• Title/Summary/Keyword: Waste solution

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A pplication of $CO_2$ Technolgy in Nuclear Decontamination (원자력 제염에서 $CO_2$ 기술 응용)

  • Park, K.H.;Kim, H.W.;Kim, H.D.;Koh, M.S.;Ryu, J.D.;Kim, Y.E.;Lee, B.S.;Park, H.T.
    • Journal of the Korean institute of surface engineering
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    • v.34 no.1
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    • pp.62-67
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    • 2001
  • Green technology is being developed up to a point that is feasible not only in an environmental sense, but also in an economical viewpoint. This paper introduces two case studies that applied $CO_2$ technology into nuclear industry. 1) Nuclear laundry : A laundry machine that uses liquid and supercritical $CO_2$ as a solvent for decontamination of contaminated working dresses in nuclear power plants was developed. The machine consists of a 16 liter reactor, a recovery system with compressors, and storage tanks. All $CO_2$ used in cleaning is fully recovered and reused in next cleaning, resulting in no production of secondary nuclear waste. Decontamination factor is still lower than that in the methods currently used in the plant. Nuclear laundry using $CO_2$ looks promising with technical improvements-surfactants and mechanical agitation. 2) $CO_2$ nozzle decontamination : An adjustable nozzle for controlling the size of dry ice snow was developed. Using the developed nozzle, a surface decontamination device was made. Human oils like fingerprints on glass were easy to remove. Decontamination ability was tested using a contaminated pump-housing surface. About 40 to 80% of radioactivity was removed. This device is effective in surface-decontamination of any electrical devices like detector, controllers which cannot be cleaned in aqueous solution.

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Effects of Surfactant on SF6 Gas Hydrate Formation Rate (가스 하이드레이트 형성 원리를 이용한 SF6 처리 기술에 관한 연구)

  • Lee, Bo-Ram;Lee, Hyun-Ju;Kim, Shin-Ho;Lee, Ju-Dong;Kim, Yang-Do
    • Korean Journal of Materials Research
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    • v.18 no.2
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    • pp.73-76
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    • 2008
  • [ $SF_6$ ] gas has been widely used as an insulating, cleaning and covering gas due to its outstanding insulating feature and because of its inert properties. However, the global warming potential of $SF_6$ gas is extremely high relative to typical global warming gases such as $CO_2$, CFCs, and $CH_4$. For these reasons, it is necessary to separate and collect waste $SF_6$ gas. In this study, the effects of a surfactant (Tween) on the formation rate of $SF_6$ gas hydrates were investigated. The $SF_6$ gas hydrate formation rate increased with the addition of Tween and showed a nearly 6.5 times faster hydrate formation rate with an addition of 0.2 wt.% Tween compared to an addition of pure water. This is believed to be due to the increased solubility of $SF_6$ gas with the addition of the surfactant. It was also found that $SF_6$ gas hydrate in the surfactant solution showed two-stage hydrate formation rates with a formation rate that increased rapidly in the 2nd stage.

A Study on Development of Automatic Westing Software by Vectorizing Technique (벡터라이징을 이용한 자동부재배치 소프트웨어 개발에 관한 연구)

  • Lho T.J.;Kang D.J.;Kim M.S.;Park Jun-Yeong;Park S.W.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.10a
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    • pp.748-753
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    • 2005
  • Among processes to manufacture parts from footwear materials like upper leathers, one of the most essential processes is the cutting one optimally arranging lots of parts on raw footwear materials and cutting. A new nesting strategy was proposed for the 2-dimensional part layout by using a two-stage approach, where which can be effectively used for water jet cutting. In the initial layout stage, a SOAL(Self-Organization Assisted Layout) based on the combination of FCM(Fuzzy C-Means) and SOM was adopted. In the layout improvement stage, SA(Simulated Annealing) based approach was adopted for a finer layout. The proposed approach saves much CPU time through a two-stage approach scheme, while other annealing-based algorithm so far reported fur a nesting problem are computationally expensive. The proposed nesting approach uses the stochastic process, and has a much higher possibility to obtain a global solution than the deterministic searching technique. We developed the automatic nesting software of NST(ver.1.1) software for footwear industry by implementing of these proposed algorithms. The NST software was applied by the optimized automatic arrangement algorithm to cut without the loss of leathers. if possible, after detecting damage areas. Also, NST software can consider about several features in not only natural loathers but artificial ones. Lastly, the NST software can reduce a required time to implement generation of NC code. cutting time, and waste of raw materials because the NST software automatically performs parts arrangement, cutting paths generation and finally NC code generation, which are needed much effect and time to generate them manually.

