• 제목/요약/키워드: Water flux

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유도용액으로 비료를 사용한 정삼투 해수담수화에서 유도용액의 성능 평가 (Evaluating the Performance of Draw Solutions in Forward Osmosis Desalination Using Fertilizer as Draw Solution)

  • 정남조;김승건;이호원
    • 멤브레인
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    • 제24권5호
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    • pp.400-408
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    • 2014
  • 유도용액으로 비료를 사용하는 정삼투식 해수담수화에서 유도용액의 성능을 평가하였다. 일반적으로 많이 사용되는 비료 중에서 삼투압, 용해도 및 pH 등을 고려하여 $NH_4NO_3$, $NH_4H_2PO_4$, $(NH_4)_2HPO_4$, KCl, $KNO_3$$KHCO_3$를 유도용액 후보군으로 선정하였다. 수투과선속, 질소와 인의 역용질선속 및 비역용질선속을 측정하여 유도용액의 성능을 평가하였다. KCl은 본 연구에서 선정된 유도용액 중에서 가장 높은 수투과선속을 나타낸 반면에 $(NH_4)_2HPO_4$는 가장 낮은 수투과선속을 나타내었다. $NH_4H_2PO_4$가 가장 낮은 역용질선속 및 비역용질선속을 보였으며, $(NH_4)_2HPO_4$ < $KNO_3$ < $NH_4NO_3$의 순서로 역용질선속 및 비역용질선속이 증가하였다. $NH_4H_2PO_4$는 비록 다른 유도물질에 비해 수투과선속이 낮으나 비료의 주요 성분인 질소와 인을 모두 포함하고 있을 뿐만 아니라 질소와 인의 역용질선속 및 비역용질선속이 다른 유도물질에 비해 매우 낮으므로 FDFO (fertilizer drawn forward osmosis)에서 효과적으로 사용될 수 있을 것으로 판단된다.

衝突水噴流에 의한 高溫面의 沸騰熱流束에 관한 硏究 (A study on the boiling heat flux on high temperature surface by impinging water jet)

  • 이기우;김유
    • 대한기계학회논문집
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    • 제12권1호
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    • pp.81-94
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    • 1988
  • 본 연구에서는 표면상태가 다양한 고온면을 충돌온류에 의하여 냉각하는 방식이 광범위하게 응용되고 있는 점에 유의하여 표면조도, 노즐직경 및 분류속도를 변화시키고 노즐끝에 전열면의 직경과 동일한 원형판을 부착하여 비철액체를 막고 문극내에 온류액체를 강제유동시킴으로써 열전달에 미치는 모든 영향을 실험에 의해 고찰하고 고찰하고 포화수온류에 의한 열류속의 무차원관계식을 도출하는 것을 본 연구의 목적으로 하였다.

Choline chloride-Glycerol (1:2 mol) as draw solution in forward osmosis for dewatering purpose

  • Dutta, Supritam;Dave, Pragnesh;Nath, Kaushik
    • Membrane and Water Treatment
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    • 제13권2호
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    • pp.63-72
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    • 2022
  • Choline chloride-glycerol (1:2 mol), a natural deep eutectic solvent (NADES) is examined as a draw solution in forward osmosis (FO) for dewatering application. The NADES is easy to prepare, low in toxicity and environmentally benign. A polyamide thin film composite membrane was used. Characterization of the membrane confirmed porous membrane structure with good hydrophilicity and a low structural parameter (722 ㎛) suitable for FO application. A dilute solution of 20% (v/v) NADES was enough to generate moderate water flux (14.98 L m-2h-1) with relatively low reverse solute flux (0.125 g m-2h-1) with deionized water feed. Application in dewatering industrial wastewater feed showed reasonably good water flux (11.9 L m-2h-1) which could be maintained by controlling the external concentration polarization and fouling/scaling mitigation via simple periodic deionized water wash. In another application, clarified sugarcane juice could be successfully concentrated. Recovery of the draw solute was accomplished easily by chilling utilizing thermo responsive phase transition property of NADES. This study established that low concentration NADES can be a viable alternative as a draw solute for dewatering of wastewater and other heat sensitive applications along with a simple recovery process.

