Therefore, it was very desirable that swirl vanes were installed within slits in gun-type gas burner in order to control the main flow fields effectively.

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Assessment of negative Poisson's ratio effect on thermal post-buckling of FG-GRMMC laminated cylindrical panels

  • Shen, Hui-Shen;Xiang, Y.
    • Advances in nano research
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    • v.10 no.5
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    • pp.423-435
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    • 2021
  • This paper examines the thermal post-buckling behaviors of graphene-reinforced metal matrix composite (GRMMC) laminated cylindrical panels which possess in-plane negative Poisson's ratio (NPR) and rest on an elastic foundation. A panel consists of GRMMC layers of piece-wise varying graphene volume fractions to obtain functionally graded (FG) patterns. Based on the MD simulation results, the GRMMCs exhibit in-plane NPR as well as temperature-dependent material properties. The governing equations for the thermal post-buckling of panels are based on the Reddy's third order shear deformation shell theory. The von Karman nonlinear strain-displacement relationship and the elastic foundation are also included. The nonlinear partial differential equations for GRMMC laminated cylindrical panels are solved by means of a singular perturbation technique in associate with a two-step perturbation approach and in the solution process the boundary layer effect is considered. The results of numerical investigations reveal that the thermal post-buckling strength for (0/90)5T GRMMC laminated cylindrical panels can be enhanced with an FG-X pattern. The thermal post-buckling load-deflection curve of 6-layer (0/90/0)S and (0/90)3T panels of FG-X pattern are higher than those of 10-layer (0/90/0/90/0)S and (0/90)5T panels of FG-X pattern.

Exact Solutions for Vibration and Buckling of An SS-C-SS-C Rectangular Plate Loaded by Linearly Varying In-plane Stresse (등변분포 평면응력을 받는 SS-C-SS-C 직사각형 판의 진동과 좌굴의 엄밀해)

  • 강재훈;심현주;장경호
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.14 no.1
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    • pp.56-63
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    • 2004
  • Exact solutions are presented for the free vibration and buckling of rectangular plates haying two opposite edges ( x=0 and a) simply supported and the other two ( y=0 and b) clamped, with the simply supported edges subjected to a linearly varying normal stress $\sigma$$_{x}$=- $N_{0}$[1-a(y/b)]/h, where h is the plate thickness. By assuming the transverse displacement ( w) to vary as sin(m$\pi$x/a), the governing partial differential equation of motion is reduced to an ordinary differential equation in y with variable coefficients. for which an exact solution is obtained as a power series (the method of Frobenius). Applying the clamped boundary conditions at y=0 and byields the frequency determinant. Buckling loads arise as the frequencies approach zero. A careful study of the convergence of the power series is made. Buckling loads are determined for loading parameters a= 0, 0.5, 1, 1.5. 2, for which a=2 is a pure in-plane bending moment. Comparisons are made with published buckling loads for a= 0, 1, 2 obtained by the method of integration of the differential equation (a=0) or the method of energy (a=1, 2). Novel results are presented for the free vibration frequencies of rectangular plates with aspect ratios a/b =0.5, 1, 2 when a=2, with load intensities $N_{0}$ / $N_{cr}$ =0, 0.5, 0.8, 0.95, 1. where $N_{cr}$ is the critical buckling load of the plate. Contour plots of buckling and free vibration mode shapes ate also shown.shown.

Design of an Autonomous Air Combat Guidance Law using a Virtual Pursuit Point for UCAV (무인전투기를 위한 가상 추적점 기반 자율 공중 교전 유도 법칙 설계)

  • You, Dong-Il;Shim, Hyunchul
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.42 no.3
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    • pp.199-212
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    • 2014
  • This paper describes an autonomous air combat guidance law using a Virtual Pursuit Point (VPP) in one-on-one close engagement for Unmanned Combat Aerial Vehicle (UCAV). The VPPs that consist of virtual lag and lead points are introduced to carry out tactical combat maneuvers. The VPPs are generated based on fighter's aerodynamic performance and Basic Fighter Maneuver (BFM)'s turn circle, total energy and weapon characteristics. The UCAV determines a single VPP and executes pursuit maneuvers based on a smoothing function which evaluates probabilities of the pursuit types for switching maneuvers with given combat states. The proposed law is demonstrated by high-fidelity real-time combat simulation using commercial fighter model and X-Plane simulator.

Contemplation on Usefulness of Plane Cone for Taking Image of Intercondyloid Fossa (무릎 과간와(Intercondyloid fossa) 촬영용 평면 Cone의 유용성에 대한 고찰)

  • Shin, WoonJae
    • Journal of the Korean Society of Radiology
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    • v.9 no.7
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    • pp.501-508
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    • 2015
  • There are various Intercondyloid fossa X-ray taking methods. The methods carried out in clinics are Holmblad method, Camp-Conventry method, and Beclere method. Taking image of Intercondyloid fossa is carried a lot as basic examination for diagnosis related to simple fracture and cruciate ligament. Considering the condition and pains of patients, safe method is chosen but because Holmblad method can cause pains to knee part adhering to cassette, it is not easily used. In this study self-produced plane circular cone was attached to a cassette and in the posture for Holmblad method questionnaires of 100 applicants were analyzed to understand cognition on alleviation of pains, and the concentration of imge quality by scattering rays was measured with densitometer by taking human body phantom with X-ray. As a result, in the posture for Holmblad method, cognition on pains was alleviated by average 99%, and the change of concentration of X-ray film taken using phantom by scattering rays decreased statistically significantly compared to the cassette which did not use self-produced plane cone, therefor it is thought that the method can be valuably used in clinics.

High Out-of-Plane Alignment of Liquid Crystalline Methacrylate Copolymer Bearing Photoreactive 4-Styrylpyridine Moiety

  • Kwak, Gi-Seop;Kong, Jong-Yun;Kim, Min-Woo;Hyun, Seok-Hee;Kim, Woo-Sik
    • Macromolecular Research
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    • v.17 no.4
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    • pp.271-275
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    • 2009
  • This paper describes the out-of-plane order of a liquid crystalline(LC) methacrylate copolymer(3) comprised of a methacrylate(1) with a 4-styrylpyridine moiety as the photo-cyclodimerizable group and a benzoate moiety as the mesogenic group in the side chain, and another methacrylate(2) with a 4-(4-methoxyphenyl)benzoate moiety as the mesogenic group. The composition of 1 and 2 units in 3 was estimated to have a molar ratio of 54.2:45.8 by $^{1}H$ NMR spectroscopy. The X-ray diffraction study revealed that the copolymer forms a partial bilayer smectic structure. The copolymer gave rise to a high out-of-plane order parameter of about 0.74 in a wide LC temperature range of $110{\sim}160^{\circ}C$ after linearly polarized, UV light irradiation and subsequent annealing. Moreover, the external reflection IR analysis indicated that excess UV-light irradiation makes the out-of-plane LC structure of the copolymer appear in a higher and wider temperature range.