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Adsorption Behaviors of Nickel Ion on the Manganese Dioxide Powder (이산화망간 미립자(微粒子)의 니켈이온 흡착(吸着) 거동(擧動))

  • Baek, Mi-Hwa;Kim, Min-Kyung;Kim, Dong-Su;Sohn, Jeong-Soo
    • Resources Recycling
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    • v.17 no.1
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    • pp.59-65
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    • 2008
  • The adsorption features of nickel ion in wastewater on manganese dioxide from spent batteries were investigated for its usage as an adsorbent. The aquatic behavior of nickel ion was characterized by MINTEQ program and the considered influential variables on the adsorption of nickel ion were its initial concentration, reaction temperature, the amount of adsorbent, and pH. The adsorption ratio of nickel ion decreased with increasing its initial concentration and thermodynamic estimation has been carried out based on the adsorption characteristics of nickel ion depending on temperature. In addition, the adsorption of nickel ion was shown to be promoted according to the amount of manganese dioxide and a lot of nickel ions were adsorbed as the solution pH was raised.

Collision between Technology and Politics in Korea's Nuclear Policy (한국의 원자력정책을 둘러싼 기술과 정치의 충돌)

  • Hong Jung-Jin;Won Byung-Chul
    • Journal of Science and Technology Studies
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    • v.2 no.1 s.3
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    • pp.135-156
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    • 2002
  • The view of technology is largely divided into 2 theories: (1) the theory of autonomous technology that claims technology's own development logic and momentum, (2) the theory of social determinism that regards technology as reflection of political choices. Autonomous technologists read our society in the language of technology and social determinists read our technology in the language of society. This paper tries to analyze that conflicts between government and environmental group in nuclear policy, especially radioactive waste disposition policy reflect collisions between autonomous technologists and social determinists representing technology and politics, respectively. On the surface, such collisions are occurred in rational, ethical and economical aspects. It maintains, however, in depth, they are about solution means to problems from which technologies derived. Also, it suggests that one of the alternatives to avoid inevitable collision may be interaction approach based on intertwining technology with society. More understanding of political natures and control possibilities for technology is needed because interaction approach is founded on this understanding. Finally, to help forming the Korea's nuclear utilization policy from now on, it gives 2 case studies compared France with Germany where expanding and contracting nuclear utilization policy, respectively.

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Modelling and packed bed column studies on adsorptive removal of phosphate from aqueous solutions by a mixture of ground burnt patties and red soil

  • Rout, Prangya R.;Dash, Rajesh R.;Bhunia, Puspendu
    • Advances in environmental research
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    • v.3 no.3
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    • pp.231-251
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    • 2014
  • The present study examines the phosphate adsorption potential and behavior of mixture of Ground Burnt Patties (GBP), a solid waste generated from cooking fuel used in earthen stoves and Red Soil (RS), a natural substance in fixed bed column mode operation. The characterization of adsorbent was done by Proton Induced X-ray Emission (PIXE), and Proton Induced ${\gamma}$-ray Emission (PIGE) methods. The FTIR spectroscopy of spent adsorbent reveals the presence of absorbance peak at $1127cm^{-1}$ which appears due to P = O stretching, thus confirming phosphate adsorption. The effects of bed height (10, 15 and 20 cm), flow rate (2.5, 5 and 7.5 mL/min) and initial phosphate concentration (5 and 15 mg/L) on breakthrough curves were explored. Both the breakthrough and exhaustion time increased with increase in bed depth, decrease in flow rate and influent concentration. Thomas model, Yoon-Nelson model and Modified Dose Response model were used to fit the column adsorption data using nonlinear regression analysis while Bed Depth Service Time model followed linear regression analysis under different experimental condition to evaluate model parameters that are useful in scale up of the process. The values of correlation coefficient ($R^2$) and the Sum of Square Error (SSE) revealed the Modified Dose Response model as the best fitted model to the experimental data. The adsorbent mixture responded effectively to the desorption and reusability experiment. The results of this finding advocated that mixture of GBP and RS can be used as a low cost, highly efficient adsorbent for phosphate removal from aqueous solution.