막여과 정수처리공정에서 전여과공정의 효용성 평가 (Utility Estimation of Pre-filtration on the Membrane Water Treatment Process)

  • 박민구;최상일
    • 상하수도학회지
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    • 제22권4호
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    • pp.445-448
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    • 2008
  • The application of the membrane filtration process has been increased for the drinking water treatment system because of excellent quality of treated water compared with the sand filtration process. The selection of suitable pre-treatment processes and optimum flux according to the characteristics of raw water are important factors for the design of membrane processes. In this study, the most efficient pre-treatment processes for drinking water was selected by investigating the effects of pre-treatment processes on the operational stability of the membrane filtration process. Both lab-scale and pilot-scale experiments were conducted. In the lab-scale test, the effect of pre-treatment processes on the stability of the membrane filtration process was investigated indirectly by comparing the performance of membrane flux for raw water, pre-treated water, and membrane permeated water. In the pilot-scale test, the usefulness of prefiltration processes was assessed by comparing the performance of single membrane process and hybrid coagulation-membrane process. The results indicated that the coagulation process contributed to the stabilization of trans-membrane pressure (TMP) by removing contaminants on membranes, though the pre-filtration process had little effect on the TMP.

수적을 이용한 순수확산화염의 소화에 관한 실험적 연구 (An Experimental Study of Extinguishiment of Purely Buoyant Diffusion Flame Using Water Drops)

  • 장용재;김명배;김진국
    • 연구논문집
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    • 통권24호
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    • pp.41-48
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    • 1994
  • This experimental study deals with the extinguishiment characteristics of an oil pool flame using the water spray. The water through the six different atomizers is ejected over the freely burning pool flame in the quiescent surrounding air. Injection direction is vertical to the surface of oil in a small tank with a diameter of 100mm and a height of 10mm. In order to estimate quantitatively the extinction, the burning rate as well as the effective water flux are measured. The effective water flux is the amount of the water which reach the pool from the nozzle. The burning rate with the water spray increases until the injection pressure increases to reach some value, which gives the maximum burning rate, while the effective water flux without the flame decreases or does not change according to increasing of the injection pressure. This maximum burning rate is greater than 2.5 times of burning rate of the fire without the water spray. As a matter of the extinguishiment, it is found that the water drops of which size is too small can not extinguish the fire because too small drops does not reach the fuel surface.

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고온평판의 분무냉각특성에 관한 연구 (A Study on the Spray Cooling Characteristics of hot Flat Plates)

  • 윤석훈
    • Journal of Advanced Marine Engineering and Technology
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    • 제22권6호
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    • pp.880-887
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    • 1998
  • In order to study heat transfer characteristics of spray cooling for the purpose of uniform and soft cooling of high temperature surface a series of experiments for a hot horizontal copper flat plate was performed by downflow spray water using flat spray nozzle. Cooling curves were mea-sured under the various experimental conditions of flow rates and temperatures of cooling water Surface temperature surface heat fluxes and heat transfer coefficients of horizontal upward-facing flat surface were calculated with cooling curves measured at each radial positions near the cooling surface by TDMA method. Generally heat transfer characteristics for spray cooling is simi-lar to boiling phenomenon of pool boiling. The minimum heat flux(MHF) appear at the surface temperature of about ${\Delta}Tsat=250^{\circ}C$ and the critical heat flux(CHF) appear at about ${\Delta}Tsat=250^{\circ}C$.

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A Mechanistic Critical Heat Flux Model for High-Subcooling, High-Mass-Flux, and Small-Tube-Diameter Conditions

  • Kwon, Young-Min;Chang, Soon-Heung
    • Nuclear Engineering and Technology
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    • 제32권1호
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    • pp.17-33
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    • 2000
  • A mechanistic model based on wall-attached bubble coalescence, previously developed by the authors, was extended to predict a vow high critical heat flux (CHF)in highly subcooled flow boiling, especially for high mass flux and small tube diameter conditions. In order to take into account the enhanced condensation due to high subcooling and high mass velocity in small diameter tubes, a mechanistic approach was adopted to evaluate the non-equilibrium flow quality and void fraction in the subcooled water flow boiling, with preserving the structure of the previous CHF model. Comparison of the model predictions against highly subcooled water CHF data showed relatively good agreement over a wide range of parameters. The significance of the proposed CHF model lies in its generality in applying over the entire subcooled flow boiling regime including the operating conditions of fission and fusion reactors.

