• Title/Summary/Keyword: Wet-reduction process

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Dependence of deep submicron CMOSFET characteristics on shallow source/drain junction depth (얕은 소오스/드레인 접합깊이가 deep submicron CMOSFET 소자 특성에 미치는 영향)

  • 노광명;고요환;박찬광;황성민;정하풍;정명준
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.33A no.4
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    • pp.112-120
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    • 1996
  • With the MOsES (mask oxide sidewall etch scheme)process which uses the conventional i-line stepper and isotropic wet etching, CMOSFET's with fine gate pattern of 0.1.mu.m CMOSFET device, the screening oxide is deposited before the low energy ion implantation for source/drain extensions and two step sidewall scheme is adopted. Through the characterization of 0.1.mu.m CMOSFET device, it is found that the screening oxide deposition sheme has larger capability of suppressing the short channel effects than two step sidewall schem. In cse of 200.angs.-thick screening oxide deposition, both NMOSFET and PMOSFET maintain good subthreshold characteristics down to 0.1.mu.m effective channel lengths, and show affordable drain saturation current reduction and low impact ionization rates.

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Experimental study of NOx reduction in marine diesel engines by using wet-type exhaust gas cleaning system (선박용 디젤엔진의 NOx를 저감하기 위한 습식 배기가스 처리기술 적용에 관한 실험적 연구)

  • Ryu, Younghyun;Kim, Taewoo;Kim, Jungsik;Nam, Jeonggil
    • Journal of Advanced Marine Engineering and Technology
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    • v.41 no.3
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    • pp.216-221
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    • 2017
  • Diesel engines have the highest brake thermal efficiency among internal combustion engines. Therefore, they are utilized in medium and large transportation vehicles requiring large amounts of power such as heavy trucks, ships, power generation systems, etc. However, diesel engines have a disadvantage of generating large quantities of nitrogen oxides during the combustion process. Therefore, the authors tried to reduce the amount of nitrogen oxides in marine diesel engines using a wet-type exhaust gas cleaning system utilizing the undivided electrolyzed seawater method. In this method, electrolyzed seawater in injected into the harmful gas discharge from the diesel engine using real seawater. The authors investigated the reduction of NO and NOx from the pH value, available chlorine concentration, and the temperature of electrolyzed seawater. The results of this experiment indicated that when the electrolyzed seawater is acidic, the NO oxidation rate in the oxidation tower is higher than that when the electrolyzed seawater has a neutral pH. Likewise, the NO oxidation rate increased with the increase in concentration of chlorine. Further, it was confirmed that the electrolyzed seawater temperature had no effect on the NO oxidation rate. Thus, the NOx exhaust emission value produced by the diesel engine was reduced by means of electrolyzed seawater treatment.

Growth Mechanism of Nickel Nanodispersoids during Consolidation of $Al_2O_3/Ni$ Nanocomposite Powder ($Al_2O_3/Ni$ 나노복합분말의 치밀화중 분산상 Ni의 성장기구)

  • ;;;;T. Sekino;K. Niihara
    • Journal of Powder Materials
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    • v.7 no.4
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    • pp.237-243
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    • 2000
  • The property and performance of the $Al_2O_3/Ni$ nanocomposites have been known to strongly depend on the structural feature of Ni nanodispersoids which affects considerably the structure of matrix. Such nanodispersoids undergo structural evolution in the process of consolidation. Thus, it is very important to understand the microstructural development of Ni nanodispersoids depending on the structure change of the matrix by consolidation. The present investigation has focused on the growth mechanism of Ni nanodispersoids in the initial stage of sintering. $Al_2O_3/Ni$ powder mixtures were prepared by wet ball milling and hydrogen reduction of $Al_2O_3$ and Ni oxide powders. Microstructural development and the growth mechanism of Ni dispersion during isothermal sintering were investigated depending on the porosity and structure of powder compacts. The growth mechanism of Ni was discussed based upon the reported kinetic mechanisms. It is found that the growth mechanism is closely related to the structural change of the compacts that affect material transport for coarsening. The result revealed that with decreasing porosity by consolidation the growth mechanism of Ni nanoparticles is changed from the migration-coalescence process to the interparticle transport mechanism.