Sorption of Heavy Metals from the Wastewater by the Artificial Zeolite (인공 제올라이트에 의한 폐수중 중금속 흡착)

  • Lee, Deog-Bae;Lee, Kyeong-Bo;Lee, Sang-Bok;Han, Sang-Soo;Henmi, Teruo
    • Korean Journal of Soil Science and Fertilizer
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    • v.31 no.1
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    • pp.61-66
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    • 1998
  • An artificial zeolite was synthesized from bituminous coal fly ash by thermo-alkali treatment, $100{\pm}3^{\circ}C$ and 3.5 N NaOH solution for 24 hours, to develope new useful material in waste water treatment system. The artificial zeolite had much higher cation exchange capacity, $299cmol^+\;kg^{-1}$ and lower concentration of extractable heavy metals than bituminous coal fly ash. The higher the temperature and the longer the shaking time, the more Zn, Cu, Cd and Pb were sorbed chemically by the artificial zeolite. Shaking artificial zeolite and wastewater at $35^{\circ}C$ for 9 hours, the amount of sorbed heavy metals were $123.5g\;kg^{-1}$ for Zn, $164.7g\;kg^{-1}$ for Cu, $184.4g\;kg^{-1}$ for Cd and $350.6g\;kg^{-1}$ for Pb, respectively.

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Preparation of Zeolite Coated with Metal-Ferrite and Adsorption Characteristics of Cu(II) (금속 페라이트가 코팅된 제올라이트의 제조와 Cu(II)의 흡착 특성)

  • Baek, Sae-Yane;Nguyen, Van-Hiep;Kim, Young-Ho
    • Applied Chemistry for Engineering
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    • v.30 no.1
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    • pp.54-61
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    • 2019
  • In this study, a magnetic adsorbent was synthesized by growing ferrite nanoparticles substituted with metals (Me = Co, Mn, Ni) on zeolite 4A for the efficient separation of waste adsorbents present in the solution after the adsorption of Cu(II). The metal ferrite grown on the surface of zeolite was prepared by solvothermal synthesis. Characteristics of the magnetic adsorbent were analyzed by X-ray diffractometer (XRD), scanning electron microscopy (SEM) and physical property measurement system (PPMS). The saturation magnetization of the A type zeolite coated with Co-ferrite (CFZC) was the highest at 5 emu/g and the Cu(II) adsorption performance was also excellent. The adsorption results of Cu(II) on CFZC were well fitted by the Langmuir model at 298 K. Also, the adsorption of Cu(II) on CFZC follows a pseudo-second order kinetic. The Gibbs free energy values (${\Delta}G^0$) ranging from -4.63 to -5.21 kJ/mol indicates that the Cu(II) adsorption is spontaneous in the temeprature range between 298 and 313 K.

Implimentation of Smart Farm System Using the Used Smart Phone (중고 스마트폰을 활용한 스마트 팜 시스템의 구현)

  • Kwon, Sung-Gab;Kang, Shin-Chul;Tack, Han-Ho
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.22 no.11
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    • pp.1524-1530
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    • 2018
  • In this paper, we designed a product that can prevent environmental pollution, waste of resources, and leakage of foreign currency by commercializing a green IT solution by merging a used smart phone with the IoT object communication technology for the first time in the world. For the experiment of the designed system, various performance and communication condition was experimented by installing it in the actual crop cultivation facility. As a result, when a problem occurs, the alarm sound and video notification are generated by the user's smart phone, and remote control of various installed devices and data analysis in real time are possible. In this study, it is thought that the terminal management board developed for the utilization of the used smart phone can be applied to various fields such as agriculture and environment.

Hydroxyapatite prepared from eggshell and mulberry leaf extract by precipitation method

  • Wu, Shih-Ching;Hsu, Hsueh-Chuan;Hsu, Shih-Kuang;Liu, Mei-Yi;Ho, Wen-Fu
    • Biomaterials and Biomechanics in Bioengineering
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    • v.4 no.1
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    • pp.21-32
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    • 2019
  • Eggshell is a waste material after the usage of egg. In this work, biowaste chicken eggshells were used for preparing carbonated hydroxyapatite (HA) nanoparticles of high purity through aqueous precipitation method at room temperature. The eggshell-derived HA will be a cost-effective bioceramics for biomedical applications and an effective material-recycling technology. Additionally, mulberry leaf extract was used as a template to regulate the morphology, size and crystallinity of HA, and the effects of pH value were also examined. Characterization of the samples was performed by X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectroscopy. Scanning electron microscopy (SEM) was used to determine the size, shape and morphology of HA. The results indicate that only one phase of HA were synthesized in the both absence and presence of mulberry leaf extract at pH of 7 and above, while DCPD or DCPA/DCPD phase was observed at pH 4 condition. The crystallite sizes of the HA samples obviously decreased when adding mulberry leaf extract as a template, while they decreased gradually as the solution pH levels increased. With increasing pH level from 7 to 14, the rod-like HA nanoparticles gradually changed to spherical shape at pH 14. Note that, the obtained product is Mg and Sr containing A- and B-type carbonate HA at alkaline pH and it can be a potential material for biomedical applications.