• Title/Summary/Keyword: Water Block

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Patterned Surfaces in Self-Organized Block Copolymer Films with Hexagonally Ordered Microporous Structures

  • Hayakawa Teruaki;Kouketsu Takayuki;Kakimoto Masa-alki;Yokoyama Hideaki;Horiuchi Shin
    • Macromolecular Research
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    • v.14 no.1
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    • pp.52-58
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    • 2006
  • A novel fabrication of the patterned surfaces in the polymer films was demonstrated by using the self-organizing character of the block copolymers of polystyrene-b-oligothiophenes and polystyrene-b-aromatic amide dendron. Hexagonally arranged open pores with a micrometer-size were spontaneously formed by casting the polymer solutions under a moist air flow. The amphiphilic character of the block copolymers played the crucial role as a surfactant to stabilize the inverse emulsion of water in the organic solvent, and subsequently the aggregated structure of the hydrophilic oligothiophene or aromatic amide dendron segments remained on the interiors of the micropores. The chemical composition on the top of the surface of the microporous films was characterized by energy-filtering transmission electron microscopy (EFTEM) or a time-of-flight secondary ion mass spectrometer (ToF-SIMS). The characterizations clearly indicated that the patterned surfaces in the self-organized block copolymer films with the hexagonally ordered microporous structures were fabricated in a single step.

Synthesis of New pH-Sensitive Amphiphilic Block Copolymers and Study for the Micellization Using a Fluorescence Probe

  • Kim, Kyung-Min;Choi, Song-Yee;Jeon, Hee-Jeong;Lee, Jae-Yeol;Choo, Dong-Joon;Kim, Jung-Ahn;Kang, Yong-Soo;Yoo, Hyun-Oh
    • Macromolecular Research
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    • v.16 no.2
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    • pp.169-177
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    • 2008
  • This paper reports a facile synthesis of new water-soluble poly(ethylene oxide) (PEO)-based amphiphilic block copolymers showing pH sensitive phase transition behaviors. The copolymers were prepared by atom transfer radical polymerization (ATRP) of methacrylamide type of monomers carrying a sulfonamide group using a PEO-based macroinitiator and a Cu(I)Br/$Me_6TREN$ catalytic system in aqueous media. The resulting polymers were characterized by a combination of $^1H$-NMR, size exclusion chromatography, and UV/Visible spectrophotometeric analysis. The micellization of the block copolymers as a drug-loading mechanism in aqueous media using fluorescein salt was examined as a function of pH. The stable micelle formation and its loading efficacy suggest that the block copolymers can be used as precursors for drug-nanocontainers.

Performance of convolutional coding using block interleaving in underwater frequency-selective channel (수중 주파수 선택적 채널에서 블록 인터리빙 기법을 적용한 길쌈부호화 기법의 성능)

  • Park, Jihyun;Yoon, Jong Rak
    • The Journal of the Acoustical Society of Korea
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    • v.38 no.2
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    • pp.207-213
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    • 2019
  • In this paper, we evaluate the communication performance of convolutional code with block interleaving in a frequency-selective channel. Block interleaving is a technique for spreading and rearranging digital data streams. A block interleaving technique is applied to improve the performance by dispersing the concentration of burst errors in a frequency-selective channel. As a result of evaluating the performance of the convolutional code with block interleaving in the water tank experiment, There was no difference in the performance of convolutional codes using block interleaving in a frequency-selective channel. However, in the frequency-selective channel, the convolutional code with block interleaving has a gain of 2dB, and it is confirmed that the underwater acoustic communication performance is improved.

A Study on the Development of Water Permeability Gap Block by Reinforced Fiber Content (보강섬유 함유량에 따른 투수성 틈새블록 개발에 관한 연구)

  • Jo, Joonho;Shin, Jung
    • The Journal of Engineering Geology
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    • v.32 no.4
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    • pp.661-670
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    • 2022
  • In recent years, extreme rainfall and rainy seasons caused by climate change have caused river flooding and flooding damage, and it is urgent to solve economic and environmental problems in the city center due to the increase in the number of peak homes. The gap block, called the fitting block, is designed to facilitate rainwater pitching by forming a gap between the block and the block by forming a concave part and a protrusion of the block differently without the use of an existing spacer. In this study, for the production of such a gap block, the existing cement content was reduced and aramid fibers and exploration fibers, which are industrial by-products such as Goroslag fine powder and reinforcing fibers, were applied.

Characteristic Analysis for Resistivity of Concrete (콘크리트의 저항률 특성 분석)

  • Kim, Sung-Sam;Choi, Jong-Kyu;Kim, Jae-Sung;Koh, Hee-Seog
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2006.05a
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    • pp.457-459
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    • 2006
  • In this paper was analyzed and compared the resistivity characteristic of concrete between moisture condition and dry condition to measure the variation of resistivity by water after making concrete scale block. The resistivity was decreased when the moisture of concrete block was gradually increased.

