• Title/Summary/Keyword: Water quenching

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Photo-sensitized oxidation of benzene in water under UV irradition (자외선 조사에 의한 벤젠의 광증감 산화처리에 관한 연구)

  • Lee, Chun Sik;Lee, Dong-Keun
    • Clean Technology
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    • v.4 no.2
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    • pp.11-22
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    • 1998
  • The photo-sensitized oxidation of benzene in water was investigated under various reaction conditions using persulfate, sulfate, nitrate, nitrite and chloride ions as sensitizers. Persulfate ion was proved to be the most effective sensitizer, while sulfate and nitrite could not play any sensitizing role on the benzene photooxidation. When exited together with other ions, the nitrite ion inhibited the photooxidation of benzene by quenching the produced hydroxyl radicals.

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Enhancement of the Soft Magnetic Properties of Co-based Amorphous Alloy by Two-step Cooling Method. (이단 냉각열처리에 의한 Co계 비정질 합금의 연자기 특성 향상)

  • 양재호;김만중;정연춘;김윤배;김택기
    • Journal of the Korean Magnetics Society
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    • v.10 no.1
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    • pp.7-10
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    • 2000
  • The soft magnetic properties of Co-based amorphous alloy have been studied as a function of cooling condition after annealing. The F&W treatment (furnace cooling to 25$0^{\circ}C$ then water quenching) could increase 60~10$0^{\circ}C$ more the initial permeability than those of furnace cooled or water quenched alloys. These results are investigated in terms of thermal stress and ordering of magnetic ion pairs.

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Improvement of Liquid Droplet Entrainment Model in the COBRA-TF Code

  • Ha, Kwi-Seok;Jeong, Jae-Jun;Sim, Suk-Ku
    • Nuclear Engineering and Technology
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    • v.30 no.3
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    • pp.181-193
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    • 1998
  • The COBRA-TF liquid droplet entrainment models have been assessed and improved through various experiments. The COBRA-TF code uses the Wurtz entrainment model in the film mist flow regime and the mechanistic model based on the critical Weber number and critical vapor velocity in the hot wall flow regimes, respectively. The Wurtz model has been replaced with the modified Sugawara model. The assessment against the experiments by Hewitt, Keeys, Yanai, and Whalley showed the modified Sugawara model better predicts the steam-water as well as the air-water experiments for the film mist flow regime. For hot wall flow regime, the COBRA-TF entrainment model was modified using two methods, one with an increased critical Weber number and the other with the Yonomoto's critical vapor velocity model. The modified models were assessed using the FLECHT-SEASET bottom reflood tests. The results showed that the Yonomoto model best predicts the quenching time, whereas the local maximum rod temperature was not affected much.

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An Experimental Study on Underwater Wet Arc Welding and Weldability (TMCP강의 수중 ARC용접 실험과 용접성)

  • 오세규;김민남
    • Journal of Ocean Engineering and Technology
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    • v.1 no.2
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    • pp.67-73
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    • 1987
  • The feasibility for a practical use of underwater wet arc welding process is experimentally investigated by using low hydrogen and high oxide type electrodes and TMCP steel plates. Main results are summarized as follows: 1)The absorption speed of the coated low hydrogen and high titanium oxide type eletrodes becomes constant after about 30 minutes in water, and more steeping time in water does not influnce welding arc behavior. 2) By bead appearance and X-ray inspection, the high titanium oxide type electrode is better than the low hydrogen type in underwater arc welding process. 3) The mechanical properties of underwater wet arc welds depend upon welding conditions more than those of in-air welds, and the optimum welding condition can be obtained. 4) Because of quenching effect by rapid cooling rate in underwater wet welding, the maximum hardness of HAZ is increased relatively higher in underwater wet welding, process.

