• Title/Summary/Keyword: WLF

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Lifetime Prediction of Geogrids for Reinforcement of Embankments and Slopes through Time-Temperature Superposition

  • Koo, Hyun-Jin;Kim, You-Kyum;Kim, Dong-Whan
    • Corrosion Science and Technology
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    • v.4 no.4
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    • pp.147-154
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    • 2005
  • The creep resistance of geogrids is one of the most significant long-term safety characteristics used as the reinforcement in slopes and embankments. The failure of geogrids is defined as creep strain greater than 10%. In this study, the accelerated creep tests were applied to polyester geogrids at various loading levels of 30, 50% of the yield strengths and temperatures using newly designed test equipment. Also, the new test equipment permitted the creep testing at or above glass transition temperature($T_g$) of 75, 80, $85^{\circ}C$. The time-dependent creep behaviors were observed at various temperatures and loading levels. And then the creep curves were shifted and superposed in the time axis by applying time-temperature supposition principles. The shifting factors(AFs) were obtained using WLF equation. In predicting the lifetimes of geogrids, the underlying distribution for failure times were determined based on identification of the failure mechanism. The results confirmed that the failure distribution of geogrids followed Weibull distribution with increasing failure rate and the lifetimes of geogrids were close to 100 years which was required service life in the field with 1.75 of reduction factor of safety. Using the newly designed equipment, the creep test of geogrids was found to be highly accelerated. Furthermore, the time-temperature superposition with the newly designed test equipment was shown to be effective in predicting the lifetimes of geogrids with shorter test times and can be applied to the other geosynthetics.

Mesoscale modeling of the temperature-dependent viscoelastic behavior of a Bitumen-Bound Gravels

  • Sow, Libasse;Bernard, Fabrice;Kamali-Bernard, Siham;Kebe, Cheikh Mouhamed Fadel
    • Coupled systems mechanics
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    • v.7 no.5
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    • pp.509-524
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    • 2018
  • A hierarchical multi-scale modeling strategy devoted to the study of a Bitumen-Bound Gravel (BBG) is presented in this paper. More precisely, the paper investigates the temperature-dependent linear viscoelastic of the material when submitted to low deformations levels and moderate number of cycles. In such a hierarchical approach, 3D digital Representative Elementary Volumes are built and the outcomes at a scale (here, the sub-mesoscale) are used as input data at the next higher scale (here, the mesoscale). The viscoelastic behavior of the bituminous phases at each scale is taken into account by means of a generalized Maxwell model: the bulk part of the behavior is separated from the deviatoric one and bulk and shear moduli are expanded into Prony series. Furthermore, the viscoelastic phases are considered to be thermorheologically simple: time and temperature are not independent. This behavior is reproduced by the Williams-Landel-Ferry law. By means of the FE simulations of stress relaxation tests, the parameters of the various features of this temperature-dependent viscoelastic behavior are identified.

Nonlinear Dielectric Relaxation in VDCN/VPr Copolymer (VDCN/VPr 공중합체(共重合體)의 비선형(非線形) 유전특성(誘電特性))

  • Lee, Duck-Chool;Kang, Dae-Ha
    • Proceedings of the KIEE Conference
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    • 1989.07a
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    • pp.356-358
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    • 1989
  • Linear and nonlinear complex permittivities have been measured for an alternating copolymer of vinylidene cyanide(VSCN) with vinyl propionale(VPr). It is found that the third order permittivity ${\varepsilon}_3$ depends upon frequency according to a function V ${\varepsilon}_3$/ ${1+(j{\omega}{\tau}_3)^{\beta}}^3$ while the linear permittivity ${\varepsilon}_1$obeys a Debye type function ${\nabla}{\varepsilon}_1$/ {1+$(j{\omega}{\tau}_1)^{\beta}$}. Experimental results are well fitled by predicted functions except at low frequency where dc conduction dominates. The relaxation times ${\tau}_1$ and ${\tau}_3$ at same teperature are nealy equal and depend upon temperature according to WLF form. The relaxation strengths ${\nabla}{\varepsilon}_1$ and ${\nabla}{\varepsilon}_3$ have a peak at the vicinity of glass transition temperature (Tg). The strength ${\nabla}{\varepsilon}_1$ has a value of -9 order and ${\nabla}{\varepsilon}_3$ has a negative value of -25 order. The analysis of mechanism by combined knowledge about linear and nonlinear permittivities and dipole moment gives us an imformation of the electrical and thermal dipolar motions in this copolymer.