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Recycling of Wastepaper(V): -Calcium Hardness Control of Process Water for Zero-Discharge System- (고지재상연구 (제5보) -공정수 폐쇄화를 위한 칼슘경도 조절-)

  • 지경락;류정용;신종호;송봉근;오세균
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.2
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    • pp.15-24
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    • 1999
  • A new technique for recycling of white water was developed in order to reduce the calcium hardness in a closed OCC recycling system. Calcium ions present in the white water were precipitated as calcium carbonate by reacting with sodium carbonate, and the precipitated $CaCO_3$ was removed from the system using a flotation fractionation method, which has been commonly used in deinking process. In the flotation stage, a mixed gas of $CO_2$-air was purged into the flotation cell because the pH of $Na_2CO_3$-treated white water was reduced to neutral by $CO_2$ gas. Since $CaCO_3$ precipitate tends to stick onto fine fiber surface and then selectively removed from the white water, a proper amount of suspended solid in white water acts as an important factor for deciding the removal efficiency. By the application of $Na_2CO_3$ addition-$CO_2$ flotation to the short circulated white water, the calcium hardness was significantly reduced by 87% and more. Removal of calcium ions with fine fibers led to a drainage improvement, reduction of fresh water consumption, and enhanced efficiency of wet-end chemicals.

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A Novel Method for Calcium Hardness Control of Closed OCC Recycling System

  • Ow, Say-Kyoun;Shin, Jong-Ho;Song, Bong-Keun;Ryu, Jeong-Yong
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.11b
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    • pp.164-171
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    • 1999
  • A new technique for recycling process water was developed in order to reduce the calcium hardness of the closed OCC recycling system. Calcium ions present in the white water were precipitated as calcium carbonate by a reaction with sodium carbonate and the CaCO$_3$precipitates were easily removed from the system by a dissolved air flotation(DAF) method. After the DAF stage, CO$_2$-gas was purged into the water because the pH of Na$_2$CO$_3$-treated white water was reduced to neutral by CO$_2$gas. Since CaCO$_3$precipitate tends to stick onto the fine fiber surface and then is selectively removed from the water, a proper amount of suspended solid in the process water acts as an important factor in deciding the removal efficiency. By the application of Na$_2$CO$_3$addition - DAF - CO$_2$purging to the short circulated white water the calcium hardness was significantly reduced by 92% and more. The removal of calcium ions with fine fibers led to drainage improvement, reduction of fresh water consumption, and enhanced efficiency of wet-end chemicals.

Biofiltration of Ammonia Gas from Composting Using Sawdust as Biofilter Media (퇴비화 암모니아 가스의 톱밥 바이오 필터 매체에 의한 생물학적 탈취)

  • Hong Ji Hyung;Park Keum Joo
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.45 no.2
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    • pp.107-115
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    • 2003
  • Dairy manure amended with crop and forest residues (moisture 69% wet basis, C/N 22) was composted in a 605 L pilot-scale vessel using continuous air flow (56 L/min) for 19 days. Three pilot-scale sawdust biofilters (moisture 63%, pH 5.0) were built to clean biological waste gas from the composting process. For each methods, two replicated experiments were monitored over a period of three weeks. The system was evaluated to determine the biofilter media depth that would be adequate for compost odour reduction. The compost air cleaning was measured based on ammonia gas concentration before and after passing through the biofilter. Ammonia gas removal efficiency over 3 weeks was 42, 75 and 87% at sawdust biofilter media depth levels of 202, 400 and 600 mm, respectively. Each sawdust biofilter was operated at a moisture content in the range of 60~62% (wb), a temperature from 15 to $25^{\circ}C$, an average pressure drop from 240 to 340 Pa and a detention time from 60 to 180 seconds during the biofiltration process.

Characteristics of Pt/C Nano-catalyst Synthesized by Arc Plasma Deposition (아크 플라즈마 증착공정을 통한 Pt/C 나노촉매 합성 및 특성평가)

  • Joo, Hye-Sook;Choi, Han-Shin;Ha, Heon-Phil;Kim, Do-Hyang
    • Journal of Powder Materials
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    • v.19 no.1
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    • pp.6-12
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    • 2012
  • Electricity is generated by the combined reactions of hydrogen oxidation and oxygen reduction which occur on the Pt/C catalyst surface. There have been lots of researches to make high performance catalysts which can reduce Pt utilization. However, most of catalysts are synthesized by wet-processes and a significant amount of chemicals are emitted during Pt/C synthesis. In this study, Pt/C catalyst was produced by arc plasma deposition process in which Pt nano-particles are directly deposited on carbon black surfaces. During the process, islands of Pt nano-particles were produced and they were very fine and well-distributed on carbon black surface. Compared with a commercialized Pt/C catalyst (Johnson & Matthey), finer particle size, narrower size distribution, and uniform distribution of APD Pt/C resulted in higher electrochemical active surface area even at the less Pt content.