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Evaluation of MCCI Behaviors in the Calandria Vault of CANDU-6 Plants Using CORQUENCH Code (CORQUENCH 코드를 활용한 중수로 calandria vault에서의 MCCI 거동 분석)

  • Seon Oh YU
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.17 no.2
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    • pp.90-100
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    • 2021
  • Molten corium-concrete interaction (MCCI) is one of the most important phenomena that can lead to the potential hazard of late containment failure due to basemat penetration during a severe accident. In this study, MCCI analytical models of the CORQUENCH code were prepared through verification calculations of several experiments, which had been performed using concrete types similar to those of the calandria vault floor in CANDU-6 plants. The behaviors of thermal-hydraulic variables related to MCCI phenomena were analyzed under the conditions of dry floor and water flooding during the severe accident stemming from a hypothetic station blackout. Uncertainty analyses on the ablation depth were also carried out. It was estimated that the concrete ablation was not interrupted due to the continuous MCCI process under the dry condition but was terminated within 24 hours under the water flooding condition. It was confirmed that the water flooding as a mitigating action was effective to achieve the quenching and thermal stabilization of the melt discharged from the calandria vessel, showing that the present models are capable of reasonably simulating MCCI phenomena in CANDU-6 plants. This study is expected to provide the technical bases to the accident management strategy during the late-phase severe accidents.

The Effects of Acidic Electrolytic Water on the Development of Barley Chloroplast (산성 전해수가 보리(Hordeum vulgae L.) 엽록체의 발달에 미치는 영향)

  • 정화숙;송승달;노광수;송종석;박강은
    • Journal of Environmental Science International
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    • v.8 no.2
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    • pp.255-261
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    • 1999
  • To investigate the effects of strong acidic electrolytic water on the chloroplast, barley leaves were treated with strong acidic electrolytic water(pH 2.5). And to investigate the effects of weak acidic electrolytic water on the chloroplast development, etiolated barley leaves were treated with weak acidic electrolytic water(pH 6.5) during greening period. Chl contents, Fo, Fv, and Chl fluorescence quenching coefficient in barley leaves were measured during and after treatment of acidic electrolytic water. The following results were obtained. Chl a, b, and carotenoid were decreased with treatment of strong acidic electrolytic water. Chl contents were significantly decreased than that of the control after 5 min. These results provide evidence that the strong acidic electrolytic water dissimilate the Chl and so that the value of Fo was slightly increased. The strong acidic electrolytic water damaged PS II because Fo was increased and Fv, Fm, and Fv/Fm ratio were decreased. qP, qNP and qE were decreased. On the other hand qI was increased than that of the control. But Chl content and Chl fluorescence patterns were a little changed as the pH increase over 4.0 Chl a, b, and carotenoid were increased with treatment of weak acidic electrolytic water during greening period. Chl contents were significantly increased than that of control after 12 hours greening. These results provide evidence that the weak acidic electrolytic water accelerated the chlorophyll synthesis. And the weak acidic electrolytic water accelerated PS II development because Fv, Fm, qP and Fv/Fm ratio were increased than that of the control.

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Antioxidant properties of brownish natural dyeing agents from medicinal plant (갈색계 천연색소 추출물의 항산화 특성)

  • Kim, Yeon-Soon;Kwon, O-Jun;Suh, Hwa-Jin;Park, Shin
    • Food Science and Preservation
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    • v.23 no.3
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    • pp.387-392
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    • 2016
  • The antioxidant activities of brownish natural dyeing agents, extracted from seven kinds of plants, were tested. Total polyphenol content, DPPH and ABTS radical scavenging activities, and singlet oxygen quenching effect were determined for hot water extracts and floral waters of plants. DPPH and ABTS radical scavenging activites increased with increasing amounts of the extracts from Uncaria gambir R. and Terminalia chebula R. displayed remarkable scavenging effects at concentrations below 0.1 mg/mL, in comparison with the positive control, ascorbic acid. However, antioxidant effects of the floral water, obtained from steam distillation of tested plants, were inefficient at concentration below 0.2 mg/mL. In particular, the natural dyeing agent effectively suppressed singlet oxygen induced by photosensitizer in in vitro assay systems. The concentrations ($IC_{50}$) required to exert 50% of singlet oxygen were 120 and $190{\mu}g/mL$ for hot water extracts from Uncaria gambir R. and Phellinus linteus, respectively. Among all the tested samples, the Uncaria gambir R. and Phellinus linteus extracts contained higher amount of total phenolic contents. The results suggest that naturally occurring dyeing agents are beneficial as natural antioxidants, encouraging further extensive studies.