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Variation of Water Quality around the Chudong Intake Tower in Daechung Reservoir (대청호 추동취수탑 부근의 수질변화 특성)

  • Ma, Xin-Chao;Lim, Bong-Su;Heo, Soon-Uk;Kwak, Mi-Ae
    • Journal of Korean Society on Water Environment
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    • v.31 no.6
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    • pp.637-643
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    • 2015
  • This study has been carried out to provide the basic data obtained from the evaluation of the variation of water quality around the Chudong intake tower in Daechung resevoir, which may be able to help the establishment of a pure water supply policy. Five sites around the Chudong intake tower were selected, and the average data for recent ten years(from year 2004 to year 2013) were analysed. The average water quality around Chudong intake tower are as followed; pH 7.5, DO 8.7 mg/L, BOD 1.0 mg/L, COD 3.0 mg/L, SS 3.0 mg/L, TN 1.495 mg/L, TP 0.017 mg/L, and Chlorophyll-a 6.5 mg/m3 were matched the good class by comparing with the living environment standard of reservoir. COD values of higher than 3.0 mg/L after July were likely due to non-point pollutants and algae outbreak during rainy summer season. Total phosphorus rose sharply in the summer season, and then algae watch was issued consistently for average 40 days. Total nitrogen to total phosphorus ratio was average 90, and it is important to control the inflow phosphrous from small stream for proper management to block an algae growth according to eutrophication. It was recommended to operate the algae removing boats around intake tower from July to October, and was required advanced water treatment processes to remove NBD COD and bad odor and taste due to algae growth.

A Study on the Application Strategies of Renewable Energy Systems Considering Layout and Block Plan in Apartment Building (공동주택의 배치 및 블록별 재생에너지 시스템의 적용성에 관한 연구)

  • Lee, Kwan-Ho
    • Journal of the Korean Solar Energy Society
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    • v.26 no.3
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    • pp.79-87
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    • 2006
  • This study aims to presents the applicability of apartment building for renewable energy systems using method of uncomplicated calculation and computer simulation. According to the weather conditions (NASA Surface meteorology and Solar Energy) analysis, it has been found that photovoltaic and wind power system can be applied to apartment buildings application. In case study considering layout and block plan, adaptation of solar water heating, photovoltaic and wind energy system to apartment buildings was proved to produce a profit. And the application strategies of renewable energy systems can be used not only for the investment decisions for economic analysis but also for the comparative analysis of uncomplicated calculation and computer simulation.

Hydraulic Application of Grass Concrete In River Environment (하천환경에서의 그라스콘크리트의 적용성 연구)

  • Jang, Suk-Hwan;Nam, Yong-Hyuk;Kim, Seo-Young;Park, Seong-Beom;Park, Ung-Seo;Park, Sang-Woo
    • Proceedings of the Korea Water Resources Association Conference
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    • 2006.05a
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    • pp.472-477
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    • 2006
  • This study aims at investigating the failure cases of the pre-cast block system in river environments which widely used nowadays and reviewing the effect and flow resistance for grass concrete structure through the physical experiments by hydraulic model test and developing application method in river slope or levee which has rigid flood resistance. Grass concrete structure has been independently tested under high velocity flow under the super critical condition, it survived the 8 m/sec maximum flow velocity. This results shows grass concrete system is also suited to use in aggressive river environments such as repairing a flood damaged embankment that had placed at risk the adjacent drainage channel with vegetation.

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MA : Multiple Acknowledgement Mechanism for UWSN (UnderWater Sensor Network)

  • Shin, Soo-Young;Lee, Seung-Joo;Park, Soo-Hyun
    • Journal of Korea Multimedia Society
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    • v.12 no.12
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    • pp.1769-1777
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    • 2009
  • With the advent of the ubiquitous technology age, the progress of network technology has enabled a robust sensor communication, not just in cities, but also in poor surroundings such as deserts, polar regions, or underwater environments. In this paper, we propose a Multiple Acknowledgement (MA) technique to replace the conventional Automatic Repeat request (ARQ) technique. The MA mechanism is to send an Ack to many receivers simultaneously. The CH (master, coordinator) of the unit cluster broadcasts a Beacon frame where Ack information of the previously transmitted data is included. This technique can reduce the number of transmissions and overhead significantly. The proposed technique is a scheme improving the efficiency of an underwater sensor network where the uplink data transmission is the mainstream. The Performance of the ARQ, Block Ack, Pervasive Block Ack and the proposed method were compared with one another and analyzed. The proposed method showed significant performance improvement as compared with the ARQ, BA, and PBA in its channel efficiency.

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Highly Sulfonated Poly(Arylene Biphenylsulfone Ketone) Block Copolymers Prepared via Post-Sulfonation for Proton Conducting Electrolyte Membranes

  • Lee, Kyu Ha;Chu, Ji Young;Kim, Ae Rhan;Nahm, Kee Suk;Yoo, Dong Jin
    • Bulletin of the Korean Chemical Society
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    • v.34 no.6
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    • pp.1763-1770
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    • 2013
  • A series of the block copolymers were successfully synthesized from post-sulfonated hydrophilic and hydrophobic macromers via three-step copolymerization. The degrees of sulfonation (DS) of the copolymers (10%, 30%, or 50%) were controlled by changing the molar ratio of the hydrophilic and hydrophobic parts. The resulting block copolymers were characterized by $^1H$ NMR and other technologies. The membranes were successfully cast using dimethyl sulfoxide (DMSO) solution at $100^{\circ}C$. The copolymers were characterized to confirm chemical structure by $^1H$ NMR and FT-IR. Thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) demonstrated that all sulfonated block copolymers exhibited good thermal stability with an initial weight loss at temperatures above $240^{\circ}C$. The membranes showed acceptable ion exchange capacity (IEC) and water uptake values in accordance with DS. The maximum proton conductivity was 184 mS $cm^{-1}$ in block copolymer-50 at $60^{\circ}C$ and 100% relative humidity, while the conductivity of Nifion-115 was 160 mS $cm^{-1}$ under the same measurement conditions. AFM images of the block copolymer membranes showed well separated the hydrophilic and hydrophobic domains. From the observed results it is that the prepared block membranes can be considered as suitable polymer electrolyte membranes for the application of polymer electrolyte membrane fuel cells (PEMFC).