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Debt Finance among Vietnamese Enterprises: The Influence of Managers' Gender

  • HO, Hoang Lan;DAO, Minh Hoa;PHAN, The Cong
    • The Journal of Asian Finance, Economics and Business
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    • v.7 no.9
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    • pp.229-239
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    • 2020
  • This paper examines the impact of gender on access to debt finance among Vietnamese enterprises. The paper investigates data and variables retrieved from the World Bank Enterprise Survey dataset using five Probit models. The regression results suggest that there exist more unfavourable debt financing conditions for women-led firms (WLF), measured as a lower probability of having loan applications fully approved. Firm's age, working sector, and perception of access to finance as a difficulty are found to have explanatory power on the discrimination. More importantly, the perception of debt finance as a difficulty or firms' level of confidence significantly explains the variance of the dependent variable of probability of loan approval, or gender effect would be more pronounced if the firm already has a low level of confidence. The paper also contributes in testing for the gender effect on Vietnamese enterprises from different sectors and scale, unlike other prior research papers focusing on specific sectors and/or small and medium enterprises only. The findings are highly useful for Vietnamese credit institutions to set out a specific business policy to attract more WLFs and help promoting gender equality in the working environment, especially in debt financing, which is often neglected in existing regulation and policy frameworks.

Effects of acid-anhydride hardener and postcuring heat-treatments on dielectric properties of epoxy composites (에폭시 복합체의 유전특성에 미치는 산무수물 경화제와 후경화 열처리의 영향)

  • 왕종배;이성일;이준웅
    • Electrical & Electronic Materials
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    • v.7 no.3
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    • pp.187-199
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    • 1994
  • In order to find an effect of structural changes due to variation of addition ratio of anhydride hardener and postcuring herat-treatments upon electrical properties of epoxy composites, the dielectric properties over a frequency range from 30[Hz] to l[MHz] were investigated in the temperature range of 20-180[.deg. C]. From the dielectric properties, the a peaks related with glass-transition phenomena of epoxy network appeared near 130[.deg. C], the conduction loss in high temperature region above 150[.deg. C] due to thermal dissociation of hardener started off with the low frequency side and the .betha. peak concerned with contribution of movable unreacted terminal epoxy groups and curing agents in the glass states concurred with the high-frequency side below 20[.deg. C]. And an effect of an hydride hardener upon structural changes and of postcuring heat treatments upon structural stability in epoxy composites would be explained through the estimation of the distribution of relaxation times and the activation energy for a .alpha. peak according to the WLF equations.

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Analysis for Filling Stage of Injection Molding Considering Compressibility and Phase Change (압축성과 상변화를 고려한 사출성형의 충전과정 해석)

  • Lee, Sang-Chan;Park, Chang-Eon;Yang, Dong-Yeol
    • Journal of the Korean Society for Precision Engineering
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    • v.18 no.12
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    • pp.60-65
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    • 2001
  • To simulate the real molding conditions, the effects of phase change and compressibility of the resin were considered in the present investigation. A modified Cross model with either an Arrhenius-type or WLF-type functional form was used for modeling viscosity of the resin. A double-domain Tait equation of state was employed to describe the compressibility of the resin during molding. The energy balance equation including latent-heat dissipation fur semi-crystalline materials was solved in order to predict the solidified layer and temperature profile. Injection molding experiments were carried out using polypropylene(PP) in the present study. Based on the comparison between experiments and simulations, it was found out the predicted pressure distributions and melt front propagations were accurate. Thus it was concluded that the program developed in this study was proved to be useful in simulations of injection molding process.

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Life-time Prediction of a FKM O-ring using Intermittent Compression Stress Relaxation (CSR) and Time-temperature Superposition (TTS) Principle (간헐 압축응력 완화와 시간-온도 중첩 원리를 이용한 FKM 오링의 수명 예측 연구)

  • Lee, Jin-Hyok;Bae, Jong-Woo;Kim, Jung-Su;Hwang, Tae-Jun;Park, Sung-Doo;Park, Sung-Han;Min, Yeo-Tae;Kim, Won-Ho;Jo, Nam-Ju
    • Elastomers and Composites
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    • v.45 no.4
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    • pp.263-271
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    • 2010
  • Intermittent CSR testing was used to investigate the degradation of an FKM O-ring, also the prediction of its life-time. An intermittent CSR jig was designed taking into consideration the O-ring's environment under use. The testing allowed observation of the effects of friction, heat loss, and stress relaxation by the Mullins effect. Degradation of O-rings by thermal aging was observed between 60 and $160^{\circ}C$. In the high temperature of range ($100-160^{\circ}C$) O-rings showed linear degradation behavior and satisfied the Arrhenius relationship. The activation energy was about 60.2 kJ/mol. From Arrhenius plots, predicted life-times were 43.3 years and 69.9 years for 50% and 40% failure conditions, respectively. Based on TTS (time-temperature superposition) principle, degradation was observed at $60^{\circ}C$, and could save testing time. Between 60 and $100^{\circ}C$ the activation energy decreased to 48.3 kJ/mol. WLF(William-Landel-Ferry) plot confirmed that O-rings show non-linear degradation behavior under $80^{\circ}C$. The life-time of O-rings predicted by TTS principle was 19.1 years and 25.2 years for each failure condition. The life-time predicted by TTS principle is more conservative than that from the Arrhenius relationship.