Thermal Impact Characteristics by Forest Fire on Porcelain Insulators for Transmission Lines

  • Lee, Won-Kyo;Choi, In-Hyuk;Choi, Jong-Kee;Hwang, Kab-Cheol;Han, Se-Won
    • Transactions on Electrical and Electronic Materials
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    • v.9 no.4
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    • pp.143-146
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    • 2008
  • In this study the thermal impact characteristics by forest fire are extensively investigated using temperature controlled ovens. The test conditions for thermal impact damage are simulated according to the characteristics of natural forest fire. The test pieces are suspension porcelain insulators made by KRI in 2005 for transmission lines. In the thermal impact cycle tests with $300\;^{\circ}C$ thermal impact gradient (-70 to $230\;^{\circ}C$), cycling in 10 minute periods, no critical failures occurred in the test samples even with long cycle times. But in tests with thermal impact gradient from room temperature to $200-600\;^{\circ}C$, cycling in 10 to 30 minute periods, there were critical failures of the porcelain insulators according to the thermal impact gradient and quenching method. In the case of thermal impact by forest fire, it was found of that duration time is more important than the cycling time, and the initiation temperature of porcelain insulator failures is about $300\;^{\circ}C$, in the case of water quenching, many cracks and fracture of the porcelain occurred. It was found that the thermal impact failure is closely related to the displacement in the cement by thermal stress as confirmed by simulation. It was estimated that the initiation displacement by the thermal impact of $300\;^{\circ}C$ is about 0.1 %. Above 1% displacement, it is expected that the most porcelain insulators would fail.

Dehydration effects on spectroscopic properties of $Er^{+3}$ doped phosphate laser Glass ($Er^{+3}$ 첨가된 인산염 레이저 유리의 탈 수산기 영향에 관한 분광학적 특성)

  • Cho, Kou-Sung;Park, Wan-Soo;Kim, Jong-Su;Kim, Chong-Don
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.335-335
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    • 2008
  • Phosphate glass samples with various $Cr_2O_3$ and $Er_2O_3$ contents based upon $55P_2O_5\cdot24BaO\cdot10K_2O\cdot4Al_2O_3\cdot6Yb_2O_3$ were prepared. The prepared glass compositions are dehydrated using gas bubble flow method in open system and investigated the effects of the eliminating of OH groups from the glass melts with bubbling time. It was found that the probability of $Er^{+3}$ fluorescence quenching by OH groups oscillations linear depends upon the OH groups absorption coefficients in the maximum of the stretch vibrations band at $3500cm^{-1}$ while $Er^{+3}$ concentration range is between $1.6\times10^{19}$ and $21.2\times10^{19}$ ion/$cm^3$.

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Effect of Cooling Rate and Annealing Temperature on Corrosion and Microstructure of Zircaloy-4 and Zr-2.5Nb Alloy (Zircaloy-4와 Zr-2.5Nb 합금의 부식과 미세조직에 미치는 냉각속도와 소둔온도의 영향)

  • Jeong, Yong-Hwan;Jeong, Yeon-Ho;Kim, Hyeon-Gil;Wee, Myung-Yong
    • Korean Journal of Materials Research
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    • v.8 no.11
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    • pp.1031-1037
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    • 1998
  • To investigate the effect of cooling rate and annealing temperature on the corrosion of Zircaloy-4 and Zr-2. 5Nb alloys, autoclave corrosion tests were performed at $500^{\circ}C$ for the specimens prepared by various heat treatments. The specimens were heat-treated at $1050^{\circ}C$ for 30 minutes and cooled by ice-brine quenching, water quenching, oil quenching, air cooling, and furnace cooling. To investigate the effect of annealing temperature, the specimens were annealed at $\alpha$, ($\alpha$+$\beta$)-, and $\beta$-temperatures. It was observed from the $500^{\circ}C$ corrosion test that nodular corrosion occurred on the Zircaloy-4 alloy but did not occur on the Zr-2.5Nb alloy. The corrosion resistance of Zircaloy-4 increased with increasing the cooling rate. On the other hand, the corrosion resistance of Zr-2.5Nb decreased with increasing the cooling rate and the annealing temperature. It is suggested that corrosion resistance of Zircaloy-4 would be controlled by the distribution of Fe and Cr element in the matrix and precipitates, while that of Zr-2.5Nb alloy the niobium concentration and $\beta_{-Nb}$ phase.

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