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비료 유도용액의 정삼투를 이용한 하수처리수의 재이용 - 유도용액의 성능 평가 - (Water Reuse of Sewage Discharge Water Using Fertilizer Drawn Forward Osmosis - Evaluating the Performance of Draw Solution -)

  • 김승건;이호원
    • 멤브레인
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    • 제26권2호
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    • pp.108-115
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    • 2016
  • 비료를 유도용액으로 사용하는 정삼투를 하수처리수(2차 침전지 유출수)의 재이용에 적용하여 유도용액의 성능을 평가하였다. 일반적으로 많이 사용되고 있는 비료 중에서 삼투압, 용해도 및 pH 등을 고려하여 $NH_4H_2PO_4$, KCl, $KNO_3$, $NH_4Cl$, $(NH_4)_2HPO_4$, $NH_4NO_3$, $NH_4HCO_3$$KHCO_3$을 유도용액 후보군으로 선정하고, 수투과선속 및 역용질선속을 측정하여 유도용액의 성능을 평가하였다. 평균 수투과선속은 KCl > $NH_4Cl$ > $NH_4NO_3$ > $KNO_3$ > $KHCO_3$ > $NH_4HCO_3$ > $NH_4H_2PO_4$ > $(NH_4)_2HPO_4$의 순서로 나타났으며, KCl을 유도용액으로 사용하였을 때, 평균 수투과선속은 13.49 LMH이었다. 하수처리장 2차 침전지 유출수의 삼투압은 탈이온수의 삼투압에 비해 큰 차이가 없었다. 역용질선속은 $NH_4H_2PO_4$ < $NH_4Cl$ < $(NH_4)_2HPO_4$ < $KNO_3$ < $NH_4HCO_3$ < $NH_4NO_3$의 순서로 나타났으며, $NH_4H_2PO_4$를 유도용액으로 사용하였을 때, 역용질선속은 $4.96{\times}10^{-3}mmol/m^2{\cdot}sec$이었다.

원수의 수질화학과 HA의 물리화학적 특성이 막 오염에 미치는 영향 (Effects of Surface Water Chemistry and Physicochemical Characteristics of Humic Acid on Fouling of Membrane)

  • 배진열;한인섭;박성호;신지원
    • 한국물환경학회지
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    • 제21권3호
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    • pp.242-247
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    • 2005
  • In this study, we investigated the removal efficiencies of pollutants and permeate fluxes depending on chemistry of feed water, various molecular weight cut-offs (MWCOs) and materials of membrane, operating pressure. We used seven MWCO membranes of YC0.5, YM1, YM3, YM10, YM30, YM100 and PM30, humic acid solution and surface water as feed water, and examined variation in permeate flux. Results of TOC removal experiment demonstrate that MWCO lower 1,000daltons could remove humic acid effectively. As increasing solution pH and decreasing divalent cations ($Ca^{2+}$) concentration, TOC removal increased. But $UV_{254}$ removal efficiency increased with higher divalent cation concentration and solution pH. Membrane fouling increased with increasing electrolyte (NaCl), divalent cation concentration and decreasing solution pH. In spite of initial permeate flux of the hydrophobic membrane (PM30) was higher than that of the hydrophilic membrane (YM30), flux decline of PM30 was significant during operation. At higher operating pressure, compactness of the cake layer on the membrane surface increased, resulting in gradual increase in hydraulic resistance.

중공사 정밀여과 MBR공정을 이용한 제직폐수의 재이용 (Reuse of Weaving Wastewater by Membrane Bioreactor Equipped with a Hollow-fiber MF Membrane)

  • 정용준;배종홍;민경석
    • 한국물환경학회지
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    • 제20권4호
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    • pp.365-369
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    • 2004
  • Submerged membrane bio-reactor equipped with a hollow fiber microfiltration was applied to reuse weaving wastewater of water jet loom, where two parameters such as the concentration of MLSS and the flux were controlled. While the flux at the concentration of MLSS around 900mg/L was constantly kept over 0.4m/d and 0.8m/d in a short time, the stable flux at around 300mg/L of MLSS was shown at the 8 days later. Regardless of MLSS and flux, BOD, CODcr and Turbidity of the permeate were 1~2mg/L, 7~10mg/L and below 1 NTU, which were 85~90%, 87~90% and 98% of removal efficiency, respectively. The stable operation without fouling was achieved because the contents of ECP were smaller than those of common MBR processes and the composition(saccharide/protein) was kept constantly. In this study, 0.5~1.0m/d of flux and 400~900mg/L of MLSS were considered as the most recommendable operating condition for the reuse of weaving wastewater.