An Ozone-based Advanced Oxidation Process for an Integrated Air Pollution Control System (복합대기오염 저감 시스템을 위한 오존 고속산화 기반 고도산화공정)

  • Uhm, Sunghyun;Hong, Gi Hoon;Hwang, Sangyeon
    • Applied Chemistry for Engineering
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    • v.32 no.3
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    • pp.237-242
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    • 2021
  • Simultaneous removal technologies of multi-pollutants such as particulate matters (PMs), NOx, SOx, VOCs and ammonia have received consistent attention due to the enhancement of pollutant abatement efficiency in addition to the stringent environmental regulation and emission standard. Pretreatment of insoluble NO by an ozone oxidation can be considered to be more effective route for saving space occupation as well as operation cost in comparison with that of traditional selective catalytic reduction (SCR) process. Moreover the primary advantage of ozone oxidation process is that the simultaneous removal with acidic gas including SOx is also available. Herein, we highlight recent studies of multi-pollutant abatement via ozone oxidation process and the promising research topics for better application in industrial sectors.

Efficient Enantioselective Synthesis of (R)-[3,5-Bis(trifluoromethyl)phenyl] Ethanol by Leifsonia xyli CCTCC M 2010241 Using Isopropanol as Co- Substrate

  • Ouyang, Qi;Wang, Pu;Huang, Jin;Cai, Jinbo;He, Junyao
    • Journal of Microbiology and Biotechnology
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    • v.23 no.3
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    • pp.343-350
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    • 2013
  • (R)-[3,5-Bis(trifluoromethyl)phenyl] ethanol is a key chiral intermediate for the synthesis of aprepitant. In this paper, an efficient synthetic process for (R)-[3,5- bis(trifluoromethyl)phenyl] ethanol was developed via the asymmetric reduction of 3,5-bis(trifluoromethyl) acetophenone, catalyzed by Leifsonia xyli CCTCC M 2010241 cells using isopropanol as the co-substrate for cofactor recycling. Firstly, the substrate and product solubility and cell membrane permeability of biocatalysts were evaluated with different co-substrate additions into the reaction system, in which isopropanol manifested as the best hydrogen donor of coupled NADH regeneration during the bioreduction of 3,5-bis(trifluoromethyl) acetophenone. Subsequently, the optimization of parameters for the bioreduction were undertaken to improve the effectiveness of the process. The determined efficient reaction system contained 200mM of 3,5-bis(trifluoromethyl) acetophenone, 20% (v/v) of isopropanol, and 300 g/l of wet cells. The bioreduction was executed at $30^{\circ}C$ and 200 rpm for 30 h, and 91.8% of product yield with 99.9% of enantiometric excess (e.e.) was obtained. The established bioreduction reaction system could tolerate higher substrate concentrations of 3,5- bis(trifluoromethyl) acetophenone, and afforded a satisfactory yield and excellent product e.e. for the desired (R)-chiral alcohol, thus providing an alternative to the chemical synthesis of (R)-[3,5-bis(trifluoromethyl)phenyl] ethanol.

Mass Reduction and Physicochemical Properties of the Produced Compost during Composting Domestic Food Wastes in a Small Composter (소형 퇴비화용기에서 가정 음식물쓰레기의 퇴비화 과정 중 감량화 및 생산 퇴비의 물리화학적 특성)

  • Park, Ju-Won;Seo, Jeoung-Yoon
    • Korean Journal of Environmental Agriculture
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    • v.20 no.4
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    • pp.238-243
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    • 2001
  • Mass reduction and physicochemical properties of the produced compost were investigated during composting domestic food wastes without additive. A small composter used in this study had the height of 15 cm from the center of bottom half circle (diameter 24 cm) up to under the lid, the side length of 50 cm and the horizontal lid angle of $50^{\circ}$ and was operated at the heating unit temperature of $85^{\circ}$. It was mixed by the rotating arm for two minutes in every half hour while supplied with air flow at 3 L/min for 10 minutes in every half hour. This condition was found in a preliminary experiment as optimal for keeping the water content of composting material in the optimal range without adding any bulking materials. The domestic food wastes were added into the composter at the rate of 1 kg/day without additives during composting. The results were as follows; during the composting process, water content maintained in the range of $51.0{\sim}53.5%$. Hemicellulose and lignin contents did not show any tendency, but cellulose content decreased. During the composting process, $NH_3-N$ and $NO_2-N$ were not detected due to nitrification. The contents of inorganic compounds did not increase during the composting process. They were in the range of $1.32{\sim}1.71%\;P_2O_5$, $1.29{\sim}1.48%\;CaO$, $0.41{\sim}0.49%\;MgO$, and $0.38{\sim}0.74%\;K_2O$. For 20 days, weight reduction rate was 67.5% in wet basis, and decomposition rate was 48% in dry basis. Concentration of heavy metals (Cu, Cr, Cd, Pb, Zn, Hg, As) was less than the limiting value of the compost. Maturity of the produced compost was 3 grade through reaching maximum temperature of $46{\sim}48^{\circ}C$.

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